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Kuhl, A. L.

Publications and source records attributed to Kuhl, A. L..

Explosion-induced ignition and combustion of acetylene clouds

We investigate the explosion-induced ignition and combustion of an acetylene cloud in a rectangular chamber (10 cm × 10 cm × 39 cm). In the experiments, a 0.2-g PETN charge was located at $x = 9.7\,\hbox {cm}$ and a soap bubble (d=5cm) filled with pure acetylene was located at $x = 27\,\hbox {cm}$ as measured relative to the end wall. Detonation of the charge created a blast wave that crushed the soap bubble—inducing mixing with the air. After 0.55 ms, the mixture ignited, forming at turbulent combustion cloud. The flow was modeled using the compressible Navier–Stokes equations assuming unity Lewis number. Arrhenius-based kinetics were used to model ignition. Adaptive mesh refinement was used to capture turbulent mixing on the grid (the MILES approach of J. Boris). Computed pressures were found to be in agreement with measured pressure histories. Finite-rate kinetics were required to capture the ignition processes over the duration of the experiment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comparison of Bacillus atrophaeus spore viability following exposure to detonation of C4 and to deflagration of halogen-containing thermites

Energetic materials are being considered for the neutralization of spore-forming bacteria. In this study, the neutralization effects of a monomolecular explosive were compared to the effects of halogen-containing thermites. Bacillus atrophaeus spores were exposed to the post-detonation environment of a 100 g charge of the military explosive C-4 at a range of 50 cm. These tests were performed in the thermodynamically closed environment of a 506-l barometric calorimeter. Associated temperatures were calculated using a thermodynamic model informed by calculations with the Cheetah thermochemical code. Temperatures in the range of 2300–2800 K were calculated to persist for nearly the full 4 ms pressure observation time. After the detonation event, spores were characterized using optical microscopy and the number of viable spores was assessed. Results showed live spore survival rates in the range of 0.01%–1%. For the thermite tests, a similar, smaller-scale configuration was employed that examined the spore neutralization effects of two thermites: aluminum with iodine pentoxide and aluminum with potassium chlorate. Only the former mixture resulted in spore neutralization. These results indicate that the detonation environment produced by an explosive with no chemical biocides may provide effective spore neutralization similar to a deflagrating thermite containing iodine.

36 MATERIALS SCIENCE↗

Pressure waves generated by steady flames.

Analysis of pressure waves that can be generated by clouds of explosive gas mixtures in a free atmosphere which is initially at a uniform state. The treatment is restricted only to the final stage of constant flame velocity when the flowfield is self-similar. By the introduction of reduced blast-wave parameters as phase-plane coordinates, the problem is resolved into the determination of the appropriate integral curves on this plane. Results, including space profiles of gasdynamic parameters, have been computed for a specific case of a hydrocarbon-air mixture characterized by a specific heat ratio of 1.3, sound speed at NTP of 345 m/sec, and volumetric expansion ratio corresponding to constant pressure deflagration of 7. Maximum overpressure ratios that can be generated by such flames in point-and line-symmetrical waves range from .00053, for the lower bound in the burning speed, up to 6 for the deflagration, while, for the average speeds of 5 to 10 m/sec, they are at a level of 0.05 to 0.10.

Kuhl, A. L.↗

On self-similar blast waves headed by the Chapman-Jouguet detonation.

Consideration of the whole class of self-similar solutions for blast waves bounded by Chapman-Jouguet detonations that propagate into a uniform, quiescent, zero counterpressure atmosphere of a perfect gas with constant specific heats. Since such conditions can be approached quite closely by some actual chemical systems at NTP, this raises the interesting possibility of the existence of Chapman-Jouguet detonations of variable velocity. The principal virtue of the results presented is, however, more of theoretical significance. They represent the limiting case for all the self-similar blast waves headed by gasdynamic discontinuities associated with a deposition of finite amounts of energy, and they exhibit some unique features owing to the singular nature of the Chapman-Jouguet condition.

Oppenheim, A. K.↗

A parametric study of self-similar blast waves.

Comprehensive examination of self-similar blast waves with respect to two parameters, one describing the front velocity and the other the variation of the ambient density immediately ahead of the front. All possible front trajectories are taken into account, including limiting cases of the exponential and logarithmic form. The structure of the waves is analyzed by means of a phase plane defined in terms of two reduced coordinates. Loci of extrema of the integral curves in the phase plane are traced, and loci of singularities are determined on the basis of their intersections. Boundary conditons are introduced for the case where the medium into which the waves propagate is at rest. Representative solutions, pertaining to all the possible cases of blast waves bounded by shock fronts propagating into an atmosphere of uniform density, are obtained by evaluating the integral curves and determining the corresponding profiles of the gasdynamic parameters. Particular examples of integral curves for waves bounded by detonations are given, and all the degenerate solutions corresponding to cases where the integral curve is reduced to a point are delineated.

Oppenheim, A. K.↗

A systematic exposition of the conservation equations for blast waves.

In order to provide a rational background for the analysis of experimental observations of blast wave phenomena, the conservation equations governing their nonsteady flow field are formulated in a general manner, without the usual restrictions imposed by an equation of state, and with proper account taken, by means of source terms, of other effects which, besides the inertial terms that conventionally dominate these equations, can affect the flow. Taking advantage of the fact that a blast wave can be generally considered as a spatially one-dimensional flow field whose nonsteady behavior can be regarded, consequently, as a function of just two independent variables, two generalized blast wave coordinates are introduced, one associated with the front of the blast wave and the other with its flow field. The conservation equations are accordingly transformed into this coordinate system, acquiring thereby a comprehensive character, in that they refer then to any frame of reference, being applicable, in particular, to problems involving either space or time profiles of the gas-dynamic parameters in the Eulerian system, or time profiles in the Lagrangian system.

Oppenheim, A. K.↗