Engineering topics
Publications and source records attributed to Li, Yixuan.
A systematic methodology for the quantification of lithium inventory is developed and the degradation mechanisms of high-voltage lithium batteries are revealed.
Here, using a thick NMC811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ) electrode as an example, we present a macro- to nanoscale 2D and 3D imaging analysis approach coupled with 4D (space + time) computational modeling to probe its degradation mechanism in a lithium-ion battery cell. Particle cracking increases and contact loss between particles and carbon-binder domain are observed to correlate with the cell degradation. This study unravels that the reaction heterogeneity within the thick cathode caused by the unbalanced electron conduction is the main cause of the battery degradation over cycling. The increased heterogeneity in the system will entail more cathode regions where the degree of active material utilization is uneven, leading to higher probabilities of particle cracking. These findings shed light on the crucial role of the electronic and ionic transportation networks in the performance deterioration of the thick cathode. They also provide guidance for cathode architecture optimization and performance improvement.
All known horizonless black-hole microstate geometries correspond to brane sources that acquire a finite size, and hence break the spherical symmetry of the black hole. We construct, for the first time, solutions with zero horizon area that have the same charges as a three-charge F1-NS5-P Type-IIA black hole and preserve this spherical symmetry. The momentum of these solutions is carried by longitudinal D0-D4 density fluctuations inside the NS5-branes. We argue that these solutions should be interpreted as the long-throat limit of a family of smooth, horizonless microstate geometries, called superstrata, where such geometries degenerate. The existence of these geometries indicates that a finite-size horizon does not appear even in the singular corners of the moduli space of three-charge microstate geometries.