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Lockwood, R. A.

Publications and source records attributed to Lockwood, R. A..

Thermoelectric properties of cerium monopnictides

Several cerium pnictides have been synthesized from the pure elements and hot pressed into test samples. Measurements of Seebeck coefficients and electrical resistivities were performed on these samples from room temperature to 1000 C. Cerium arsenide and cerium antimonide are n-type; cerium nitride changes from p-type to n-type conduction at 800 C. The materials are semimetals with resistivities below 1 mohm/cm. Cerium arsenide is the most favorable of the pnictides studied for high-temperature thermoelectric energy conversion, with an average power factor of 15 microW/cm K sq from 500 to 1000 C.

Danielson, L. R.↗

High-Temperature Hall-Effect Apparatus

Compact furnace minimizes thermal gradients and electrical noise. Semiautomatic Hall-effect apparatus takes measurements on refractory semiconductors at temperatures as high as 1,100 degrees C. Intended especially for use with samples of high conductivity and low chargecarrier mobility that exhibit low signal-to-noise ratios, apparatus carefully constructed to avoid spurious electromagnetic and thermoelectric effects that further degrade measurements.

Wood, C.↗

Determining Thermal Diffusivities of Radiating Specimens

Two heat-pulse techniques eliminate uncertainties due to radiation losses. Flashlamp supplies pulse of heat to one side of specimen. Temperatures of illumninated surface and of opposite surface monitored photometrically. In second method, pulse of electrons supplies heat to one side of specimen. Temperature of opposite side monitored by photon detector. Techniques needed because radiation heat losses in this temperature range introduce uncertainties into conventional heat-flux measurements.

Wood, C.↗

Rare earth chalcogenide stoichiometry determination

Rare earth chalcogenides, and particularly lanthanum sulfide, are currently explored as candidate materials for thermoelectric applications. Since the electrical properties of LaS(x) are largely determined by its stoichiometry, a simple and accurate method has been developed for determining the value of x. The procedure involves dissolving a weighted sample in acid and measuring the amount of hydrogen evolved by the lanthanum that is in excess of the 1.500 ratio of S/La. The analytical error in the determination of x in LaS(x) is about 0.001.

Lockwood, R. A.↗