Kuan, Y. -J. | Search NASA

NASA NTRS2017

Deep K-Band Observations of TMC-1 with the Green Bank Telescope: Detection of HC7O, Nondetection of HC11N, and a Search for New Organic Molecules

The 100-meter Robert C. Byrd Green Bank Telescope K-band (KFPA) receiver was used to perform a high-sensitivity search for rotational emission lines from complex organic molecules in the cold interstellar medium toward TMC-1 (Taurus Molecular Cloud - cyanopolyyne peak), focussing on the identification of new carbon-chain-bearing species as well as molecules of possible prebiotic relevance. We report a detection of the carbon-chain oxide species HC7O and derive a column density of (7.8 plus or minus 0.9) times 10 (sup 11) per square centimeter. This species is theorized to form as a result of associative electron detachment reactions between oxygen atoms and C7H minus, and/or reaction of C6H2 plus with CO (followed by dissociative electron recombination). Upper limits are given for the related HC6O, C6O, and C7O molecules. In addition, we obtained the first detections of emission from individual (sup 13) C isotopologues of HC7N, and derive abundance ratios HC7N/HCCCC (sup 13) CCCN equal to 110 plus or minus 16 and HC7N/HCCCC (sup 13) CCCN equal to 96 plus or minus 11, indicative of significant (sup 13) C depletion in this species relative to the local interstellar elemental (sup 12) C divided by (sup 13) C ratio of 60-70. The observed spectral region covered two transitions of HC11N, but emission from this species was not detected, and the corresponding column density upper limit is 7.4 times 10 (sup 10) per square centimeter (at 95 percent confidence). This is significantly lower than the value of 2.8 times 10 (sup 11) per square centimeter previously claimed by Bell et al. and conï¬rms the recent nondetection of HC11N in TMC-1 by Loomis et al. Upper limits were also obtained for the column densities of malononitrile and the nitrogen heterocycles quinoline, isoquinoline, and pyrimidine.

ISM: abundances, ISM: lines and bands, ISM: molecu↗

NASA NTRS2012

Ground-Based Centimeter, Millimeter, and Submillimeter Observations of Recent Comets

Comets provide important clues to the physical and chemical processes that occurred during the formation and early evolution of the Solar System, and could also have been important for initiating prebiotic chemistry on the early Earth [I]. Comets are comprised of molecular ices, that may be pristine interstellar remnants of Solar System formation, along with high-temperature crystalline silicate dust that is indicative of a more thermally varied history in the protosolar nebula [2]. Comparing abundances of cometary parent volatiles, and isotopic fractionation ratios, to those found in the interstellar medium, in disks around young stars, and between cometary families, is vital to understanding planetary system formation and the processing history experienced by organic matter in the so-called interstellar-comet connection [3]. In the classical picture, the long-period comets probably formed in the nebular disk across the giant planet formation region (5-40 AU) with the majority of them originating from the Uranus-Neptune region. They were subsequently scattered out to the Oort Cloud (OC) by Jupiter. The short-period comets (also known as ecliptic or Jupiter Family Comets - JFC) reside mainly in the Edgeworth-Kuiper belt where they were formed. Given the gradient in physical conditions expected across this region of the nebula, chemical diversity in this comet population is to be expected [4,5]. We have conducted observations of comets I 03P/Hartley 2 (JFC) and C/2009 PI (Garradd) (OC), at primarily millimeter and submillimeter wavelengths, to determine important cosmogonic quantities, such as the ortho:para ratio and isotope ratios, as well as probe the origin of cometary organics and if they vary between the two dynamic reservoirs.

Milam, S. N.↗