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Lauer, J. L.

Publications and source records attributed to Lauer, J. L..

34 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Surface profile changes of scuffed bearing surfaces

A phase locked interference microscope capable of resolving depth differences to 30 A and planar displacements of 6000 A was constructed for the examination of the profiles of bearing surfaces without physical contact. This instrument was used to determine surface chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than unscuffed ones, but bearing surfaces which had been previously exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at room temperature. The change of surface contour as a result of the probe reaction followed an Arrhenius type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.

Lauer, J. L.↗
NASA NTRS1981

Alignment of fluid molecules in an EHD contact

Dichroic infrared emission spectra have been obtained from an operating elastohydrodynamic contact under conditions showing unequivocally that the molecules of the fluid are aligned under shear flow in the bulk of the fluid and that the extent of the alignment is increased by the presence of an additive in a small concentration. This work applied particularly to polyphenyl ether and to 1,1,2-trichloroethane as the additive, but similar results have been obtained with polycyclohexyls and the same additive. The observation of two separate glass transitions for the polycyclohexyl solution is an indication of the occurrence of a phase separation in the Hertzian inlet zone. A model has been developed to explain the effect of these phenomena and their relation to traction.

Lauer, J. L.↗
NASA NTRS1981

Determination of physical and chemical states of lubricants in concentrated contacts, part 2

Infrared emission spectroscopy through a window in an operating bearing continued to provide most of the information gathered on the state of lubricants subjected to elastohydrodynamic (EHD) conditions. Other measurements were traction, scanning electron microscopy and elemental surface analysis X-rays. A very significant finding was the decomposition of a naphthenic oil lubricant in the presence of small concentrations of an organic chloride. Olefins and aromatics were formed in ever increasing amounts prior to total lubricant failure. An aromatic fluid also failed in the presence of chloride. A correlation was found between changes of the alignment of lubricant molecules evidence by infrared polarization and changes of traction under varying EHD stresses.

Lauer, J. L.↗
NASA NTRS1981

Analysis of infrared emission from thin adsorbates

Fuel and lubricant deposits on solid surfaces, though often of similar visual appearance, differ in composition, depending on the nature of the deposit formers and the circumstances of deposition. To help establish these relations an Infrared Emission Fourier Polarization Microspectrophotometer was constructed to record infrared spectra from the deposits on their original support. By focussing on small aggregates with a reflecting microscope objective and by discriminating against the randomly polarized blackbody radiation with a rotating polarizing filter phase-locked to an amplifier, excellent Fourier emission spectra of polarized bands could be obtained. In many instances, the microscope objective was adequate without the polarizer. The analysis was calibrated against a very thin film of polyethylene terephthalate attached to a highly reflective aluminum mirror on the sample positioner.

Lauer, J. L.↗
NASA NTRS1980

Temperature gradients through EHD films and molecular alignment evidenced by infrared spectroscopy

Partial and complete emission band reversals have been observed in the infrared emission spectra from portions of operating sliding contacts. An elementary analysis has been carried out to show that partial reversals are due to temperature gradients in the fluid film - the film acts both as a radiation-emitter and absorber, and that total reversals - an emission spectrum appears as an absorption spectrum are likely to be due to a continuum source, such as hot solid asperities. The total energy radiated under the latter conditions exceeds that under the others. A decrease in gap width with increased load was accompanied by a dramatic spectral change in the case of 5P4E polyphenyl ether, which is indicative of molecular alignment.

King, V. W.↗
NASA NTRS1980

Spectroscopic study of the effect on an EHD contact of trichloroethane addition to a traction fluid

Addition of trichloroethane to a traction fluid was studied in a ball/diamond plate EHD apparatus by infrared emission spectroscopy of the radiation transmitted through the plate. Small concentrations of an organic chloride at first increased infrared radiance, then decreased it. Large concentrations caused a rapid decrease. During running, the infrared spectrum showed an increase of aromatics and olefins. A polymeric deposit formed on the plate. X-ray examination of the ball surface showed the presence of chlorine. Reuse of the same ball with fresh fluid resulted in similar chain of events, indicating that adsorbed chloride could promote fluid deterioration.

Lauer, J. L.↗
NASA NTRS1979

Determination of physical and chemical states of lubricants in concentrated contacts, part 1

A Fourier emission infrared microspectrometer, set up on a vibration-proof optical table and interfaced to a dedicated minicomputer, was used to record infrared emission spectra from elastohydrodynamic bearing contacts. Its range was extended to cover the entire mid-infrared from 2 to 15 micron. A series of experiments with 5P4E polyphenyl ether showed the existence of a temperature gradient through the lubricant in an ehd contact, which is perpendicular to the flow direction. The experiments also show marked polarization of some of the spectral bands, indicating a molecular alignment. Alignment is less evident at high pressure than at low pressure. To account for this behavior, a model is suggested along the lines developed for the conformational changes observed in long-chain polymers when subjected to increased pressure--to accommodate closer packing, molecules become kinked and curl up. Experiments with a traction fluid showed periodic changes of flow pattern associated with certain spectral changes. These observations will be studied further. A study by infrared attenuated total reflection spectrophotometry was undertaken to determine whether gamma irradiation would change polyethylene wear specimens. The results were negative.

Lauer, J. L.↗
NASA NTRS1979

Fourier emission infrared microspectrophotometer for surface analysis. I - Application to lubrication problems

A far-infrared interferometer was converted into an emission microspectrophotometer for surface analysis. To cover the mid-infrared as well as the far-infrared the Mylar beamsplitter was made replaceable by a germanium-coated salt plate, and the Moire fringe counting system used to locate the moveable Michelson mirror was improved to read 0.5 micron of mirror displacement. Digital electronics and a dedicated minicomputer were installed for data collection and processing. The most critical element for the recording of weak emission spectra from small areas was, however, a reflecting microscope objective and phase-locked signal detection with simultaneous referencing to a blackbody source. An application of the technique to lubrication problems is shown.

Lauer, J. L.↗
NASA NTRS1979

Infrared analysis of polyethylene wear specimens using attenuated total reflection spectroscopy

Attenuated total reflection infrared spectroscopy was used to analyze ultrahigh molecular weight polyethylene wear test specimens. Three different specimens were analyzed. One specimen was gamma irradiated to a dose of 5.0 MRad, another to a dose of 2.5 MRad, and the final specimen was unirradiated. There was no conclusive evidence of chemical changes (i.e., unsaturation or oxidation) in the surface regions of any of the polyethylene samples. Therefore, it was concluded that the gamma irradiation sterilization procedure shoud not alter the boundary lubricating properties of the polyethylene.

Jones, W. R.↗
NASA NTRS1979

Study of polyphenyl ether fluid /5P4E/ in operating elastohydrodynamic contacts by infrared emission spectroscopy

Infrared emission spectra of 5P4E polyphenyl ether were obtained from an operating elastohydrodynamic sliding contact at different speeds and loads by Fourier emission microspectrophotometry. The spectra were found to be polarized with respect to the direction of the conjunction line, especially at high shear rates. Film and metal surface temperatures were calculated from the spectra, and film thicknesses were determined under various operating conditions. Changes of polarized band structure above a critical shear rate, at which the slope of the film temperature versus shear curve changes abruptly and at which the film thickness assumes a minimum value, are consistent with a transition of the lubricant from a viscous liquid to a viscoelastic liquid or to an elastic solid.

Lauer, J. L.↗
NASA NTRS1978

Study of dynamic emission spectra from lubricant films in an elastohydrodynamic contact using Fourier transform spectroscopy

Infrared emission spectra were obtained through a diamond window from lubricating fluids in an operating sliding elastohydrodynamic contact and analyzed by comparison with static absorption spectra under similar pressures. Different loads, shear rates and temperatures were used. Most of the spectra exhibited polarization characteristics, indicating directional alignment of the lubricant in the EHD contact. Among the fluids studied were a "traction" fluid, an advanced ester, and their mixtures, a synthetic paraffin, a naphthenic reference fluid (N-1), both neat and containing 1 percent of p-tricresyl phosphate as an anti-wear additive, and a C-ether. Traction properties were found to be nearly proportional to mixture composition for traction fluid and ester mixtures. The anti-wear additive reduced traction and fluid temperature under low loads but increased them under higher loads, giving rise to formation of a friction polymer.

Lauer, J. L.↗
NASA NTRS1978

Traction and lubricant film temperature as related to the glass transition temperature and solidification

Does a traction fluid have to be a glass or solid under operating conditions. Infrared spectra on dynamic EHD contacts of several types of fluid were used to determine the surface and oil-film temperatures. Polarized spectral runs were made to study molecular alignment. Static glass transition pressures at appropriate temperatures were between 0.1 and 2.0 GPa, with the traction fluid showing the highest. In the EHD contact region, the traction fluid showed both the highest film temperatures as well as the greatest degree of molecular alignment. A plot of the difference between the film and surface temperatures vs shear rate resulted in a master plot valid for all the fluids. From this work, the authors propose a model of 'fluid' traction, where friction between parallel rough molecules provides the traction.

Lauer, J. L.↗
NASA NTRS1976

Infrared emission spectra from operating elastohydrodynamic sliding contacts

Infrared emission spectra from an operating EHD sliding contact were obtained through a diamond window for an aromatic polymer solute present in equal concentration in four different fluids. Three different temperature ranges, three different loads, and three different speeds for every load were examined. Very sensitive Fourier spectrophotometric (Interferometric) techniques were employed. Band Intensities and band intensity ratios found to depend both on the operating parameters and on the fluid. Fluid film and metal surface temperatures were calculated from the spectra and their dependence on the mechanical parameters plotted. The difference between these temperatures could be plotted against shear rate on one curve for all fluids. However, at the same shear rate the difference between bulk fluid temperature and diamond window temperature was much higher for one of the fluids, a traction fluid, than for the others.

Lauer, J. L.↗
NASA NTRS1975

Infrared emission spectra of elastohydrodynamic contacts

A small diamond disk mounted as a window in a steel plate was covered with test fluid, and a weighted steel ball was rotated over the window so as to form a sliding elastohydrodynamic (EHD) contact region. Some of the radiant energy generated in this region, both in the fluid and at the boundaries, passed through the window into an infrared interferometer, giving rise to an emission spectrum. This spectrum could be separated into contributions from the fluid and from the ball surface, making it possible, by appropriate calibrations, to estimate their temperatures separately under operating conditions. Moreover, the shape of the discrete spectral bands of the fluid permitted some inferences on its state. Two fluids were studied under identical mechanical conditions, a polyester and a naphthenic oil, each containing an equal amount of polymethylstyrene as a spectral indicator. Differences of band intensity, band width, and frequency could, therefore, be attributed to differences in the behavior of the base fluid.

Lauer, J. L.↗
NASA NTRS1974

Study to define behavior of liquid lubricants in an elastohydrodynamic contact

The spectra of an ester and a saturated hydrocarbon polymer were obtained at pressures ranging from ambient to 2 GN/sq m (20 kilobar) and at temperatures between ambient and 180 C in absorption and between 150 C and 210 C in emission. To simulate contact conditions the fluids were contained in the tiny sample volume of a diamond cell, i.e., the hole in a metal spacer separating two diamonds pressed against each other in a nut crackerlike arrangement. Pressures could be deduced from bandshifts and states of aggregation from bandwidths in the fluorescence spectrum of a ruby crystal immersed in the fluids. An infrared Fourier transform spectrometer was used with attachments specially designed to analyze the radiation passed through the sample and both diamonds (absorption technique) or the radiation emanating from the heated sample and passing through only one diamond (emission technique). The latter technique is applicable to operating EHD contacts. Spectral changes pointing to possible glass transitions and composition changes were observed. Emission and absorption spectra were generally equivalent. Some emission bandshapes appear to be temperature sensitive enough to be useful as internal temperature probes.

Lauer, J. L.↗