Engineering topics
Publications and source records attributed to Kuppermann, A..
System performs rapid multiple analyses of entire compound classes or individual compounds on small amounts of sample and reagent. Method will allow screening of large populations for metabolic disorders and establishment of effective-but-safe levels of therapeutic drugs in body fluids and tissues.
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The authors (1971) detected a new triplet state of water at 9.81 eV energy, and assigned the low energy-loss feature to the excitation of low-lying triplet state(s) of water on the basis of the angular distribution of the scattered electrons. The results are discussed here in more detail, as well as relative differential cross sections for elastic scattering, and for the excitation of these and several other electronic and pure vibrational states of water at impact energies of 15, 20, and 53 eV and at scattering angles ranging from 0 to 90 deg.
Study of the electron-impact excitation spectrum of O2 at 20 and 45 eV impact energies and at scattering angles ranging from 10 to 90 deg. The angular behavior of the differential scattering cross sections for excitation of the a super 1 delta sub g, b super 1 sigma sub g (+), B super 3 sigma sub u (-) states for the 9.97-eV ('longest' band) and the 10.29-eV ('second' band) transitions, for the broad feature at 6.1 eV energy-loss, and for elastic scattering is determined. The experimentally measured relative differential and integral cross sections for these processes are approximately normalized to the absolute scale. The intensities of the different transitions in optical and electron-impact spectra are compared, and the importance of spin-orbit coupling and exchange processes is discussed. It is found that the energy-loss feature at 6.1 eV in the electron-impact spectrum is mostly due to the excitation of the c super 1 sigma sub u (-) state, and not the A super 3 sigma sub u (+) state, as had been previously thought.
Single to triplet transitions of water vapor as function of scattering angle in electron impact detection
Differential cross sections for electron scattering by hydrogen with and without vibrational excitation, discussing inelastic processes
Elastic scattering of electrons by hydrogen
Born approximation to calculate electron scattering by hydrogen molecules