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Khaleel Rahman, Ramees

Publications and source records attributed to Khaleel Rahman, Ramees.

5 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

DME-Propane Autoignition Measurements inside a Shock Tube

Dimethyl ether (DME) is a biofuel that has the potential to replace diesel in heavy-duty engines. A blend of propane (C3H8) and DME could reduce emissions when compared to diesel at heavy-duty compression engine-relevant conditions. Testing a potential new mixture in a compression engine requires a high-fidelity chemical kinetics model that accurately predicts autoignition delay times, which is especially necessary for a compression engine. In this work, autoignition data has been gathered at an equivalence ratio of 2.0 for pressures of 60 and 80 bar. DME and propane were combusted in synthetic air while excited hydroxyl (OH*) chemiluminescence was used to gather ignition delay times. Data was compared to recent chemical kinetic mechanisms for the two different pressures. Using the mechanism with the best fit of autoignition data, a sensitivity analysis was conducted to analyze the chemical kinetics of the DME/C3H8 combustion at elevated pressures.

Mohammed, Zuhayr Pasha↗
DOE OSTI2023

DME-Propane Ignition Delay Time Measurements at Mixing Controlled Compression Ignition Engine-Relevant Conditions

The blend of dimethyl ether (DME, CH 3 OCH 3 ) and propane (C 3 H 8 ) is a potentially renewable fuel mixture that has the potential to replace diesel in compression ignition engines. The combination can potentially reduce particulate and greenhouse gas emissions compared to a conventional diesel engine operating under similar conditions. However, detailed conceptual and simulation studies must be conducted before adopting a new fuel on a compression ignition engine. For these simulations, accurate chemical kinetic models are necessary. However, the validity of chemical kinetic mechanisms in the literature is unknown for mixing controlled compression ignition (MCCI) engine operating conditions. Hence, in this work, we studied the ignition of dimethyl ether (DME) and propane blends in a shock tube at MCCI engine conditions. Ignition delay time (IDT) data was collected behind the reflected shock for DME-propane mixtures for heavy-duty compression ignition (CI) engine parameters. Undiluted experiments spanning temperatures of 700 to 1100 K and pressures of 55 to 84 bar for various blends (100% CH 3 OCH 3 / 0% C 3 H 8, 100% C 3 H 8 / 0% CH 3 OCH 3 , 60% CH 3 OCH 3 / 40% C 3 H 8 ) of DME and propane were combusted in synthetic air (21% O 2 / 79% N 2 ). Some experiments were conducted at higher pressures (90-120 bar) to understand model performance at these conditions. Comparisons of IDT were made with the predictions of recent chemical kinetic mechanisms for DME-propane mixture, including the Aramco3.0, NUIG, and Dames et al. mechanisms. All mechanisms overpredicted IDT compared to experimental values. Sensitivity analysis was conducted with Dames et al. model, and critical reactions sensitive to IDT of DME-propane mixture near 100 bar are outlined.

Mohammed, Zuhayr Pasha↗
DOE OSTI2023

Autoignition Delay Times of Hydrogen/Ammonia/Air Mixtures at Gas Turbine Relevant Conditions

This study reports the autoignition delay times of hydrogen/ammonia mixtures at conditions similar to turbine engine operating conditions (23 bar, 1100-1250 K). H2 was mixed with NH3 and shock-heated using synthetic air as the oxidizer. The data is compared against the current state-of-the-art NH3 chemical kinetic mechanisms found in the literature for undiluted fuel validation and refinement. Experiments were performed in a high-pressure shock tube and have shown detonation pressures reaching 200 bar. Lower temperature points have also exhibited non-ideal behavior, which calls for extensive chemical analysis to accurately report the IDTs. This work will aid in the design of air-breathing turbine engines using hydrogen and ammonia as fuel and develop a well-built NH3-based chemical kinetic mechanism.

Pierro, Michael↗
DOE OSTI2022

Ammonia Hydrogen Ignition Measurements for Clean Aircraft Propulsion

In the current study, the oxidation of ammonia with hydrogen as well as ammonia with Natural Gas was carried out in order to study the ignition delay times behind reflected shock waves to refine chemical kinetic models. Experiments were carried out in the University of Central Florida’s shock tube facility by utilizing chemiluminescence to obtain OH* emission. Experimental results were then compared with the mainstay GRI 3.0 mechanism, as well as the proprietary UCF 2022 mechanism. Results indicate that for hydrogen/ammonia mixtures, GRI 3.0 overpredicts experimental values while UCF 2022 aligns well at low temperatures but shows variance at high temperature conditions. For hydrogen/Natural Gas mixtures, neither mechanism is able to accurately predict the experimental ignition delay times. The UCF 2022 mechanism is currently being adjusted based on a sensitivity study that was carried out and the experimental results so that it will be able to capture the ignition behavior of hydrogen-carrying compounds during combustion. Experiments are currently being planned in order to extend the pressure and temperature range.

Baker, Jessica↗