Engineering topics
Liu, Zhongyu
Publications and source records attributed to Liu, Zhongyu.
Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters
Abstract Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision materials and attracted wide interest in recent years. One of the unique properties of such nanoclusters pertains to their photoluminescence (PL), for it can widely span visible to near‐infrared–I and –II wavelengths (NIR‐I/II), and even beyond 1700 nm by manipulating the size, structure, and composition. The current research efforts focus on the structure–PL correlation and the development of strategies for raising the PL quantum yields, which is nontrivial when moving from the visible to the near‐infrared wavelengths, especially in the NIR–II regions. This review summarizes the recent progress in the field, including i) the types of PL observed in gold NCs such as fluorescence, phosphorescence, and thermally activated delayed fluorescence, as well as dual emission; ii) some effective strategies that are devised to improve the PL quantum yield (QY) of gold NCs, such as heterometal doping, surface rigidification, and core phonon engineering, with double‐digit QYs for the NIR PL on the horizons; and iii) the applications of luminescent gold NCs in bioimaging, photosensitization, and optoelectronics. Finally, the remaining challenges and opportunities for future research are highlighted.
Dissecting Critical Factors for Electrochemical CO 2 Reduction on Atomically Precise Au Nanoclusters
Here, this work investigates the critical factors impacting electrochemical CO 2 reduction reaction (CO 2 RR) using atomically precise Au nanoclusters (NCs) as electrocatalysts. First, the influence of size on CO 2 RR is studied by precisely controlling NC size in the 1–2.5 nm regime. We find that the electrocatalytic CO partial current density increases for smaller NCs, but the CO Faradaic efficiency (FE) is not directly associated with the NC size. This indicates that the surface-to-volume ratio, i.e. the population of active sites, is the dominant factor for determining the catalytic activity, but the selectivity is not directly impacted by size. Second, we compare the CO 2 RR performance of Au 38 isomers (Au 38 Q and Au 38 T) to reveal that structural rearrangement of identical size NCs can lead to significant changes in both CO 2 RR activity and selectivity. Au 38 Q shows higher activity and selectivity towards CO than Au 38 T, and density functional theory (DFT) calculations reveal that the average formation energy of the key *COOH intermediate on the proposed active sites is significantly lower on Au 38 Q than Au 38 T. These results demonstrate how the structural isomerism can impact stabilization of reaction intermediates as well as the overall CO 2 RR performance of identical size Au NCs. Overall, this work provides important structure–property relationships for tailoring the NCs for CO 2 RR.