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Klima, R. L.

Publications and source records attributed to Klima, R. L..

Geochemical Advances in Mercury Science Facilitated by a Landed Mission

The data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft have revealed several surprising characteristics about the surface of Mercury, leading to its classification as a geochemical endmember among the terrestrial planets. Some of these features include elevated abundances of up to 3 wt% S, C enrichment as high as 4 wt% over the local mean in low reflectance materials (LRM), Na up to 5 wt% at high northern latitudes, and Fe abundances typically lower than 2 wt% [e.g., 1–4]. The S and Fe concentrations have been used to infer that Mercury’s igneous history evolved under highly reduced oxygen fugacity conditions between 2.6 and 7.3 log10 units below the iron-wüstite buffer [e.g., 5], which is more reducing than any other terrestrial planet in the solar system [e.g., 6]. This highly reduced nature has important consequences for the differentiation and thermal/magmatic evolution of Mercury. While the immense amount of data collected by MESSENGER revealed Mercury as a geochemical endmember, this new knowledge gained raised additional questions that necessitate continued exploration of the planet. Fortunately, BepiColombo launched in October of 2018, and this joint ESA/JAXA dual-orbiter spacecraft is the most ambitious effort yet attempted to explore Mercury [e.g., 7]. Looking beyond BepiColombo, there are major aspects of Mercury’s geochemical character and evolution for which significant knowledge gaps can be dramatically improved with data acquired from the planet’s surface via in situ landed science.

Vander Kaaden, K. E.↗

A Mercury Lander Mission Concept Study for the Next Decadal Survey

Mariner 10 provided our first closeup reconnaissance of Mercury during its three flybys in 1974 and 1975. MESSENGER’s 2011–2015 orbital investigation enabled numerous discoveries, several of which led to substantial or complete changes in our fundamental understanding of the planet. Among these were the unanticipated, widespread presence of volatile elements (e.g., Na, K, S); a surface with extremely low Fe abundance whose darkening agent is likely C; a previously unknown landform—hollows— that may form by volatile sublimation from within rocks exposed to the harsh conditions on the surface; a history of expansive effusive and explosive volcanism; substantial radial contraction of the planet from interior cooling; offset of the dipole moment of the internal magnetic field northward from the geographic equator by ~20% of the planet’s radius; crustal magnetization, attributed at least in part to an ancient field; unexpected seasonal variability and relationships among exospheric species and processes; and the presence in permanently shadowed polar terrain of water ice and other volatile materials, likely to include complex organic compounds. Mercury’s highly chemically reduced and unexpectedly volatile-rich composition is unique among the terrestrial planets and was not predicted by earlier hypotheses for the planet’s origin. As an end-member of terrestrial planet formation, Mercury holds unique clues about the original distribution of elements in the earliest stages of the Solar System and how planets (and exoplanets) form and evolve in close proximity to their host stars. The BepiColombo mission promises to expand our knowledge of this planet and to shed light on some of the mysteries revealed by the MESSENGER mission. However, several fundamental science questions raised by MESSENGER’s pioneering exploration of Mercury can only be answered with in situ measurements from the planet’s surface.

Ernst, C. M.↗

Identifying and Characterizing Impact Melt Outcrops in the Nectaris Basin

The Nectaris Basin is an 820-km diameter, multi-ring impact basin located on the near side of the Moon. Nectaris is a defining stratigraphic horizon based on relationships between ejecta units, giving its name to the Nectarian epoch of lunar history. Lunar basin chronology based on higher resolution LRO imagery and topography, while assigning some important basins like Serenitatis to pre-Nectarian time, were generally consistent with those previously derived. Based on this stratigraphy, at least 11 large basins formed in the time between Nectaris and Imbrium. The absolute age of Nectaris, therefore, is a crucial marker in the lunar time-stratigraphic sequence for understanding the impact flux on the Moon, and by extension, the entire inner solar system. For several decades, workers have attempted to constrain the age of the Nectaris basin through radiometric dating of lunar samples. However, there is little agreement on which samples in our collection represent Nectaris, if any, and what the correct radiometric age of such samples is. The importance of the age of Nectaris goes far beyond assigning a stratigraphic marker to lunar chronology. Several dynamical models use Nectaris as their pin date, so that this date becomes crucial in understanding the time-correlated effects in the rest of the solar system. The importance of the Nectaris basin age, coupled with its nearside, mid-latitude location, make remnants of the impact-melt sheet an attractive target for a future mission, either for in-situ dating or for sample return. We have started exploring this possibility. We have begun a consortium data-analysis effort bringing multiple datasets and analysis methods to bear on these putative impact-melt deposits to characterize their extent, elemental composition and mineralogy, maturity and geologic setting, and to identify potential landing sites that meet both operational safety and science requirements.

Nectaris Basin↗

Pyroxene Spectroscopy: Effects of Major Element Composition on Near, Mid and Far-Infrared Spectra

Pyroxene is one of the most common minerals in both evolved and undifferentiated solid bodies of the solar system. Various compositions of pyroxene have been directly studied in meteorites and lunar samples and remotely observed by telescopic and orbital measurements of the moon, Mars, Mercury, and several classes of asteroids. Laboratory studies of pyroxene spectra have shown that absorption features diagnostic of pyroxene in both the near and mid infrared are composition dependent. The challenge for remote analyses has been to reduce the level of ambiguity to allow a quantitative assessment of mineral chemistry. This study focuses on the analysis of a comprehensive set of synthetic Ca-Fe-Mg pyroxenes from the visible through far-IR (0.3-50 m) to address the fundamental constraints of crystal structure on absorption.

Klima, R. L.↗

Capabilities and Limitations of Infrared Reflectance Microspectroscopy

Technological improvements in IR microspectroscopy have made it an increasingly appealing tool for planetary mineralogy. Microspectroscopy presents the prospect of examining small samples nondestructively and acquiring spectra that can be related to remote sensing observations. However, complications are introduced as a target beam size is reduced, and it is critical that limitations are understood. We present the results of a series of well constrained spectroscopic measurements, linking microspectroscopic data to traditionally collected reflectance spectra and petrologic information for the same rock.

Klima, R. L.↗