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Engineering topics

Kelzenberg, Michael D.

Publications and source records attributed to Kelzenberg, Michael D..

Apparatus and systems for incorporating effective transparent catalyst for photoelectrochemical application

Photoelectrochemical (PEC) technology for the conversion of solar energy into chemicals may require cost-effective photoelectrodes to efficiently and stably drive anodic and/or cathodic half-reactions to complete the overall reactions for storing solar energy in chemical bonds. Apparatus and systems incorporating effectively transparent metal catalysts enable the design and/or implementation of PEC devices for light harvesting. Triple-junction photocathodes with the triangular catalyst grids are provided to improve the efficiency of the photocathodes to generate renewable fuel from sunlight.

Cheng, Wen-Hui↗

Countdown to perovskite space launch: Guidelines to performing relevant radiation-hardness experiments

Perovskite photovoltaics (PVs) are under intensive development for promise in terrestrial energy production. Soon, the community will find out how much of that promise may become reality. Perovskites also open new opportunities for lower cost space power. However, radiation tolerance of space environments requires appropriate analysis of relevant devices irradiated under representative radiation conditions. We present guidelines designed to rigorously test the radiation tolerance of perovskite PVs. We review radiation conditions in common orbits, calculate nonionizing and ionizing energy losses (NIEL and IEL) for perovskites, and prioritize proton radiation for effective nuclear interactions. Low-energy protons (0.05-0.15 MeV) create a representative uniform damage profile, whereas higher energy protons (commonly used in ground-based evaluation) require significantly higher fluence to accumulate the equivalent displacement damage dose due to lower scattering probability. Furthermore, high-energy protons may "heal" devices through increased electronic ionization. These procedural guidelines differ from those used to test conventional semiconductors.

14 SOLAR ENERGY↗

Irradiation Experiments on High Efficiency Nanowire Solar Cells Including Tilted Incidence Angle

Nanowire based solar cells have promising potential to become the next generation of space solar cells. In this study we corroborate their high radiation tolerance by irradiating high efficiency GaAs (efficiency > 15 %) nanowire solar cells with 1 MeV electrons at a fluence of 10 16 e - /cm 2 . Additionally, we theoretically show that the damage in nanowire solar cells is expected to be slightly dependent on the incidence angle and the geometry of the nanowire array. However, experimentally, two sets of GaAs nanowire solar cells have been irradiated with 1 MeV electrons at normal incidence and with a 25° tilted angle exhibiting a similar degradation.

high specific power↗

Radiation Tolerant Nanowire Array Solar Cells

Space power systems require photovoltaics that are lightweight, efficient, reliable, and capable of operating for years or decades in space environment. Current solar panels use planar multi-junction, III-V based solar cells with very high efficiency, but their specific power (power to weight ratio) is limited by the added mass of radiation shielding (e.g. coverglass) required to protect the cells from the high-energy particle radiation that occurs in space. Here we demonstrate that III-V nanowire-array solar cells have dramatically superior radiation performance relative to planar solar cell designs and show this for multiple cell geometries and materials, including GaAs and InP. Nanowire cells exhibit damage thresholds ranging from ~10-40 times higher than planar control solar cells when subjected to irradiation by 100-350 keV protons and 1 MeV electrons. Furthermore, using Monte Carlo simulations, we show that this improvement is due in part to a reduction in the displacement defect generation within the wires arising from their nanoscale dimensions. Radiation tolerance, combined with the efficient optical absorption and the improving performance of nanowire photovoltaics, indicates that nanowire arrays could provide a pathway to realize high-specific-power, substrate-free, III-V space solar cells with substantially reduced shielding requirements. More broadly, the exceptional reduction in radiation damage suggests that nanowire architectures may be useful in improving the radiation tolerance of other electronic and optoelectronic devices.

14 SOLAR ENERGY↗