Engineering topics

Laul, J. C.

Publications and source records attributed to Laul, J. C..

At least 19 records

NASA NTRS1990

Chemical characterization of a unique chondrite - Allan Hills 85085

Allan Hills 85085 is a new and very important addition to the growing list of unique carbonaceous chondrites because of its unique chemical and mineralogical properties. This chemical study provides more precise data on the major, minor, and trace element characteristics of ALH85085. ALH85085 has compositional, petrological, and isotopic affinities to AL Rais and Renazzo, and to Bencubbin-Weatherford. The similarities to Al Rais and Renazzo suggest similar formation locations and thermal processing, possibly in the vicinity of CI chondrites. Petrologic, compositional and isotopic studies indicate that the components that control the abundance of the various refractory and volatile elements were not allowed to equilibrate with the nebula as conditions changed, explaining the inconsistencies in the classification of these meteorites using known taxonomic parameters.

Gosselin, David C.↗

NASA NTRS1990

Petrology and chemistry of Apollo 17 regolith breccias - A history of mixing of highland and mare regolith

Results are presented of petrological and chemical analyses of ten Apollo 17 breccias, showing that two of these consist predominantly of highland material, seven are mare-dominated, and one is a welded volcanic glass deposit; all were formed at or near the Apollo 17 site, and all contain both mare and highland components. The data are indicative of the Apollo 17 breccias formation from immature source regolith. The breccias are considered to be formed locally after an eruption of basalt and orange glass at the site. Since the formation of the breccias, the regolith at the Apollo 17 site has become more mature, and the orange glass abundance has been somewhat decreased by mixing. One of the sample may contain a previously unreported volcanic glass type.

Simon, S. B.↗

NASA NTRS1989

Chemistry and petrology of Apollo 17 highland coarse fines - Plutonic and melt rocks

A suite of 21 fragments from the Apollo 17 coarse-fines consists of ferroan anorthosites, anorthositic gabbros, granulitic and regolith breccias, and impact melts. These samples belong to known petrographic and chemical groups. Three ferroan anorthosites were found, including one which appears to be the lowest in REE (La = 0.60X) and probably the purest of the Apollo 17 anorthosites identified thus far. The ferroan suite is a more important component at the Apollo 17 site than previously recognized. The Apollo 17 melt rocks are similar to other samples with LKFM and low-K KREEP compositions and show less diversity in trace elements (REE) than the Apollo 15 melt rocks. Apollo 17 melt rocks consist of aphanitic and poikilitic types that show some compositional variability with identical Ni/Ir, suggesting that either two distinct melt sheets formed by similar projectiles, or compositional heterogeneity within one melt sheet is possible.

Laul, J. C.↗

NASA NTRS1988

Apollo 16 regolith breccias and soils - Recorders of exotic component addition to the Descartes region of the moon

Using the subdivision of Apollo 16 regolith breccias into ancient (about 4 Gyr) and younger samples (McKay et al., 1986), with the present-day soils as a third sample, a petrologic and chemical determination of regolith evolution and exotic component addition at the A-16 site was performed. The modal petrologies and mineral and chemical compositions of the regolith breccias in the region are presented. It is shown that the early regolith was composed of fragments of plutonic rocks, impact melt rocks, and minerals and impact glasses. It is found that KREEP lithologies and impact melts formed early in lunar history. The mare components, mainly orange high-TiO2 glass and green low-TiO2 glass, were added to the site after formation of the ancient breccias and prior to the formation of young breccias. The major change in the regolith since the formation of the young breccias is an increase in maturity represented by the formation of fused soil particles with prolonged exposure to micrometeorite impacts.

Simon, S. B.↗

NASA NTRS1988

Chemistry and petrology of the Apennine Front, Apollo 15. I - KREEP basalts and plutonic rocks. II - Impact melt rocks

The mineralogy, petrology, and chemistry of rock fragments for the Apennine Front coarse fines (10-4 and 4-2 mm) have been determined. The data are consistent with a single eruptive event that produced several flows. It is found that most of the plutonic rocks are ferroan in nature, with a few belonging to the Mg-suite. The mineral and bulk chemistry of KREEP basalts and the composition of ferroan anorthosites are discussed. Petrographic studies of 21 impact melts are also presented, showing a variety of textures. It is found that the Apollo 15 impact melts are mixtures of low-K Fra Mauro, KREEP, and plutonic components. The Ni/Ir ratios of the melt rocks are shown to be greater than chondritic values, indicating ancient and/or iron meteorite components.

Simon, S. B.↗

NASA NTRS1987

Roosevelt County 027 - A low-shock ureilite with interstitial silicates and high noble gas concentrations

The RC027 lightly-shocked ureilite contains less than 1 percent of a fine-grained interstitial silicate that has an igneous texture indicating crystallization from an interstitial liquid. RC027 is also noted to exhibit the strongest olivine preferred-orientation thus far observed in a ureilite; its fabric is characteristic of fabrics formed by tabular minerals in a fluid laminar flow regime, and is unlike those formed by synectonic recrystallization and plastic flow. The elemental and isotopic compositions of noble gases in RC027 are typical of previously analyzed ureilites.

Goodrich, Cyrena Anne↗

NASA NTRS1987

Rare earth patterns in shergottite phosphates and residues

Leaching experiments with 1M HCl on ALHA 77005 powder show that rare earth elements (REE) are concentrated in accessory phosphate phases (whitlockite, apatite) that govern the REE patterns of bulk shergottites. The REE patterns of whitlockite are typically light REE-depleted with a negative Eu anomaly and show a hump at the heavy REE side, while the REE pattern of apatite (in Shergotty) is light REE-enriched. Parent magmas are calculated from the modal compositions of residues of ALHA 77005, Shergotty, and EETA 79001. The parent magmas lack a Eu anomaly, indicating that plagioclase was a late-stage crystallizing phase and that it probably crystallized before the phosphates. The parent magmas of ALHA 77005 and Shergotty have similar REE patterns, with a subchondritic Nd/Sm ratio. However, the Sm/Nd isotopoics require a light REE-depleted source for ALHA 77005 (if the crystallization age is less than 600 Myr) and a light REE-enriched source for Shergotty. Distant Nd and Sr isotopic signatures may suggest different source regions for shergottites.

Laul, J. C.↗

NASA NTRS1987

The lunar regolith - Chemistry and petrology of Luna 24 grain size fractions

Chemical data obtained by instrumental neutron activation analysis are reported for 30 elements in eight lunar soil size fractions from 370 to less than 2 microns, as well as petrology for five size fractions down to 40-10 microns in two Luna 24 soils. While the compositions of coarser fractions are similar to each other, they differ from the fractions smaller than 10 microns; these become increasingly feldspathic and enriched in large ion lithophile elements (LILE) with decreasing grain size. The high concentrations of the Ni, Au and Ir meteoritic indicator elements in these finer fractions are consistent with comminution by meteoritic impact. Size distributions, petrology and LILE patterns indicate that Luna 24 soils are less reworked than most lunar soils.

Laul, J. C.↗

NASA NTRS1986

Petrology, chemistry, and origin of Apollo 15 regolith breccias

Variations in modal petrology, mineral compositions, and bulk compositions were determined for ten Apollo 15 regolith breccias for comparison with local soils and assessment of the intrasite petrologic variability of the Apollo 15 regolith. Based on the above criteria the breccias are of local origin and mimic the soils from the corresponding sampling stations, with the exception of station 2 breccia 15205. This sample formed from an anomalous regolith, and although not considered exotic to the site is not representative of the soil at the site. KREEP basalt and green glass components vary from trace amounts to dominant in the breccias, evidence that these materials entered the regolith prior to formation of the breccias. Breccias from the edge of Hadley Rille are modally richer in highland fragments than the soils, whereas at the base of Hadley Delta the reverse is true. This is explained by the loss of material into the Rille to be replaced by basalt-derived material, making the soils more basalt-rich. At the base of Hadley Delta highland material is accumulating and the soils are becoming more highland-rich. Over billions of years these processes have developed differences between the present day, evolving soils, and 'fossil' nonevolving soils represented by the regolith breccias. This shows that there has been little change in the geology and the morphology of the Apollo 15 site, probably since the eruption of mare basalts at the site (about 3.3 b.y.).

Simon, S. B.↗

NASA NTRS1986

The Shergotty consortium and SNC meteorites - An overview

The key up-to-date findings on the Shergotty and other SNC meteorites are summarized. The Martian origin of these meteorites is strongly suggested by the evidence of trapped noble gases and nitrogen compositions in glasses of the EETA 79001 meteorite, which compare well with the results of the Martian atmosphere investigation by the Viking spacecraft. Age-dating and exposure scenarios suggest two possibilities for the ejection of SNC meteorites: (1) ejection as a large (larger than 6 m) body by a single impact on Mars and then multiple breakup in the asteroidal belt, at about 11 Myr for Chassigny and nakhlites, at 2.5 Myr for Shergotty, Zagami and ALHA 77005, and at 0.6 Myr for EETA 79001; and (2) ejection of small (less than 0.5 m) objects by multiple impacts on the Martian terrain at 11, 2.5, and 0.6 Myr, with no breakup in space.

Laul, J. C.↗

NASA NTRS1986

Chemical systematics of the Shergotty meteorite and the composition of its parent body (Mars)

Sixty elements in two bulk samples of Shergotty meteorite and 30 elements in various mineral separates of Shergotty were identified, using mainly INAA and RNAA techniques. In addition, elements leached out from powdered samples of Shergotty and EETA 79001 meteorites by 0.1 N HCl, as well as the elements of their residues, were analyzed. The results have indicated that Shergotty meteorite is homogeneous in its major element composition, but heterogeneous with respect to large-ion lithophile elements, such as K, Ba, Sr, Zr, Hf, Ta, Th, and rare-earth elements (REEs). It is even more heterogeneous with respect to volatile elements, such as Cd, Te, Tl, and Bi, and the siderophiles Au and Ag. The REE patterns of the Shergotty and EETA 79001 residues are identical, indicating that the parent magmas of both meteorites are compositionally similar. However, their leachate (phosphate) patterns are different, suggesting two components for the Shergotty, one of which is similar to the EETA 79001 leachate.

Laul, J. C.↗

NASA NTRS1986

The Maryville meteorite - A 1983 fall of an L6 chondrite

The Maryville chondrite fell on January 28, 1983 in eastern Tennessee. Compositions of olivine (Fa 24.5), orthopyroxene (Fs 20.8), plagioclase (An 10.6), along with the bulk composition and siderophile concentrations, indicate L-group classification. The presence of highly equilibrated minerals, strongly recrystallized matrix, and the development of large, clear plagioclase grains suggest petrologic type 6 classification. Subsequent to metamorphism the meteorite was subjected to high transient pressures that converted some feldspar to glass, deformed the silicates, and caused small amounts of melting to occur. The effects of this shock event correspond to shock facies 'd' or 'e'.

Shervais, J. W.↗

NASA NTRS1986

Chemistry of the Apollo 12 highland component

Eleven chemical highland groups are identified in Apollo 12 fragments and a range of petrographic types is found. Among the chemical groups, four are newly recognized; one group is a very high-K KREEP-La at 520X with a -Eu anomaly at 50X, and the other three have positive anomalies as follows (1) a poikilitic/granulitic rock with La at 130X, (2) anorthosite with La at 30X and Eu at 90X, and (3) anorthosite with La at 12X and Eu at 25X. The Apollo 12 highland suite is dominated by high-K Kreep and is similar to the Apollo 12 highland suite is dominated by hign-K Kreep and is similar to the Apollo 14 highland suite. The presence of high-K Kreep explains the relatively high LIL contents in the Apollo 12 soils. The plutonic suite data exhibit a trend in Eu anomaly versus longitude. Several parent magmas are suggested to explain the wide variety of plutonic and other highland suites observed at the Apollo 11 and 12 sites.

Laul, J. C.↗

NASA NTRS1985

Very high potassium (VHK) basalt - Complications in mare basalt petrogenesis

The first comprehensive report on the petrology and geochemistry of Apollo 14 VHK (Very High Potassium) basalts and their implications for lunar evolution is presented. The reported data are most consistent with the hypothesis that VHK basalts formed through the partial assimilation of granite by a normal low-Ti, high-Al mare basalt magma. Assimilation was preceded by the diffusion-controlled exchange of alkalis and Ba between basalt magma and the low-temperature melt fraction of the granite. Hypotheses involving volatile/nonvolatile fractionations or long-term enrichment of the source regions in K are inconsistent with the suprachondritic Ba/La ratios and low initial Sr-87/Sr-86 ratios of VHK basalt. An important implication of this conclusion is that granite should be a significant component of the lunar crust at the Apollo 14 site.

Shervais, J. W.↗

NASA NTRS1985

Petrology and chemistry of Apollo 12 regolith breccias

Petrographic, mineral chemical, and bulk chemical data are reported for the three large Apollo 12 regolith breccias of the regolith breccia suite and for eight breccias handpicked from Apollo 12 coarse fines. Two samples formed from non-KREEPy anorthositic regolith not presently found at the sampling site. Eight of the samples can be considered mixtures of local basalt and KREEP components, with minor anorthositic components. Mare:KREEP ratios indicated by chemical mixing models range from 86:7 to essentially endmember KREEP. One sample is unlike the others (FeO 23.7; MgO 21.7) and may be a new lithology or alternatively a nonrepresentative sample. Of the 11 samples studied, five appear to be of local origin, three are most likely exotic to the site, and results for three others are inconclusive. The anorthositic breccias formed from Apollo 16-like regolith and may have been transported over several hundred kilometers from the non-KREEPy highlands to the east. Alternatively, they may be of local origin, formed from the material beneath the Apollo 12 basalt flows.

Simon, S. B.↗

NASA NTRS1985

Chemistry and petrology of Apollo 12 drive tube 12027

Papike et al. (1982) have provided a summary of previous petrologic and chemical studies of the lunar regolith, taking into account samples from all of the Apollo and Luna sites. On the basis of these studies, an understanding is obtained of the processes which form and characterize the lunar regolith. It is found that comminution of local lithologies by meteorite impact and soil mixing are the most important regolith-forming processes. On the basis of grain size studies of Apollo 14 surface, trench, and drive tube soils, Simin et al. (1982) and Laul et al. (1982) concluded that comminution of local lithologies and vertical soil mixing processes are most important in the formation of the soils at that site. In the present investigation, this study of chemistry and petrology of lunar soils is extended to the Apollo 12 drive tube 12027. This drive tube provides an opportunity to study lunar soil from a depositional environment involving a location at the rim of a crater. The chemical and petrologic data are found to be consistent and suggest three stratigraphic units in the 12027 core.

Smith, M. R.↗

NASA NTRS1985

Noble gas component organization in Apollo 14 breccia 14318 I-129 and Pu-244 regolith chronology

Drozd et al. (1972) have first detected the presence of Xe-129 in lunar material. Bernatowicz et al. (1979, 1980) established that this xenon component resides exclusively on grain surfaces and confirmed previous observations that it is less tightly bound than other surface components. The present investigation extends many of the observations made on the basis of a study of the 14301 to 14318, which is the only other lunar regolith breccia for which the isotopic structure of 'parentless xenon' has been accurately resolved. Actually this isotope has two parents, including Pu-244 and I-129, which are both now extinct. Attention is given to the analyzed samples, the employed analytical methods, the petrology and chemistry of the grain size separates, and stepwise heating experiments. On the basis of the obtained results, it is concluded that the I-Pu-Xe system can be used as a chronometer.

Swindle, T. D.↗

NASA NTRS1985

Apollo 15 regolith breccias and soils: Comparative petrology and chemistry

Soils and regolith breccias contain clues to the geologic processes that contributed to the evolution of the local regolith over time. A suite of ten regolith breccias from the Apollo 15 site were compared with the results of previous studies in order to learn more about the regolith evolution at that site.

Simon, S. B.↗