Search NASA⌕ Search

Engineering topics

King, Trude V. V.

Publications and source records attributed to King, Trude V. V..

Initial vegetation species and senescience/stress indicator mapping in the San Luis Valley, Colorado using imaging spectrometer data

We analyzed AVIRIS data obtained over agricultural areas in the San Luis Valley of Colorado. The data were acquired on September 3, 1993. A combined method of radiative transfer modeling and ground calibration site reflectance was used to correct the flight data to surface reflectance. This method, called Radiative Transfer Ground Calibration, or RTGC, corrects for variable water vapor in the atmosphere and produces spectra free of artifacts with spectral channel to channel noise approaching the signal to noise of the raw data. The calibration site soil samples were obtained on the day of the overflight and measured on our laboratory spectrometer. The site was near the center of the AVIRIS scene and the spectra of the soil is spectrally bland, especially in the region of the chlorophyll absorption in the visible portion of the spectrum. The center of the scene is located at approximately 106 deg 03' longitude, 37 deg 23' latitude, and the scene covers about 92 square kilometers. This scene is one of 28 in the area for a general project to study the Summitville abandoned mine site, located in the mountains west of the San Luis Valley, and its effects on the surrounding environment.

Clark, Roger N.↗

Remote mineral mapping using AVIRIS data at Summitville, Colorado and the adjacent San Juan Mountains

We have demonstrated the unique utility of imaging spectroscopy in mapping mineral distribution. In the Summitville mining region we have shown that the mine site does not contribute clay minerals to the Alamosa River, but does contribute Fe-bearing minerals. Such minerals have the potential to carry heavy metals. This application illustrates only one specific environmental application of imaging spectroscopy data. For instance, the types of minerals we can map with confidence are those frequently associated with environmental problems related to active and abandoned mine lands. Thus, the potential utility of this technology to the field of environmental science has yet to be fully explored.

King, Trude V. V.↗

Hydrous carbonates on Mars? Evidence from Mariner 6/7 infrared spectrometer and ground-based telescopic spectra

Absorption features at 2.28 and 5.4 micrometers identified in Mariner 6/7 infrared spectrometer and terrestrial telescopic spectra are consistent with the spectra of hydrous magnesium carbonates such as hydromagnesite and artinite. Spectral characteristics of these hydrous carbonates are different from those of the anhydrous carbonates, as the former do not have the strong spectral features typically associated with anhydrous carbonates such as calcite and siderite. Theoretical mixing indicates that, depending on the type of hydrous carbonate, 10-20 wt % can be incorporated into the regolith without contradicting the spectral observations or the Viking x ray fluorescence chemical analysis. Hydrous carbonates form as weathering products of mafic minerals in the presence of H2O and CO2, even in the Antarctic. Their formation as evaporite minerals from either original magmas or hydrothermally altered rocks is consistent with the Martian environment, provided liquid water is or has been at least transiently present. On Earth, formation of hydrous Mg carbonates is associated with the production of amorphous iron oxides, which is consistent with both the environment and the inferred surface mineralogy of Mars. These minerals are about 60 wt % H2O, CO3, and OH; if they are abundant everywhere at the 10% level, then about 6% of the surface weight could be volatiles bound in this type of mineral. Although the spectroscopic evidence for anhydrous carbonates is scant, the possible presence of hydrous carbonates provides an appealing mechanism for the existence of carbonates on Mars.

Calvin, Wendy M.↗

The US Geological Survey, digital spectral reflectance library: version 1: 0.2 to 3.0 microns

We have developed a digital reflectance spectral library, with management and spectral analysis software. The library includes 500 spectra of 447 samples (some samples include a series of grain sizes) measured from approximately 0.2 to 3.0 microns. The spectral resolution (Full Width Half Maximum) of the reflectance data is less than or equal to 4 nm in the visible (0.2-0.8 microns) and less than or equal 10 nm in the NIR (0.8-2.35 microns). All spectra were corrected to absolute reflectance using an NBS Halon standard. Library management software lets users search on parameters (e.g. chemical formulae, chemical analyses, purity of samples, mineral groups, etc.) as well as spectral features. Minerals from sulfide, oxide, hydroxide, halide, carbonate, nitrate, borate, phosphate, and silicate groups are represented. X-ray and chemical analyses are tabulated for many of the entries, and all samples have been evaluated for spectral purity. The library also contains end and intermediate members for the olivine, garnet, scapolite, montmorillonite, muscovite, jarosite, and alunite solid-solution series. We have included representative spectra of H2O ice, kerogen, ammonium-bearing minerals, rare-earth oxides, desert varnish coatings, kaolinite crystallinity series, kaolinite-smectite series, zeolite series, and an extensive evaporite series. Because of the importance of vegetation to climate-change studies we have include 17 spectra of tree leaves, bushes, and grasses.

Clark, Roger N.↗

Evidence for ammonium-bearing minerals on Ceres

Spectra obtained from recent telescopic observation of 1-Ceres and laboratory measurements and theoretical calculations of three component mixtures of Ceres analog material suggest that an ammoniated phyllosilicate is present on the surface of the asteroid, rather than H2O frost as had been previously reported. The presence of an ammoniated phyllosilicate, most likely ammoniated saponite, on the surface of Ceres implies that secondary temperatures could not have exceeded 400 Kelvin.

King, Trude V. V.↗

High spectral resolution reflectance spectroscopy of minerals

The reflectance spectra of minerals are studied as a function of spectral resolution in the range from 0.2 to 3.0 microns. Selected absorption bands were studied at resolving powers as high as 2240. At resolving powers of approximately 1000, many OH-bearing minerals show diagnostic sharp absorptions at the resolution limit. At low resolution, some minerals may not be distinguishable, but as the resolution is increased, most can be easily identified. As the resolution is increased, many minerals show fine structure, particularly in the OH-stretching overtone region near 1.4 micron. The fine structure can enhance the ability to discriminate between minerals, and in some cases the fine structure can be used to determine elemental composition.

Clark, Roger N.↗

Spectral characteristics of chlorites and Mg-serpentines using high-resolution reflectance spectroscopy

High-resolution reflectance spectroscopy is used to determine the spectral characteristics of serpentines and chlorites. The structure and chemistry of hydrous layered silicates are reviewed. The possibility of distinguishing between isochemical end-members of the Mg-rich serpentine group and the capability of recognizing spectral variations in chlorites as a function of Fe/Mg ratio are demonstrated. Consideration is given to the application of the findings to terrestrial, asteroid, and meteorite studies.

King, Trude V. V.↗

Calibration and evaluation of AVIRIS data: Cripple Creek in October 1987

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were obtained over Cripple Creek and Canon City Colorado on October 19, 1987 at local noon. Multiple ground calibration sites were measured within both areas with a field spectrometer and samples were returned to the laboratory for more detailed spectral characterization. The data were used to calibrate the AVIRIS data to ground reflectance. Once calibrated, selected spectra in the image were extracted and examined, and the signal to noise performance was computed. Images of band depth selected to be diagnostic of the presence of certain minerals and vegetation were computed. The AVIRIS data were extremely noisy, but images showing the presence of goethite, kaolinite and lodgepole pine trees agree with ground checks of the area.

Clark, Roger N.↗

Relation of the spectroscopic reflectance of olivine to mineral chemistry and some remote sensing implications

High-resolution visible and near-IR diffuse spectral reflectance are used to systematically investigate apparent wavelength shifts as a function of mineral chemistry in the Fe/Mg olivine series from Fo(11) to Fo(91). The study also shows that trace amounts of nickel can be spectrally detected in the olivine structure. Significant compositional information can only be extracted at relatively high resolution, because the overall spectral characteristics of the olivines change only subtly as a function of the Fe/Mg ratio. This laboratory study is expected to aid in the interpretation of remotely sensed data from both terrestrial and extraterrestrial bodies. Terrestrial applications may include the recognition of ultramafic, ultrabasic, and basaltic terrains which in themselves may have mineral potential. Among extraterrestrial applications, the asteroids are obvious candidates for further examination. Some permutations of Fe-Mg-Ni relations in olivines are discussed as they apply to the interpretation of asteroid surfaces and other extraterrestrial bodies.

King, Trude V. V.↗

Causes of spurious features in spectral reflectance data

Several techniques are becoming common in the analysis of imaging spectrometer data that can lead to spurious absorption features or to changes in the position, width, and shape of actual absorption features. It is a common practice to calibrate AIS or other imaging spectrometer data by averaging each pixel along the flight line. The average is used to calibrate the spectral data by dividing the spectrum at each pixel by the average. If some pixels in the data set contain an absorption, then the average will also show an absorption. Some AIS data has had problems with wavelength stability from one scan line to the next which can produce spurious features with some analysis methods. If a pixel has a spectrum with an absorption having a different position or width than the spectrum used in a ratio, then the ratio can produce a spurious absorption at a different position and width than the true absorption feature. An average spectrum ratioed to each pixel will produce band shifts, and changes in width or shape. If continuum removal is performed by substraction rather than division, band positions can also be shifted.

Clark, Roger N.↗

Automatic continuum analysis of reflectance spectra

A continuum algorithm based on a Segmented Upper Hull method (SUH) is described. An upper hull is performed on segments of a spectrum defined by local minima and maxima. The segments making a complete spectrum are then combined. The definition of the upper hull allows the continuum to be both concave and/or convex, adapting to the shape of the spectrum. The method performs multiple passes on a spectrum by segmenting each local maximum to minimum and performing an upper hull. The algorithm naturally adapts to the widths of absorption features, so that all features are found, including the nature of doublets, triplets, etc. The algorithm is also reasonably fast on common minicomputers so that it might be applied to the large data sets from imaging spectrometers.

Clark, Roger N.↗