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Lin, M. C.

Publications and source records attributed to Lin, M. C..

9 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

CN radical reactions with hydrogen cyanide and cyanogen - Comparison of theory and experiment

The method of laser photolysis/laser-induced fluorescence is used to obtain absolute rate constants for CN radical reactions with HCN and C2N2. The rate constants were found to be temperature-dependent in the range 300-740 K and pressure independent in the range 100-600 Torr. Rice-Remsperger-Kassel-Marcus theory for both reactions employing the transition state parameters obtained by the BAC-MP4 method are made. These calculations yielded reasonable results for the CN + HCN reaction, predicting both the temperature dependence and pressure independence. No pressure effect was observed in the pressure range 100-1000 Torr at temperatures below 900 K, confirming the experimental results.

Yang, D. L.↗
NASA NTRS1988

Kinetics of CH(X 2Pi) radical reactions with cyclopropane, cyclopentane, and cyclohexane

Rate constants have been obtained for CH(X 2Pi) radical reactions with cyclopropane, cyclopentane, and cyclohexane in order to establish the rate of CH insertion into secondary C-H bonds in alkanes. Data indicate that there is no measurable dependence on photolysis laser energy. The reactions all exhibited rate constants that decrease with increasing temperature. It is suggested that a possible set of pathways for the cycloalkane reactions is a ring-opening process where the excited adduct decomposes to a hydrogen atom and a diene.

Zabarnick, S.↗
NASA NTRS1986

Kinetic study of the reaction CH (X 2Pi) + H2 yields CH2 (X 3B1) + H in the temperature range 372 to 675 K

The kinetics of the reversible reaction CH (X 2Pi) + H2 yields CH2 (X 3B1) + H at 372-675 K and total pressure 100 torr (mainly Ar) is investigated experimentally. The ground-state CH radicals are produced by photolysis of CHBr3 using 10-mJ 266-nm laser pulses (repetition rate 10 Hz) and monitored by measuring the fluorescence induced by a 429.8-nm dye laser, in the apparatus described by Berman et al. (1982) and Berman and Lin (1984). The results are presented in tables and graphs and characterized. The absolute rate constants for the forward and reverse reactions are determined, and their temperature dependence is given by Arrhenius expressions and formulas obtained in transition-state-theory calculations. The heat of formation of CH2 at 0 K is estimated (assuming that the recombination reaction CH2 + H has zero activation energy) as 92.6 + or - 0.5 kcal/mol.

Zabarnick, S.↗
NASA NTRS1985

Analysis of data from NASA B-57B gust gradient program

Statistical analysis of the turbulence measured in flight 6 of the NASA B-57B over Denver, Colorado, from July 7 to July 23, 1982 included the calculations of average turbulence parameters, integral length scales, probability density functions, single point autocorrelation coefficients, two point autocorrelation coefficients, normalized autospectra, normalized two point autospectra, and two point cross sectra for gust velocities. The single point autocorrelation coefficients were compared with the theoretical model developed by von Karman. Theoretical analyses were developed which address the effects spanwise gust distributions, using two point spatial turbulence correlations.

Frost, W.↗
NASA NTRS1983

Statistical analysis of turbulence data from the NASA Marshall Space Flight Center atmospheric boundary layer tower array facility

Statistical properties of atmospheric turbulence near the Earth's surface are presented. Emphasis is placed on the probability density distribution two point spatial correlation, length scale, and two point and single point spectrum. Comparison of the data with isotropic homogeneous models is made. In general, agreement with the models is poor. For the design of aircraft during operations in the lower levels associated with approach, takeoff, and terrain following, it appears necessary to improve existing models or develop new nonisotropic turbulence models.

Frost, W.↗
NASA NTRS1983

Low-level gust gradient program and avialtion workshop effort

The Proceedings of the Workshop on Meteorological and Environmental Inputs to Aviation Systems, hosted by the University of Tennessee Space Institute, October 26-28, 1982, were prepared for publication. The Proceedings were submitted to FAA and will be distributed by August. Also, the proceedings of a one day workshop devoted specifically to wind shear and hosted during the same time frame were prepared and distributed. Plans for the 1983 workshop are proceeding extremely well. The workshop theme was established, the committee topics identified, and all ten committee chairmen contacted have agreed to accept their respective assignments. Additional logistics for the workshop are being carried out. The 1983 workshop is scheduled for October 26-28, 1983. Data gathered with the B-57B during the Joint Airport Weather Studies Project in Denver, Colorado, were analyzed. All runs for Flight 6 on July 16, 1982, were analyzed. Spectra, cross spectra and probability distributions were computed for each run. Also, Runs 10-14 of Flight 7 on July 15, 1982, were analyzed in similar detail.

Frost, W.↗
NASA NTRS1981

Two-dimensional turbulence models

Two-dimensional turbulence models are compared with experimental measurements made using an array of instrumented towers. The spatial correlation coefficient, the two-point spectrum or cross spectrum, and the coherence function are discussed. The prediction techniques in general agree reasonably well with the experimental results. Measurements of the integral length scale however, do not correlate well with the prediction model.

Frost, W.↗