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Lange, M. A.

Publications and source records attributed to Lange, M. A..

Passive microwave observations of the Wedell Sea during austral winter and early spring

The results of multispectral passive microwave observations (6.7 to 90-GHz) are presented from the cruises of the FS Polarstern in the Weddell Sea from July to December 1986. This paper includes primarily the analysis of radiometric observations taken at ice station sites. Averaged emissivity spectra for first-year (FY) ice were relatively constant throughout the experiment and were not statistically different from FY ice signatures in the Arctic. Detailed ice characterization was carried out at each site to compare the microwave signatures of the ice with the physical properties. Absorption optical depths of FY ice were found to be sufficiently high that only the structure in the upper portions of the ice contributed significantly to interstation emissivity variations. The emissivities at 90-GHz, e(90), had the greatest variance. Both e(90) at vertical polarization and GR(sub e)(90, 18.7)(defined as (e(sub V)(90)-e(sub V)(18.7))/e(sub V)(90 + e(sub V)(18.7)) depended on the scattering optical depth which is a function of the snow grain diameter and layer thickness. The variance showed a latitude dependence and is probably due to an increase in the strength of snow metamorphism nearer the northern edge of the ice pack. The contribution of variations of near-surface brine volume to the emissivity was not significant over the range of values encountered at the station sites. Emissivity spectra are presented for a range of thin ice types. Unsupervised principal component analysis produced three significant eigenvectors and showed a separation among four different surface types: open water, thin ice, FY ice, and FY ice with a thick snow cover. A comparison with SMMR satellite data showed that average ice concentrations derived from the ship's ice watch log were consistent with the satellite concentrations. The surface based emissivities for FY ice were also compared with emissivities calculated from scanning multichannel microwave radiometer (SMMR) satellite radiances. Best agreement was found at 6.7 and 10-GHz, while at 18 and 37-GHz, SMMR emissivities were slightly lower than surface based results. For the three lower frequencies agreement was found within a confidence limit of 95% and for 37-GHz within about 90%.

Grenfell, T. C.↗

Passive microwave in situ observations of winter Weddell Sea ice

Results are presented on the microwave radiative characteristics of Antarctic sea ice measured during the 1986 Winter Weddell Sea Project with a set of portable radiometers. Radiometer measurements at 6, 10, 18, 37, and 90 GHz in vertical and horizontal polarizations were supplemented by near-simultaneous measurements of the ice physical characteristics (including ice thickness, salinity, temperature, snow cover, and density) made during two cruises, lasting 3 months each. Measurements were obtained on various types of sea ice over a large portion of the Weddell-Sea ice cover, including four transects across the entire ice pack. Data analysis shows a large variability in the multispectral microwave emissivities of different ice types, especially at 90 GHz, demonstrating a strong potential of the use of the 90-GHz channel, in combination with lower-frequency channels, for detailed characterizations of the ice cover.

Comiso, J. C.↗

Shock-induced CO2 loss from CaCO3 - Implications for early planetary atmospheres

Recovered samples from shock recovery experiments on single crystal calcite were subjected to thermogravimetric analysis to determine the amount of post-shock CO2, the decarbonization interval and the activation energy, for the removal of remaining CO2 in shock-loaded calcite. Comparison of post-shock CO2 with that initially present determines shock-induced CO2 loss as a function of shock pressure. Incipient to complete CO2 loss occurs over a pressure range of approximately 10 to approximately 70 GPa. Optical and scanning electron microscopy reveal structural changes which are related to the shock-loading. The occurrence of dark, diffuse areas, which can be resolved as highly vesticular areas as observed with a scanning electron microscope are interpreted as representing quenched partial melts, into which shock-released CO2 was injected. The experimental results are used to constrain models of shock-produced, primary CO2 atmospheres on the accreting terrestrial planets.

Lange, M. A.↗

Shock effects on hydrous minerals and implications for carbonaceous meteorites

The effect of shock loading over the pressure range of 29-59 GPa on the shock-recovered specimens of antigorite serpentine, Mg3Si2O5(OH)4, were investigated employing infrared (IR) spectroscopy, thermogravimetric analysis, and optical and scanning electron microscopy. With increasing shock pressure, there was an increase in H2O IR absorption peaks at the expense of OH peaks, while the changes in SiO bond vibration modes were identical to those seen for other, nonhydrous minerals. Thermogravimetric results on vented assembly samples showed linear relationships between the shock pressure and both the length of dehydration interval and the effective activation energy for releasing post-shock structural water. Optical and scanning electron microscopy revealed gas bubbles, which appeared to be injected into zones of partial melting, and vesicular dark veins distributed throughout the shocked samples. It is suggested that shock loading of hydrous minerals would release and redistribute free water in the regoliths of carbonaceous chondrite parent bodies, giving rise to observed hydrous alterations.

Lange, M. A.↗

An impact-induced terrestrial atmosphere and iron-water reactions during accretion of the Earth

Shock wave data and theoretical calculations were used to derive models of an impact-generated terrestrial atmosphere during accretion of the Earth. The models showed that impacts of infalling planetesimals not only provided the entire budget of terrestrial water but also led to a continuous depletion of near-surface layers of water-bearing minerals of their structural water. This resulted in a final atmospheric water reservoir comparable to the present day total water budget of the Earth. The interaction of metallic iron with free water at the surface of the accreting Earth is considered. We carried out model calcualtions simulating these processes during accretion. It is assumed that these processes are the prime source of the terrestrial FeO component of silicates and oxides. It is demonstrated that the iron-water reaction would result in the absence of atmospheric/hydrospheric water, if homogeneous accretion is assumed. In order to obtain the necessary amount of terrestrial water, slightly heterogeneous accretion with initially 36 wt% iron planetesimals, as compared with a homogeneous value of 34 wt% is required.

Lange, M. A.↗

Shock-induced CO2 loss from CaCO3: Implications for early planetary atmospheres

Recovered samples from shock recovery experiments on single crystal calcite were subjected to thermogravimetric analysis to determine the amount of post-shock CO2, the decarbonization interval and the activation energy, for the removal of remaining CO2 in shock-loaded calcite. Comparison of post-shock CO2 with that initially present determines shock-induced CO2 loss as a function of shock pressure. Incipient to complete CO2 loss occurs over a pressure range of approximately 10 to approximately 70 GPa. Optical and scanning electron microscopy reveal structural changes, which are related to the shock-loading. The occurrence of dark, diffuse areas, which can be resolved as highly vesicular areas as observed with a scanning electron microscope are interpreted as representing quenched partial melts, into which shock-released CO2 was injected. The experimental results are used to constrain models of shock-produced, primary CO2 atmospheres on the accreting terrestrial planets.

Lange, M. A.↗

FeO and H2O and the homogeneous accretion of the earth

Shock devolatilization recovery data for brunite (Mg(OH)2) shocked to 13 and 23 GPa are presented. These data combined with previous data for serpentine (Mg3Si2O5(OH)4) are used to constrain the minimum size terrestrial planet for which planetesimal infall will result in an impact generated water atmosphere. Assuming, in hydrous phyllosilicates, model calculations simulating the interaction of metallic iron with impact released free water on the surface of the accreting earth were carried out. It is assumed that the reaction of water with iron in the presence of enstatite is the prime source of the terrestrial FeO component of silicates and oxides. Lower and upper bounds on the terrestrial FeO budget are based on mantle FeO content and possible incorporation of FeO in the outer core. We demonstrate that the iron water reaction would resuit in the absence of atmospheric/hydrospheric water, if homogeneous accretion is assumed.

Lange, M. A.↗

Impact cratering and spall failure of gabbro

Both hypervelocity impact and dynamic spall experiments were carried out on a series of well-indurated samples of gabbro. The impact experiments carried out with 0.04 to 0.2 g, 5-6 km/sec projectiles produced deci-centimeter-sized craters and demonstrated crater efficiencies of 6/10 to the -9 g/erg, and order of magnitude greater than in metal and some two to three times that of previous experiments on less strong igneous rocks. Most of the crater volume (some 60 to 80 percent) is due to spall failure. Distribution of cumulative fragment number, as a function of mass of fragments with masses greater than 0.1 gram yield values of b = d(log10N sub f)dlog10(m) of -0.5 to -0.6, where N sub f is the cumulate number of fragments and m is the mass of fragments. These values are in agreement or slightly higher than those obtained for less strong rocks and indicate that a large fraction of the ejecta resides in a few large fragments.

Lange, M. A.↗

The dynamic tensile strength of ice and ice-silicate mixtures

The dynamic tensile strength of icy media is measured at strain rates on the order of 10,000/sec to aid in the understanding of impact and cratering phenomena. Compressed samples consisting of ice and ice-silicate mixtures with 5 and 30 wt % sand were impacted at temperatures between 230 and 250 K by projectile plexiglas plates imparting the required strain rates in less than 0.75 microsec. Taking the tensile stress corresponding to the transition from intact to spalled or fragmented samples as the dynamic tensile strength, strengths of 17, 20 and 22 MPa were obtained for the pure ice, 5 wt % sand, and 30 wt % sand specimens, respectively. The values lie considerably above those observed in static testing. A continuum fracturing model is used to obtain relations between tensile strength and stress rate as well as to derive stress and damage histories during tensile loading and the size distribution of icy fragments as a function of strain rate.

Lange, M. A.↗

Impact cratering and spall failure at gabbro

Both hypervelocity impact and dynamic spall experiments were carried out on a series of well-indurated samples of gabbro. The impact experiments carried out with 0.04 to 0.2g, 5-6 km/sec projectiles produced deci-centimeter-sized craters and demonstrated crater efficiencies of 6/10 to the - 9 g/erg, and order of magnitude greater than in metal and some two to three times that of previous experiments on less strong igneous rocks. Most of the crater volume (some 60 to 80%) is due to spall failure. Distribution of cumulative fragment number, as a function of mass of fragments with masses greater than 0.1 gram yield values of b = d(log10N sub f)dlog10(m)of -0.5 to -0.6, where N sub f is the cumulate number of fragments and m is the mass of fragments. These values are in agreement or slightly higher than those obtained for less strong rocks and indicate that a large fraction of the ejectra resides in a few large fragments.

Lange, M. A.↗

FeO and H-2O and the homogeneous accretion of the earth

Shock devolatilization recovery data for brunite (Mg(OH)2) shocked to 13 and 23 GPa are presented. These data combined with previous data for serpentine (Mg3Si2O5(OH)4) are used to constrain the minimum size terrestrial planet for which planetesimal infall will result in an impact generated water atmosphere. Assuming, in hydrous phyllosilicates, model calculations simulating the interaction of metallic iron with impact released free water on the surface of the accreting Earth were carried out. It is assumed that the reaction of water with iron in the presence of enstatite is the prime source of the terrestrial FeO component of silicates and oxides. Lower and upper bounds on the terrestrial FeO budget are based on mantle FeO content and possible incorporation of FeO in the outer core. We demonstrate that the iron water reaction would result in the absence of atmospheric/hydrospheric water, if homogeneous accretion is assumed.

Lange, M. A.↗

The evolution of an impact-generated atmosphere

The minimum impact velocities and pressures required to form a primary H2O atmosphere during planetary accretion from chondritelike planetessimals are determined by means of shock wave and thermodynamic data for rock-forming and volatile-bearing minerals. Attenuation of impact-induced shock pressure is modelled to the extent that the amount of released water can be estimated as a function of projectile radius, impact velocity, weight fraction of target water, target porosity, and dehydration efficiency. The two primary processes considered are the impact release of water bound in such hydrous minerals as serpentine, and the subsequent reincorporation of free water by hydration of forsterite and enstatite. These processes are described in terms of model calculations for the accretion of the earth. It is concluded that the concept of dehydration efficiency is of dominant importance in determining the degree to which an accreting planet acquires an atmosphere during its formation.

Lange, M. A.↗

Fragmentation of ice by low velocity impact

Low-velocity impact experiments (0.14 to 1 km/s) carried out in polycrystalline water ice targets at 257 and 81 K reveal interactions which are assigned to four fragmentation classes: cratering, erosion, disruption, and total fragmentation. The specific kinetic energies for the transitions between these classes are found to be about one to two orders of magnitude below those for silicate rocks. The mass vs. cumulative number distribution of fragments in the experiments is described by a simple power law, similar to that observed in fragmented rocks both in the laboratory and in nature. The logarithmic slopes of cumulative number vs. fragment weight range from -0.9 to -1.8; they decrease with increasing projectile energy and are approximately independent of target temperature. The shapes of fragments resulting from erosion and disruption of ice targets are found to be significantly less spherical for 257 K targets than for 81 K targets. Fragment sphericity increases with increasing projectile energy at 257 K; however, no similar trend is observed for 81 K ice.

Lange, M. A.↗

Impact induced dehydration of serpentine and the evolution of planetary atmospheres

Results of shock recovery experiments carried out on antigorite serpentine Mg3Si2O5(OH)4 are reported. The main objective of the present study is the determination of critical shock pressures for partial and complete dehydration of serpentine under shock loading. It is pointed out that serpentine and serpentine-like layer silicates are the major water-bearing phases in carbonaceous chondrites. It appears that these minerals, and a poorly defined cometary contribution, were the most likely water-bearing phases in accreting planetesimals which led to the formation of the terrestrial planets. The obtained results imply that the process of impact induced devolatilization of volatile bearing minerals during accretion is likely to have occurred on earth. The findings lend support to the model of a terrestrial atmosphere/hydrosphere forming during the later stages of accretion of the earth.

Lange, M. A.↗

Impact melting early in lunar history

The total amount of impact melt produced during early lunar history is examined in light of theoretically and experimentally determined relations between crater diameter (D) and impact melt volume. The time dependence of the melt production is given by the time dependent impact rate as derived from cratering statistics for two different crater-size classes. Results show that small scale cratering (D less than or equal to 30 km) leads to melt volumes which fit selected observations specifying the amount of impact melt contained in the lunar regolith and in craters with diameters less than 10 km. Larger craters (D greater than 30 km) are capable of forming the abundant impact melt breccias found on the lunar surface. The group of large craters (D greater than 30 km) produces nearly 10 times as much impact melt as all the smaller craters, and thus, the large impacts dominate the modification of the lunar surface. A contradiction between the distribution of radiometric rock ages and a model of exponentially decreasing cratering rate going back to 4.5 b.y. is reflected in uncertainty in the distribution of impact melt as a function of time on the moon.

Lange, M. A.↗