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Killen, Rosemary M.

Publications and source records attributed to Killen, Rosemary M..

At least 19 records

Was the Sun a Slow Rotator? Sodium and Potassium Constraints from the Lunar Regolith

While the Earth and Moon are generally similar in composition, a notable difference between the two is the apparent depletion in moderately volatile elements in lunar samples. This is often attributed to the formation process of the Moon, and it demonstrates the importance of these elements as evolutionary tracers. Here we show that paleo space weather may have driven the loss of a significant portion of moderate volatiles, such as sodium and potassium, from the surface of the Moon. The remaining sodium and potassium in the regolith is dependent on the primordial rotation state of the Sun. Notably, given the joint constraints shown in the observed degree of depletion of sodium and potassium in lunar samples and the evolution of activity of solar analogs over time, the Sun is highly likely to have been a slow rotator. Because the young Sun's activity was important in affecting the evolution of planetary surfaces, atmospheres, and habitability in the early Solar System, this is an important constraint on the solar activity environment at that time. Finally, as solar activity was strongest in the first billion years of the Solar System, when the Moon was most heavily bombarded by impactors, evolution of the Sun's activity may also be recorded in lunar crust and would be an important well-preserved and relatively accessible record of past Solar System processes.

Saxena, Prabal

Coronagraphic Observations of the Lunar Sodium Exosphere January-June, 2017

In order to observe the lunar sodium exosphere out to one-half degree around the Moon, we designed, built and installed a small robotically controlled coronagraph at the Winer Observatory in Sonoita, Arizona. Observations are obtained remotely every available clear night from our home base at Goddard Space Flight Center or from Prescott, Arizona. We employ an Andover temperature-controlled 1.5-angstrom-wide narrow-band filter centered on the sodium D2 line, and a similar 1.5-angstrom filter centered blueward of the D2 line by 3 angstroms for continuum observations. Our data encompass lunations in 2015, 2016, and 2017, thus we have a long baseline of sodium exospheric calibrated images. During the course of three years we have refined the observational sequence in many respects. Therefore this paper only presents the results of the spring, 2017, observing season. We present limb profiles from the south pole to the north pole for many lunar phases. Our data do not fit any power of cosine model as a function of lunar phase or with latitude. The extended Na exosphere has a characteristic temperature of about 2250–6750 degrees Kelvin, indicative of a partially escaping exosphere. The hot escaping component may be indicative of a mixture of impact vaporization and a sputtered component.

Moon

Observations of Mercury's Exosphere: Composition and Structure: Chapter - 14

Mercury is surrounded by a tenuous exosphere in which particles travel on ballistic trajectories under the influence of a combination of gravity and solar radiation pressure. The densities are so small that the surface forms the exobase and particles in the exosphere are more likely to collide with it rather than with each other. For a planet with a more substantial collision­-dominated atmosphere, a population of particles that enters from below the exobase supplies the exosphere. In contrast Mercury's exosphere is supplied both by incoming sources including the solar wind (hydrogen and helium), micrometeoroids (dust), meteoroids and cornets, and by particles released from the surface through a variety of processes that include sputtering by solar wind ions, desorption by solar photons and electrons, impacts by micrometeoroids, and thermal desorption of surface materials. These source processes are balanced by loss processes, which include impact with and sticking to the surface, Jeans (or thermal) escape, ionization followed by trans­port along magnetic field lines, and acceleration by solar radia­tion pressure to escape velocity. Ground-based attempts to detect an atmosphere around Mercury before Mariner 10 first visited the planet in 1974 were unsuccessful and led only to increasingly tight upper limits, culminating in a limiting value for surface atmospheric pressure of 0.015 Pascal (Pa) determined by Fink et al. (1974).

Solar

Understanding Mercury's Exosphere: Models Derived from MESSENGER Observations: Chapter - 15

The observations of Mercury's exosphere described in Chapter 14 have led to many modeling efforts. Early models were based upon a few simple assumptions and primarily explored the dynamics of sodium atoms pushed anti-sunward by radiation pressure [Ip, 1986; Smyth and Marconi, 1995]. More recently, these early models have been superseded by simulations with an increasing number of interdependent source processes [Leblanc and Johnson, 2003; Mura et al., 2009; Leblanc and Johnson, 2010; Burger et al., 2010, 2012, 2014]. We briefly summarize the source and loss processes before describing the published exosphere models, first for the three species observed almost continuously during the MESSENGER mission by the Ultraviolet and Visible Spectrometer (UVVS) channel of the Mercury Atmospheric and Surface Composition2Spectrometer (MASCS), (Na, Mg and Ca), and then more briefly for other species that have been observed or for which new upper limits have been derived.15.1 Overview of Source and Loss Processes15.1.1 Source Processes15.1.1.1 Thermal DesorptionThermal desorption (or thermal evaporation) is the release of adsorbed atoms from a surface via heating. Thermal desorption is related to the binding energy of the atom on the surface and the vibrational frequency of the bound atom, such that the rate of thermal desorption is given by, (15.1)where TD,

Thermal

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium-Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Mercury

The Lunar Neon Exosphere Seen in LACE Data

Using the LACE data from Apollo 17 we have found measured neon densities consistent with the 20Ne surface number densities reported by Cook et al. (2013) for normal conditions, terminator surface densities of 3 (±1.5) × 10(exp 3) per cu.cm. These values are almost an order of magnitude less than those reported by Benna et al. (2015) for CME conditions. Using a Monte Carlo model and assuming the normal solar wind and a photoionization lifetime for Ne of 300 days, our result was more consistent with the Benna (2015) result than our measured result. Two lunations showed an increase in Ne during the night, consistent with the simulation, but two of the lunations showed a decrease in surface number density through the night. We have shown that explaining the Ne distribution is not as simple as assuming dynamic equilibrium with the solar wind and an exosphere accommodated to the local surface temperature.

LACE Data

Exospheric Escape: A Parametrical Study

The study of exospheres can help us understand the long-term loss of volatiles from planetary bodies due to interactions of planets, satellites, and small bodies with the interplanetary medium, solar radiation, and internal forces including diffusion and outgassing. Recent evidence for water and OH on the Moon has spurred interest in processes involving chemistry and sequestration of volatile species at the poles and in voids. In recent years, NASA has sent spacecraft to asteroids including Vesta and Ceres, and ESA sent Rosetta to comet 67P/Churyumov-Gerasimenko and the asteroids Lutetia and Steins. Japan's Hayabusa spacecraft returned a sample from asteroid Itakowa, and OSIRIS-REX will return a sample from a primitive asteroid, Bennu, to Earth. In a surface-bounded exosphere, the gases are derived from the surface and thus reflect the composition of the body's regolith, although not in a one-to-one ratio. Observation of an escaping exosphere, termed a corona, is challenging. We have therefore embarked on a parametrical study of exospheres as a function of mass of the exospheric species, mass of the primary body and source velocity distribution, specifically thermal (Maxwell-Boltzmann) and sputtering. The goal is to provide a quick look to determine under what conditions and for what mass of the primary body the species of interest are expected to be bound or escaping and to quickly estimate the observability of exospheric species. This work does not provide a comprehensive model but rather serves as a starting point for further study. These parameters will be useful for mission planning as well as for students beginning a study of planetary exospheres.

Volatilels

Seasonal Variations of Mercury's Magnesium Dayside Exosphere from MESSENGER Observations

The Ultraviolet and Visible Spectrometer channel of the Mercury Atmospheric and Surface Composition Spectrometer instrument aboard the MErcury Surface, Space ENvironment, GEochemistry, and Ranging spacecraft made near-daily observations of solar-scattered resonant emission from magnesium in Mercury's exosphere during the mission's orbital phase (March 2011-April 2015, approx.17 Mercury years). In this paper, a subset of these data (March 2013-April 2015) is described and analyzed to illustrate Mg's spatial and temporal variations. Dayside altitude profiles of emission are used to make estimates of the Mg density and temperature. The main characteristics of the Mg exosphere are (a) a predominant enhancement of emission in the morning (6 am-10 am) near perihelion, (b) a bulk temperature of approx. 6000 K, consistent with impact vaporization as the predominant ejection process, (c) a near-surface density that varies from 5/cu cm to 50/cu cm and (d) a production rate that is strongest in the morning on the inbound leg of Mercury's orbit with rates ranging from 1×10(exp 5)/sq cm/s to 8×10(exp 5)/sq cm/s.

Ultraviolet

Observations of the Minor Species Al and Fe in Mercury's Exosphere

We report here on the first observational evidence of Al and Fe in the exosphere of Mercury, based on measurements of resolved emission lines of these metals with Keck-1/HIRES. Al emission was observed on two separate runs, in 2008 and 2013, with tangent column densities of 3.1 +/- 1.0 and 4.0 +/-1.5 x 10(exp 7) Al atoms cm(exp - 2) at altitudes of 1185 and 1870 km (1.5 and 1.75 R(sub M). The Al radiative intensity was seen to increase where the slit crossed the planetary penumbral shadow, and then decrease monotonically with altitude. Fe emission has been observed once, in 2009, indicating an extended source. We also present observed 3- Sigma Ca(+) upper limits near Mercury's equatorial anti-solar limb, from which an abundance limit of 4.0 x 10(exp 6) cm(exp -2) at 1650 km altitude is derived for the Ca ion. A simple model for zenith column abundances of the neutral species yields 1.9 -5.2 x 10(exp 7) Al cm(exp -2) , and 8.2 x 10(exp 8) Fe cm(exp -2) . The observations appear to be consistent with production of these species by impact vaporization, with a large fraction of the Al ejecta in molecular form, and that for Fe in mixed atomic and molecular forms. The scale height of the Al gas is consistent with a kinetic temperature of 6100-8000 K. The apparent high temperature and low density of the Al gas would suggest that it may be produced by dissociation of molecules.

Mercury

Contributions of Solar Wind and Micrometeoroids to Molecular Hydrogen in the Lunar Exosphere

We investigate the density and spatial distribution of the H2 exosphere of the Moon assuming various source mechanisms. Owing to its low mass, escape is non-negligible for H2. For high-energy source mechanisms, a high percentage of the released molecules escape lunar gravity. Thus, the H2 spatial distribution for high-energy release processes reflects the spatial distribution of the source. For low energy release mechanisms, the escape rate decreases and the H2 redistributes itself predominantly to reflect a thermally accommodated exosphere. However, a small dependence on the spatial distribution of the source is superimposed on the thermally accommodated distribution in model simulations, where density is locally enhanced near regions of higher source rate. For an exosphere accommodated to the local surface temperature, a source rate of 2.2 g s-1 is required to produce a steady state density at high latitude of 1200 cm-3. Greater source rates are required to produce the same density for more energetic release mechanisms. Physical sputtering by solar wind and direct delivery of H2 through micrometeoroid bombardment can be ruled out as mechanisms for producing and liberating H2 into the lunar exosphere. Chemical sputtering by the solar wind is the most plausible as a source mechanism and would require 10-50 of the solar wind H+ inventory to be converted to H2 to account for the observations.

Impact

Pathways for Energization of Ca in Mercury's Exosphere

We investigate the possible pathways to produce the extreme energy observed in the calcium exosphere of Mercury. Any mechanism must explain the facts that Ca in Mercury's exosphere is extremely hot, that it is seen almost exclusively on the dawnside of the planet, and that its content varies seasonally, not sporadically. Simple diatomic molecules or their clusters are considered, focusing on calcium oxides while acknowledging that Ca sulfides may also be the precursor molecules. We first discuss impact vaporization to justify the assumption that CaO and Ca-oxide clusters are expected from impacts on Mercury. Then we discuss processes by which the atomic Ca is energized to a 70,000 K gas. The processes considered are (1) electron-impact dissociation of CaO molecules, (2) spontaneous dissociation of Ca-bearing molecules following impact vaporization, (3) shock-induced dissociative ionization, (4) photodissociation and (5) sputtering. We conclude that electron-impact dissociation cannot produce the required abundance of Ca, and sputtering cannot reproduce the observed spatial and temporal variation that is measured. Spontaneous dissociation is unlikely to result in the high energy that is seen. Of the two remaining processes, shock induced dissociative ionization produces the required energy and comes close to producing the required abundance, but rates are highly dependent on the incoming velocity distribution of the impactors. Photodissociation probably can produce the required abundance of Ca, but simulations show that photodissociation cannot reproduce the observed spatial distribution.

Sulfides

Impact Vaporization as a Possible Source of Mercury's Calcium Exosphere

Mercury's calcium exosphere varies in a periodic way with that planet's true anomaly. We show that this pattern can be explained by impact vaporization from interplanetary dust with variations being due to Mercury's radial and vertical excursions through an interplanetary dust disk having an inclination within 5 degrees of the plane of Mercury's orbit. Both a highly inclined dust disk and a two-disk model (where the two disks have a mutual inclination) fail to reproduce the observed variation in calcium exospheric abundance with Mercury true anomaly angle. However, an additional source of impacting dust beyond the nominal dust disk is required near Mercury's true anomaly (ν) 25deg +/-5deg. This is close to but not coincident with Mercury's true anomaly (ν=45deg) when it crosses comet 2P/Encke's present day orbital plane. Interestingly, the Taurid meteor storms at Earth, which are also due to Comet Encke, are observed to occur when Earth's true anomaly is +/-20 or so degrees before and after the position where Earth and Encke orbital planes cross. The lack of exact correspondence with the present day orbit of Encke may indicate the width of the potential stream along Mercury's orbit or a previous cometary orbit. The extreme energy of the escaping calcium, estimated to have a temperature greater than 50000 K if the source is thermal, cannot be due to the impact process itself but must be imparted by an additional mechanism such as dissociation of a calcium-bearing molecule or ionization followed by recombination.

Dust

Mercury's Seasonal Sodium Exosphere: MESSENGER Orbital Observations

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) Ultraviolet and Visible Spectrometer (UVVS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft now orbiting Mercury provides the first close-up look at the planet's sodium exosphere. UVVS has observed the exosphere from orbit almost daily for over 10 Mercury years. In this paper we describe and analyze a subset of these data: altitude profiles taken above the low-latitude dayside and south pole. The observations show spatial and temporal variations, but there are no obvious year-to-year variations in most of the observations. We do not see the episodic variability reported by some ground-based observers. We used these altitude profiles to make estimates of sodium density and temperature. The bulk of the exosphere, at about 1200 K, is much warmer than Mercury's surface. This value is consistent with some ground-based measurements and suggests that photon-stimulated desorption is the primary ejection process. We also observe a tenuous energetic component but do not see evidence of the predicted thermalized (or partially thermalized) sodium near Mercury's surface temperature. Overall we do not see the variable mixture of temperatures predicted by most Monte Carlo models of the exosphere.

Environment

Mercury's Seasonal Sodium Exosphere: MESSENGER Orbital Observations

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) Ultraviolet and Visible Spectrometer (UVVS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft now orbiting Mercury provides the first close-up look at the planet's sodium exosphere. UVVS has observed the exosphere from orbit almost daily for over 10 Mercury years. In this paper we describe and analyze a subset of these data: altitude profiles taken above the low-latitude dayside and south pole. The observations show spatial and temporal variation but there is little or no year-to-year variation; we do not see the episodic variability reported by ground-based observers. We used these altitude profiles to make estimates of sodium density and temperature. The bulk of the exosphere is about 1200 K, much warmer than Mercury's surface. This value is consistent with some ground-based measurements and suggests that photon-stimulated desorption is the primary ejection process. We also observe a tenuous energetic component but do not see evidence of the predicted thermalized (or partially thermalized) sodium near Mercury's surface temperature. Overall we do not see the variable mixture of temperatures predicted by most Monte Carlo models of the exosphere.

Exosphere

Seasonal Variations in Mercury's Dayside Calcium Exosphere

The Mercury Atmospheric and Surface Composition Spectrometer on the MESSENGER spacecraft has observed calcium emission in Mercury's exosphere on a near-daily basis since March 2011. During MESSENGER's primary and first extended missions (March 2011 - March 2013) the dayside calcium exosphere was measured over eight Mercury years. We have simulated these data with a Monte Carlo model of exospheric source processes to show that (a) there is a persistent source of energetic calcium located in the dawn equatorial region, (b) there is a seasonal dependence in the calcium source rate, and (c) there are no obvious year-to-year variations in the near-surface dayside calcium exosphere. Although the precise mechanism responsible for ejecting the calcium has not yet been determined, the most likely process is the dissociation of Ca-bearing molecules produced in micrometeoroid impact plumes to form energetic, escaping calcium atoms.

Exosphere

Mercury's Weather-Beaten Surface: Understanding Mercury in the Context of Lunar and Asteroidal Space Weathering Studies

Mercury's regolith, derived from the crustal bedrock, has been altered by a set of space weathering processes. Before we can interpret crustal composition, it is necessary to understand the nature of these surface alterations. The processes that space weather the surface are the same as those that form Mercury's exosphere (micrometeoroid flux and solar wind interactions) and are moderated by the local space environment and the presence of a global magnetic field. To comprehend how space weathering acts on Mercury's regolith, an understanding is needed of how contributing processes act as an interactive system. As no direct information (e.g., from returned samples) is available about how the system of space weathering affects Mercury's regolith, we use as a basis for comparison the current understanding of these same processes on lunar and asteroidal regoliths as well as laboratory simulations. These comparisons suggest that Mercury's regolith is overturned more frequently (though the characteristic surface time for a grain is unknown even relative to the lunar case), more than an order of magnitude more melt and vapor per unit time and unit area is produced by impact processes than on the Moon (creating a higher glass content via grain coatings and agglutinates), the degree of surface irradiation is comparable to or greater than that on the Moon, and photon irradiation is up to an order of magnitude greater (creating amorphous grain rims, chemically reducing the upper layers of grains to produce nanometer scale particles of metallic iron, and depleting surface grains in volatile elements and alkali metals). The processes that chemically reduce the surface and produce nanometer-scale particles on Mercury are suggested to be more effective than similar processes on the Moon. Estimated abundances of nanometer-scale particles can account for Mercury's dark surface relative to that of the Moon without requiring macroscopic grains of opaque minerals. The presence of nanometer-scale particles may also account for Mercury's relatively featureless visible-near-infrared reflectance spectra. Characteristics of material returned from asteroid 25143 Itokawa demonstrate that this nanometer-scale material need not be pure iron, raising the possibility that the nanometer-scale material on Mercury may have a composition different from iron metal [such as (Fe,Mg)S]. The expected depletion of volatiles and particularly alkali metals from solar-wind interaction processes are inconsistent with the detection of sodium, potassium, and sulfur within the regolith. One plausible explanation invokes a larger fine fraction (grain size less than 45 micron) and more radiation-damaged grains than in the lunar surface material to create a regolith that is a more efficient reservoir for these volatiles. By this view the volatile elements detected are present not only within the grain structures, but also as adsorbates within the regolith and deposits on the surfaces of the regolith grains. The comparisons with findings from the Moon and asteroids provide a basis for predicting how compositional modifications induced by space weathering have affected Mercury's surface composition.

Weathering

Modeling MESSENGER Observations of Calcium in Mercury's Exosphere

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MESSENGER spacecraft has made the first high-spatial-resolution observations of exospheric calcium at Mercury. We use a Monte Carlo model of the exosphere to track the trajectories of calcium atoms ejected from the surface until they are photoionized, escape from the system, or stick to the surface. This model permits an exploration of exospheric source processes and interactions among neutral atoms, solar radiation, and the planetary surface. The MASCS data have suggested that a persistent, high-energy source of calcium that was enhanced in the dawn, equatorial region of Mercury was active during MESSENGER's three flybys of Mercury and during the first seven orbits for which MASCS obtained data. The total Ca source rate from the surface varied between 1.2x10(exp 23) and 2.6x10(exp 23) Ca atoms/s, if its temperature was 50,000 K. The origin of this high-energy, asymmetric source is unknown, although from this limited data set it does not appear to be consistent with micrometeoroid impact vaporization, ion sputtering, electron-stimulated desorption, or vaporization at dawn of material trapped on the cold nightside.

Messenger

Mercury's Sodium Exosphere: Observations during the MESSENGER Orbital Phase

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft entered into orbit about Mercury on March 18,2011. We now have approximately five Mercury years of data from orbit. Prior to the MESSENGER mission, Mercury's surface-bounded exosphere was known to contain H, He, Na. K, and Ca. The Ultraviolet and Visible Spectrometer (UVVS) began routine orbital observations of both the dayside and nightside exosphere on March 29. 2011, measuring altitude profiles for all previously detected neutral species except for He and K. We focus here on what we have learned about the sodium exosphere: its spatial, seasonal, and sporadic variation. Observations to date permit delineation of the relative roles of photon-stimulated desorption (PSD) and impact vaporization (IV) from seasonal and spatial effects, as well as of the roles of ions both as sputtering agents and in their possible role to enhance the efficiency of PSD. Correlations of Mercury's neutral sodium exosphere with measurements from MESSENGER's Magnetometer (MAG) and Energetic Particle and Plasma Spectrometer (EPPS) provide insight into the roles of ions and electrons. Models incorporating MAG observations provide a basis for identifying the location and area of the surface exposed to solar wind plasma, and EPPS observations reveal episodic populations of energetic electrons in the magnetosphere and the presence of planetary He(+), 0(+), and Na(+),

Killen, Rosemary M.