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Kramarova, Natalya A.

Publications and source records attributed to Kramarova, Natalya A..

Trends in Global Tropospheric Ozone Inferred from a Composite Record of TOMS/OMI/MLS/OMPS Satellite Measurements and the MERRA-2 GMI Simulation

Past studies have suggested that ozone in the troposphere has increased globally throughout much of the 20th century due to increases in anthropogenic emissions and transport. We show, by combining satellite measurements with a chemical transport model, that during the last four decades tropospheric ozone does indeed indicate increases that are global in nature, yet still highly regional. Satellite ozone measurements from Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) are merged with ozone measurements from the Aura Ozone Monitoring Instrument/Microwave Limb Sounder (OMI/MLS) to determine trends in tropospheric ozone for 1979–2016. Both TOMS (1979–2005) and OMI/MLS (2005–2016) depict large increases in tropospheric ozone from the Near East to India and East Asia and further eastward over the Pacific Ocean. The 38-year merged satellite record shows total net change over this region of about +6 to +7 Dobson units (DU) (i.e., ∼15 %–20 % of average background ozone), with the largest increase (∼4 DU) occurring during the 2005–2016 Aura period. The Global Modeling Initiative (GMI) chemical transport model with time-varying emissions is used to aid in the interpretation of tropospheric ozone trends for 1980–2016. The GMI simulation for the combined record also depicts the greatest increases of +6 to +7 DU over India and East Asia, very similar to the satellite measurements. In regions of significant increases in tropospheric column ozone (TCO) the trends are a factor of 2–2.5 larger for the Aura record when compared to the earlier TOMS record; for India and East Asia the trends in TCO for both GMI and satellite measurements are ∼+3 DU decade(exp −1) or greater during 2005–2016 compared to about +1.2 to +1.4 DU decade(exp −1) for 1979–2005. The GMI simulation and satellite data also reveal a tropospheric ozone increases in ∼+4 to +5 DU for the 38-year record over central Africa and the tropical Atlantic Ocean. Both the GMI simulation and satellite-measured tropospheric ozone during the latter Aura time period show increases of ∼+3 DU decade−1 over the N Atlantic and NE Pacific.

Ziemke, Jerald R.↗

Long-Term Ozone Variability and Trends from Reanalyses: Can It Be Done?

Stratospheric ozone concentrations have begun to show early signs of recovery following the implementation of the Montreal Protocol and its amendments as well as in response to decreasing upper-stratospheric temperatures. Secular trends in stratospheric ozone are modulated by considerable interannual variability and systematic changes in transport patterns that are expected under increasing concentrations of greenhouse gases, especially in the lower stratosphere. These factors necessitate the continued close monitoring of stratospheric ozone in upcoming decades, with a special focus on the lower stratosphere.As highly resolved data sets combining a plethora of observations with model simulations atmospheric reanalyses are, in principle, well suited for the task. All major reanalyses generate ozone output. However, significant spurious discontinuities that arise from step changes in the observing systems prevent a straightforward analysis of ozone trends and long-term variability. Building on our recent work, in this presentation we will demonstrate that trend detection is nonetheless possible using the ozone record from NASA's MERRA-2 (Modern-Era Retrospective Analysis for Research and Applications, Version 2) reanalysis bias-corrected using a chemistry model simulation as a transfer function. Next, we will outline several strategies to reduce artificial discontinuities in the ozone record in future NASA reanalyses. This discussion will be illustrated by an example of joint assimilation of bias-corrected ozone profiles from the Microwave Limb Sounder (MLS) on the Aura satellite (2004 to present) and the Ozone Mapping Profiler Suite Limb Profiler (OMPS-LP) sensors that are expected to operate on future NOAA platforms.

Wargan, Krzysztof↗

Validation of Ozone Profile Retrievals Derived from the OMPS LP Version 2.5 Algorithm Against Correlative Satellite Measurements

The Limb Profiler (LP) is a part of the Ozone Mapping and Profiler Suite launched on board of the Suomi NPP satellite in October 2011. The LP measures solar radiation scattered from the atmospheric limb in ultraviolet and visible spectral ranges between the surface and 80 km. These measurements of scattered solar radiances allow for the retrieval of ozone profiles from cloud tops up to 55 km. The LP started operational observations in April 2012. In this study we evaluate more than 5.5 years of ozone profile measurements from the OMPS LP processed with the new NASA GSFC version 2.5 retrieval algorithm. We provide a brief description of the key changes that had been implemented in this new algorithm, including a pointing correction, new cloud height detection, explicit aerosol correction and a reduction of the number of wavelengths used in the retrievals. The OMPS LP ozone retrievals have been compared with independent satellite profile measurements obtained from the Aura Microwave Limb Sounder (MLS), Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) and Odin Optical Spectrograph and InfraRed Imaging System (OSIRIS). We document observed biases and seasonal differences and evaluate the stability of the version 2.5 ozone record over 5.5 years. Our analysis indicates that the mean differences between LP and correlative measurements are well within required +/- 10% between 18 and 42 km. In the upper stratosphere and lower mesosphere (>43 km) LP tends to have a negative bias. We find larger biases in the lower stratosphere and upper troposphere, but LP ozone retrievals have significantly improved in version 2.5 compared to version 2 due to the implemented aerosol correction. In the northern high latitudes we observe larger biases between 20 and 32 km due to the remaining thermal sensitivity issue. Our analysis shows that LP ozone retrievals agree well with the correlative satellite observations in characterizing vertical, spatial and temporal ozone distribution associated with natural processes, like the seasonal cycle and quasi-biennial oscillations. We found a small positive drift approx. 0.5%/yr in the LP ozone record against MLS and OSIRIS that is more pronounced at altitudes above 35 km. This pattern in the relative drift is consistent with a possible 100m drift in the LP sensor pointing detected by one of our altitude-resolving methods.

Ozone Mapping↗

Estimating Uncertainties in the SBUV Version 8.6 Merged Profile Ozone Data Set

The combined record of total and profile ozone measurements from the solar backscatter ultraviolet (SBUV) and SBUV/2 series of instruments, known as the SBUV Merged Ozone Data (MOD) product, constitutes the longest satellite-based ozone time series from a single instrument type and as such plays a key role in ozone trend analyses. Following the approach documented in Frith et al. (2014) to analyze the merging uncertainties in the MOD total ozone record, we use Monte Carlo simulations to estimate the potential for uncertainties in the calibration and drift of individual instruments in the profile ozone merged data set. We focus our discussion on the trends and associated merging uncertainty since 2001 in an effort to verify the start of ozone recovery as predicted by chemistry climate models. We find that merging uncertainty dominates the overall estimated uncertainty when considering only the 15 years of data since 2001. We derive trends versus pressure level for the MOD data set that are positive in the upper stratosphere as expected for ozone recovery. These trends appear to be significant when only statistical uncertainties are included but become not significant at the 2o level when instrument uncertainties are accounted for. However, when we use the entire data set from 1979 through 2015 and fit to the EESC (equivalent effective stratospheric chlorine) we find statistically significant fits throughout the upper stratosphere at all latitudes. This implies that the ozone profile data remain consistent with our expectation that chlorine is the dominant ozone forcing term.

Ozone profile↗