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Lin, S. H.

Publications and source records attributed to Lin, S. H..

11 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Quantum-mechanical approach to predissociation of water dimers in the vibrational adiabatic representation: Importance of channel interactions

The results of application of the quantum-mechanical adiabatic theory to vibrational predissociation (VPD) of water dimers, (H{sub 2}O){sub 2} and (D{sub 2}O){sub 2}, are presented. We consider the VPD processes including the totally symmetric OH mode of the dimer and the bending mode of the fragment. The VPD in the adiabatic representation is induced by breakdown of the vibrational adiabatic approximation, and two types of nonadiabatic coupling matrix elements are involved: one provides the VPD induced by the low-frequency dissociation mode and the other provides the VPD through channel interactions induced by the low-frequency modes. The VPD rate constants were calculated using the Fermi golden rule expression. A closed form for the nonadiabatic transition matrix element between the discrete and continuum states was derived in the Morse potential model. All of the parameters used were obtained from the potential surfaces of the water dimers, which were calculated by the density functional theory procedures. The VPD rate constants for the two processes were calculated in the non-Condon scheme beyond the so-called Condon approximation. The channel interactions in and between the initial and final states were taken into account, and those are found to increase the VPD rates by 3(1) orders of magnitude for the VPD processes in (H{sub 2}O){sub 2} ((D{sub 2}O){sub 2}). The fraction of the bending-excited donor fragments is larger than that of the bending-excited acceptor fragments. The results obtained by quantum-mechanical approach are compared with both experimental and quasi-classical trajectory calculation results.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

Non-Markovian response of ultrafast coherent electronic ring currents in chiral aromatic molecules in a condensed phase

Results of a theoretical study on non-Markov response for femtosecond laser-driven coherent ring currents in chiral aromatic molecules embedded in a condensed phase are presented. Coherent ring currents are generated by coherent excitation of a pair of quasi-degenerated π-electronic excited states. The coherent electronic dynamical behaviors are strongly influenced by interactions between the electronic system and phonon bath in a condensed phase. Here, the bath correlation time is not instantaneous but should be taken to be a finite time in ultrashort time-resolved experiments. In such a case, Markov approximation breaks down. A hierarchical master equation approach for an improved semiclassical Drude dissipation model was adopted to examine the non-Markov effects on ultrafast coherent electronic ring currents of (P)-2,2{sup ′}-biphenol in a condensed phase. Time evolution of the coherent ring current derived in the hierarchical master equation approach was calculated and compared with those in the Drude model in the Markov approximation and in the static limit. The results show how non-Markovian behaviors in quantum beat signals of ring currents depend on the Drude bath damping constant. Effects of temperatures on ultrafast coherent electronic ring currents are also clarified.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

Optoelectronic Integrated Circuits For Neural Networks

Many threshold devices placed on single substrate. Integrated circuits containing optoelectronic threshold elements developed for use as planar arrays of artificial neurons in research on neural-network computers. Mounted with volume holograms recorded in photorefractive crystals serving as dense arrays of variable interconnections between neurons.

Psaltis, D.↗
NASA NTRS1989

Monolithically integrated two-dimensional arrays of optoelectronic threshold devices for neural network applications

A monolithic 10 x 10 two-dimensional array of 'optical neuron' optoelectronic threshold elements for neural network applications has been designed, fabricated, and tested. Overall array dimensions are 5 x 5 mm, while the individual neurons, composed of an LED that is driven by a double-heterojunction bipolar transistor, are 250 x 250 microns. The overall integrated structure exhibited semiconductor-controlled rectifier characteristics, with a breakover voltage of 75 V and a reverse-breakdown voltage of 60 V; this is attributable to the parasitic p-n-p transistor which exists as a result of the sharing of the same n-AlGaAs collector between the transistors and the LED.

Kim, J. H.↗
NASA NTRS1985

Flow formed by spanwise gaps between roughness elements

Measurements of the three mean velocity components and the three Reynolds shear stresses were made in the region downstream of gaps between wall-mounted roughness elements of square cross section and high aspect ratio in a thick turbulent boundary layer. The effect of small and large gaps was studied in a wind tunnel at a Reynolds number of 3600, based on obstacle height and free-stream velocity. The small gap produces retardation of the gap flow as with a two-dimensional roughness element, but a definite interaction between gap and wake flows is observed. The interaction is more intense for the large gap than for the small. Both gaps generate a secondary crossflow which moves fluid away from the centerline in the wall region and toward the centerline in the outer (y greater than 1.5H) region.

Logan, E.↗
NASA NTRS1983

Wakes from arrays of buildings

Experiments were carried out in a small wind tunnel in which atmospheric flow around buildings was simulated. Arrays of one, two, three, and four model buildings were tested, and wake profiles of velocity and turbulence were measured. The data indicate the effect of the buildings on the wind environment encountered by aircraft during landing or takeoff operations. It was possible to use the results to locate the boundaries of the air regions affected by the obstacles and to recommend preferred arrangement of buildings to maximize light safety. Previously announced in STAR as N83-14430

Logan, E., Jr.↗
NASA NTRS1982

Wakes from arrays of buildings

Experiments were carried out in a small wind tunnel in which atmospheric flow around buildings was simulated. Arrays of one, two, three, and four model buildings were tested, and wake profiles of velocity and turbulence were measured. The data indicate the effect of the buildings on the wind environment encountered by aircraft during landing or takeoff operations. It was possible to use the results to locate the boundaries of the air regions affected by the obstacles and to recommend preferred arrangements of buildings to maximize light safety.

Logan, E., Jr.↗
NASA NTRS1982

Wind tunnel measurements of three-dimensional wakes of buildings

Measurements relevant to the effect of buildings on the low level atmospheric boundary layer are presented. A wind tunnel experiment was undertaken to determine the nature of the flow downstream from a gap between two transversely aligned, equal sized models of rectangular cross section. These building models were immersed in an equilibrium turbulent boundary layer which was developed on a smooth floor in a zero longitudinal pressure gradient. Measurements with an inclined (45 degree) hot-wire were made at key positions downstream of models arranged with a large, small, and no gap between them. Hot-wire theory is presented which enables computation of the three mean velocity components, U, V and W, as well as Reynolds stresses. These measurements permit understanding of the character of the wake downstream of laterally spaced buildings. Surface streamline patterns obtained by the oil film method were used to delineate the separation region to the rear of the buildings for a variety of spacings.

Logan, E., Jr.↗