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Liu, Junxiu

Publications and source records attributed to Liu, Junxiu.

4 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Pressure-induced suppression of Jahn–Teller distortions and enhanced electronic properties in high-entropy oxide (Mg 0.2 Ni 0.2 Co 0.2 Zn 0.2 Cu 0.2 )O

Jahn–Teller distortions are often observed in Cu II -containing complex oxides resulting in remarkable changes of physical properties. Tuning the Jahn–Teller distortions with pressure has attracted considerable interest but is less studied in Cu II -containing high-entropy oxides (HEOs). We found that pressure can suppress the structural distortions originating from the Jahn–Teller effect of CuO 6 octahedra in the rock salt-type (Mg 0.2 Ni 0.2 Co 0.2 Zn 0.2 Cu 0.2 )O HEO and significantly modify its electronic properties. Synchrotron x-ray diffraction shows that the structural distortions arising from the Jahn–Teller effect of CuO 6 octahedra are progressively suppressed, and the distorted structure evolves into a nearly ideal form under compression. Alternating current impedance and ultraviolet-visible absorption measurements reveal a dramatic resistance drop by more than three orders of magnitude and an obvious bandgap decrease in ~0.1 eV, respectively, accompanied by the pressure-induced suppression of structural distortions. Our study presents a promising route for tuning the structural distortions and the electronic structures of Cu II -containing HEOs for optimizing materials functionalities.

36 MATERIALS SCIENCE↗