Engineering topics

Kim, Sang J.

Publications and source records attributed to Kim, Sang J..

10 records

NASA NTRS1994

(H2)2 mole-fraction altitude profile in the atmosphere of Jupiter: A computational study

The mole fraction x(sub 2) of (H2)2 in equilibrium mixture with H2 under the atmospheric conditions of Jupiter is evaluated from the dimerization equilibrium constant calculated by quantum-chemical treatments and also from the Lennard-Jones potential. The treatments are of an ab initio type with the second and fourth order Moller-Plesset perturbation techniques and a basis set superposition error evaluation. The computed dimerization equilibrium constant is combined with observed height profiles of temperature and pressure. In six treatments considered it is found that the mole fraction decreases with increasing height. Various approximations suggest the dimeric mole fraction at the Jupiter 1 atm pressure level between 0.04 and 1.06%.

Slanina, Zdenek↗

NASA NTRS1993

Spatial and spectral characteristics of the near-infrared aurorae of Jupiter

Data are presented which show the power of a long-slit IR spectrograph to yield spectral and spatial coverage of the Jovian auroral zones in an efficient manner. Strong 3 micron H3(+) lines are observed on the eastern bright spot and moderately strong 3 micron H3(+) lines in the central meridian and western region of the northern aurora. Higher temperatures are found in the central meridian and western region of the northern aurora compared with a temperature of 1000 K +/- K on the eastern bright spot, suggesting an enhanced abundance of H3(+) on the bright spot compared to other auroral regions. The H2 quadrupole lines of Q1(1), Q1(3), S1(1), and several H3(+) lines between 2 and 2.5 microns are identified in the northern auroral region. The eastern bright spot as seen in the 2 micron H2 and H3(+) emission lines is at nearly the same position as the eastern bright spot due to the 3 micron H3(+) fundamental band lines.

Kim, Sang J.↗

NASA NTRS1992

g-factors of the SH (0-0) band and SH upper limit in Comet P/Brorsen-Metcalf (1989o)

A search for SH, the prime dissociative product of H2S, has been prompted by the microwave-band detection of H2S in Comets Austin and Levy. Attention is accordingly given here to g-factors for the A-X (0-0) band of SH as a function of heliocentric velocity at a heliocentric distance of 1 AU. An upper-limit production rate for SH relative to water of 0.017 is derived for the case of Comet P/Brorsen-Metcalf. A dissociative lifetime of 105 sec, at 1 AU heliocentric distance, and a heliocentric velocity of -28.5 km/sec, are also obtained.

Kim, Sang J.↗

NASA NTRS1992

Application of the Stogryn-Hirschfelder treatment of weak dimers to planetary atmospheres

The thermodynamics of carbon dioxide dimerization is treated as an example of the evaluation of weak dimer populations in planetary atmospheres (e.g., Mars and Venus). Two approaches considered are the Stogryn-Hirschfelder (1960) treatment using the Lennard-Jones interaction and calculations based on recent quantum chemical data. Several improvements of these treatments are developed. It is indicated that carbon dioxide dimers may be less or more abundant at the surfaces of Mars or Venus, respectively, than is suggested by previous calculations.

Slanina, Zdenek↗

NASA NTRS1992

g-Factors of the SH (0-0) Band and SH Upper Limit in Comet P/Brorsen-Metcalf (1980o)

Since H2S was detected in Comets Austin (1989cl) and Levy (1990c) in the microwave range, there has been increasing interest in searching for SH, which is the prime dissociative product of H2S. We present g-factors for the A-X (0-0) band of SH as a function of heliocentric velocity at r = 1.0 AU. We derive an upper limit production rate, Q(SH)/Q(H2O) less than 0.017, for Comet Brorsen-Metcalf (1989o) and calculate a dissociative lifetime of 105 sec at a heliocentric distance, r = 1.0 AU, and at a heliocentric velocity, v(r) = -28.5 km/sec.

Kim, Sang J.↗

NASA NTRS1991

The 2-micron polar haze of Jupiter

Model spectra have been constructed for the CH4 lines of the polar regions of Jupiter in such as way as to encompass the hydrogen pressure-induced opacity and haze layers revealed by high-resolution spectroscopy. Comparisons between observation and model spectra indicate that, for optically thin haze models, the polar haze is primarily located between the 70 and 5 mbar pressure levels; for opaque haze models, the top of the haze layers lies in the vicinity of the 15-mbar level. It is concluded that the polar haze is widely distributed over both polar regions and exhibits no strong correlation with auroral activities.

Kim, Sang J.↗

NASA NTRS1991

Upper Limits of SO AND SO2 in Comets

We have calculated synthetic spectra of SO and compared them with spectra of Comets I-A-A and P/Halley, in which Wallis and Krishna-Swamy claimed a tentative identification of SO. We found no evidence for the presence of So in these spectra. The derived upper limits on the production rates of SO and S02 in Comet I-A-A were found to be at least 50 times less than the S2 production rate. We also found that the SO and S02 upper limits in Comets P/Halley, P/Encke, and Bradfield (1979X) were less than the S2 abundance, reported in Comet IRAS-Araki-Alcock. Our result, contradict recent irradiation experiments, which produced abundant SO compared with S2 under most circumstances. This may suggest totally different models of the S2 producing mechanism in comets.

Kim, Sang J.↗

NASA NTRS1988

Infrared processes in the Jovian auroral zone

In the present theoretical model of the Jovian auroral zone's CH4 and H2 vibrational excitation and deexitation processes, the calculation of the emission intensities of nu3 and nu4 bands of CH3 assume that electrons are the bombarding particles. The most uncertain part of the model calculation involves the energy flux spectrum of incident electrons on the auroral zone. Comparisons with Voyager 1 IRIS observations indicate a domination of the nonthermal, directly or indirectly particle bombardment-derived emission by the thermal emission of the CH4 band.

Kim, Sang J.↗

NASA NTRS1988

Spectra of van der Waals complexes (dimers) with applications to planetary atmospheres

Spectral features observed in the atmosphere of Titan by the Voyager IR experiment have been attributed to weakly bound complexes of N2 and H2, dominant and minor constituents, respectively. The abundance of H2-N2 dimers there was computed. Current calculations include quantitative spectral line positions and intensities for N2-Ar and CO2-CO2 relating to Titan and Earth, and to Mars and Venus, respectively. This work suggests applications to spectra of planetary atmospheres obtained in spacecraft missions.

Fox, Kenneth↗

NASA NTRS1988

Data catalog series for space science and applications flight missions. Volume 5A: Descriptions of astronomy, astrophysics, and solar physics spacecraft and investigations. Volume 5B: Descriptions of data sets from astronomy, astrophysics, and solar physics spacecraft and investigations

The main purpose of the data catalog series is to provide descriptive references to data generated by space science flight missions. The data sets described include all of the actual holdings of the Space Science Data Center (NSSDC), all data sets for which direct contact information is available, and some data collections held and serviced by foreign investigators, NASA and other U.S. government agencies. This volume contains narrative descriptions of data sets of astronomy, astrophysics, solar physics spacecraft and investigations. The following spacecraft series are included: Mariner, Pioneer, Pioneer Venus, Venera, Viking, Voyager, and Helios. Separate indexes to the planetary and interplanetary missions are also provided.

Kim, Sang J.↗