Geochemistry of amino acid enantiomers - Gas chromatography of their diastereomeric derivatives.
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Engineering topics
Publications and source records attributed to Kvenvolden, K. A..
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Detection limits were between 300 pg and 1 ng for different amino acids, in an analysis by gas-liquid chromatography of water extracts from Apollo 14 lunar fines in which amino acids were converted to their N-trifluoro-acetyl-n-butyl esters. Initial analyses of water and HCl extracts of sample 14240 and 14298 samples showed no amino acids above background levels.
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Quartz crystals from calcite veins of unknown age in Precambrian metasedimentary rocks at Geiaus No. 6 and Aukam farms in South-West Africa contain both primary and secondary inclusions filled with one substance or a combination of substances. These substances include organic liquid, moderately saline aqueous liquid, dark-colored solid, and a vapor. Analysis of these materials by microscopy and by gas chromatography and mass spectrometry shows the presence of constituents of both low and high molecular weights.
Extraterrestrial amino acids identification in carbonaceous chondrite Murray meteorite by gas chromatographic method
Permeability and porosity of Precambrian Onverwacht cherts and other low permeability rocks, discussing geological origin of rock-contained organic compounds
Biogenicity and significance of oldest stromatolites from optical microscopic and carbon isotopic studies
Murchison meteorite composition analysis, investigating nonprotein amino acids of extraterrestrial origin
Biogeochemical analysis on lunar dust sample for organic compounds
Porphyrin-like pigments in Apollo 12 lunar soil sample 12023, using spectral analysis involving fluorescence, absorption and magnetic circular dichroism spectrometry
Description of one approach to the analysis for carbon compounds in lunar materials from the Apollo 11 mission. The sequential scheme followed generally accepted organic geochemical practices, but was unusual in its application to a single sample. The procedures of the scheme were designed to minimize handling of the solids and extracts or hydrolysates. The solid lunar sample was retained in all steps of the sequential analysis in the vessel in which it was originally placed. Centrifugation was used to separate solid and liquid phases after extraction or refluxing. Liquids were recovered from solids by decantation.
Amino acid racemization as enantiomers in core sediment samples
Apollo 11 lunar fines carbon compounds, examining chemical state of porphyrins, fatty and amino acids, purines, pyrimidines and carbohydrates, etc
Apollo 11 lunar fines porphyrin-like pigments content demonstrated by fluorescence spectrometry and analytical demetallation, suggesting rocket exhaust source
Lunar fines hydrochloric acid hydrolysates examination by gas-liquid chromatography indicating presence of organosiloxanes
Volatilizable C compounds in lunar fines from Mare Tranquillitatis, investigating pyrolysis and acid hydrolysis products by mass spectroscopy and gas chromatography