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Linda C. Kah

Publications and source records attributed to Linda C. Kah.

6 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Diverse Organic-Mineral Associations in Jezero Crater, Mars

The presence and distribution of preserved organic matter on the surface of Mars can provide key information about the Martian carbon cycle and the potential of the planet to host life throughout its history. Several types of organic molecules have been previously detected in Martian meteorites1 and at Gale crater, Mars. Evaluating the diversity and detectability of organic matter elsewhere on Mars is important for understanding the extent and diversity of Martian surface processes and the potential availability of carbon sources1,5,6. Here we report the detection of Raman and fluorescence spectra consistent with several species of aromatic organic molecules in the Máaz and Séítah formations within the Crater Floor sequences of Jezero crater, Mars. We report specific fluorescence-mineral associations consistent with many classes of organic molecules occurring in different spatial patterns within these compositionally distinct formations, potentially indicating different fates of carbon across environments. Our findings suggest there may be a diversity of aromatic molecules prevalent on the Martian surface, and these materials persist despite exposure to surface conditions. These potential organic molecules are largely found within minerals linked to aqueous processes, indicating that these processes may have had a key role in organic synthesis, transport or preservation.

Sunanda Sharma↗
NASA NTRS2021

A persistently low level of atmospheric oxygen in Earth’s middle age

Resolving how Earth surface redox conditions evolved through the Proterozoic Eon is fundamental to understanding how biogeochemical cycles have changed through time. The redox sensitivity of cerium relative to other rare earth elements and its uptake in carbonate minerals make the Ce anomaly (Ce/Ce*) a particularly useful proxy for capturing redox conditions in the local marine environment. Here, we report Ce/Ce* data in marine carbonate rocks through 3.5 billion years of Earth’s history, focusing in particular on the mid-Proterozoic Eon (i.e., 1.8 – 0.8 Ga). To better understand the role of atmospheric oxygenation, we use Ce/ Ce* data to estimate the partial pressure of atmospheric oxygen (pO2) through this time. Our thermodynamics-based modeling supports a major rise in atmospheric oxygen level in the aftermath of the Great Oxidation Event (~ 2.4 Ga), followed by invariant pO2 of about 1% of present atmospheric level through most of the Proterozoic Eon (2.4 to 0.65 Ga).

Xiao-Ming Liu↗
NASA NTRS2020

Is a Linear or a Walkabout Protocol More Efficient When Using a Rover to Choose Biologically Relevant Samples in a Small Region of Interest?

We conducted a field test at a potential Mars analog site to provide insight into planning for future robotic missions such as Mars 2020, where science operations must facilitate efficient choice of biologically relevant sampling locations. We compared two data acquisition and decision-making protocols currently used by Mars Science Laboratory: (1) a linear approach, where sites are examined as they are encountered and (2) a walkabout approach, in which the field site is first examined with remote rover instruments to gain an understanding of regional context followed by deployment of time- and power-intensive contact and sampling instruments on a smaller subset of locations. The walkabout method was advantageous in terms of both the time required to execute and a greater confidence in results and interpretations, leading to enhanced ability to tailor follow-on observations to better address key science and sampling goals. This advantage is directly linked to the walkabout method's ability to provide broad geological context earlier in the science analysis process. For Mars 2020, and specifically for small regions to be explored (e.g., <1 sq. km), we recommend that the walkabout approach be considered where possible, to provide early context and time for the science team to develop a coherent suite of hypotheses and robust ways to test them.

R. Aileen Yingst↗
NASA NTRSDate not supplied

Mapping Organic-Mineral Associations in Jezero crater

The search for potential signs of life on Mars, a primary aim of the Mars 2020 mission, is greatly informed by the detection of organic matter1. The presence of organic matter also provides key information about the habitability and biological potential of the planet throughout its history. The Perseverance rover was designed for in situ science with the ability to collect a suite of promising samples for eventual return to Earth. One of its instruments, Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC), is a deep ultraviolet (DUV) Raman and fluorescence spectrometer designed to map the distribution of organic molecules and minerals on rock surfaces at a resolution of 100 μm2. With its unique spectral mapping capabilities, SHERLOC enables a novel understanding of organic-mineral relationships on Mars to better determine their formation, deposition, and preservation mechanisms. The rover’s landing site within Jezero crater combines a high potential for past habitability as the site of an ancient lake basin with a diverse set of minerals, including carbonates and clays, that may preserve organic materials and potential biosignatures. The Jezero crater floor includes three formations (fm); two of these, Máaz and Séítah, were explored as part of the mission’s first campaign. Here, we report the detection of multiple species of aromatic organic molecules using Raman and fluorescence spectroscopy across ten targets in the two formations. This is the first evidence of organic molecules in Martian materials obtained using Raman spectroscopy, and among the first using fluorescence spectroscopy, beyond Earth3. We report specific spatial patterns and classes of organic molecules in these compositionally distinct formations, potentially indicating different fates of carbon in these environments. Our findings indicate that there is a diversity of aromatic molecules prevalent on the Martian surface and these materials persist despite exposure to surface conditions. These organic molecules are largely found within minerals linked to aqueous processes, suggesting that these processes may have had a key role in organic synthesis, transport from their point of origin, or preservation.

Sunanda Sharma↗