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Kleiner, I.

Publications and source records attributed to Kleiner, I..

Exponential Sum Absorption Coefficients of Phosphine from 2750 to 3550/cm for Application to Radiative Transfer Analyses on Jupiter and Saturn

PH3 exponential sum k coefficients were computed between 2750 and 3550/cm (2.82-3.64 (microns), in view of future application to radiative transfer analyses of Jupiter and Saturn in a phosphine absorption band near 3 microns. The temperature and pressure of this data set cover the ranges from 80 to 350 K and from 10 (exp -3)to 10(exp 1) bars, respectively. Transmission uncertainty incurred by the use of the k coefficients is smaller than a few percent as long as the radiation is confined above an altitude of a few bars in the giant planets. In spectral regions of weak absorption at high pressures close to 10 bars, contributions from far wings of strong absorption lines must be carefully taken into account. Our data set helps map the three-dimensional distribution of PH3 on the giant planets, revealing their global atmospheric dynamics extending down to the deep interior. The complete k coefficient data set of this work is available at the Web site of the NASA Planetary Data System Atmospheres Node.

phosphine↗

Positions and Intensities in the 2v4/v1/v3 Vibrational System of 14NH3 near 3 mu m

Line positions and line intensities of the v1, v3 and 2V4 bands of 14NH3 were analyzed using line positions from 0.0054 cm-1 apodized resolution FT spectra recorded at Orsay and using line intensities from 0.011 cm-1 unapodized resolution FT spectra recorded at Kitt peak National Observatory. The theoretical model and the set of programs developed for treating the infrared system v1/v3/2v4 of ammonia are briefly discussed.

ammonia Jupiter infrared mapping↗

Positions and Intensities in the 3v2/v2+v4 Vibrational System of 14NH3 Near 4 micron meters

Ammonia is the fourth most abundant constituent in the atmospheres of Jupiter and Saturn, after hydrogen, helium and methane. This relative abundance is attested by the presence in the infrared planetary spectra of many absorption features observed in the range of fundamental bands and also in the higher bands. Reported are experimental line positions and intensities of selected ammonia bands.

ammonia Jupiter Saturn spectroscopy planetary gass↗

The laboratory spectrum of acetaldehyde at 1 millimeter (230-325 GHz)

The rotational spectrum of acetaldehyde (CH3CHO) in the frequency range 230-325 GHz has been measured in the laboratory using millimeter/submillimeter direct absorption spectroscopy. Over 250 transition frequencies are presented for this molecule for both A and E symmetry species in its ground (upsilon(sub t) = 0) and first excited (upsilon(sub t) = 1) torsional state, with experimental uncertainties of +/- 50 kHz. The data were fitted with a model involving an internal rotation potential function, which typically reproduces the measured frequencies to nu(sub obs) - nu(sub calc) less than or approximately 50 kHz for both ground and upsilon(sub t) = 1 state. These newly measured rest frequencies should aid in the identification of interstellar CH3CHO and in spectral line assignments for millimeter-band scans.

Barclay, W. L., Jr.↗