Engineering topics
Lee, Jason J.
Publications and source records attributed to Lee, Jason J..
Drastic enhancement of carbon dioxide adsorption in fluoroalkyl-modified poly(allylamine)
Aminopolymer functionalization with fluoroalkyl chains and resulting void volume afford 4.1-fold increase in amine efficiency and 2.8-fold increase in CO 2 capture capacity in the fluorinated material.
Porosity and hydrophilicity modulated quaternary ammonium-based sorbents for CO 2 capture
Quaternary ammonium (QA)-based polymeric sorbents are known to be effective for CO 2 capture, especially from ultradilute streams like air. In this work, we address two major challenges in QA sorbent design for application in moisture-swing processes, porosity control and hydrophilicity modulation. Facilely substituting porous CO 2 -active components for non-porous ones can enhance the sorption kinetics by 4-fold compared to the state-of-art, and micro–mesoporous structures are identified as optimal porous structures. A method to modulate the hydrophilicity of QA-based sorbents is developed using controlled radical polymerization, incorporating fluorine-containing monomers. The CO 2 sorption capacity and the tolerance towards moisture are simultaneously enhanced via adjustment of the structure and the content of fluorine-containing blocks. Finally, we postulate that porosity and hydrophilicity optimization can make QA-based sorbents adaptive to deployment of scalable moisture-swing processes in varied and complex atmospheric circumstances.