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Longhi, John

Publications and source records attributed to Longhi, John.

Experimental and Modeling Studies of Massif Anorthosites

This termination report covers the latter part of a single research effort spanning several grant cycles. During this time there was a single title, "Experimental and Modeling Studies of Massif Anorthosites", but there were several contract numbers as the mode and location of NASA contract administration changed. Initially, the project was funded as an increment to the PI's other grant, "Early Differentiation of the Moon: Experimental and Modeling Studies", but subsequently it became an independent grant. Table 1 contains a brief summary of the dates and contract numbers.

Longhi, John↗

Early differentiation of the Moon: Experimental and modeling studies and experimental and modeling studies of massif anorthosites

NASA grant NAG9-329 was in effect from 3/1/89 to 8/31/94, the last 18 months being a no-cost extension. While the grant was in effect, the P.I., coworkers, and students gave 22 talks and poster sessions at professional meetings, published 12 articles in referred journals (one more is in press, and another is in review), and edited 2 workshop reports relevant to this project. Copies of all the publications are appended to this report. The major accomplishments during the grant period have derived from three quarters: 1) the application of quantitative models of fractional crystallization and partial melting to various problems in planetary science, such as the petrogenesis of picritic glasses and mare basalts and the implications of the SNC meteorites for martian evolution; 2) an experimental study of silicate liquid immiscibility relevant to early lunar differentiation and the petrogenesis of evolved highlands rocks; and 3) experimental studies of massif anorthosites and related rocks that provide terrestrial analogs for the proposed origin of lunar anorthosites by multistage processes. The low-pressure aspects of the quantitative models were developed by the P.I. in the 1980s with NASA support and culminated with a paper comparing the crystallization of terrestrial and lunar lavas. The basis for the high-pressure modifications to the quantitative models is a data set gleaned from high pressure melting experiments done at Lamont and is supplemented by published data from other labs that constrain the baric and compositional dependences of various liquidus phase boundaries such as olivine/orthopyroxene, relevant to the melting of the mantles of the terrestrial planets. With these models it is possible to predict not only the thermal and compositional evolution of magmatic liquids ranging in composition from lumar mare basalt to terrestrial calc-alkaline basalts, but also the small increments of fractional melting that are produced when mantle rises adiabatically. Copies of the crystallization/melting programs have been given to several colleagues in planetary science. Additionally, a series of computer graphics programs, based on the algorithms in the crystallization programs have been developed that display liquidus diagrams appropriate to input compositions.

Longhi, John↗

Experimental petrology and petrogenesis of mare volcanics

The present review is an extension of a review of experimental studies by Kesson and Lindsley (1976) on mare basalts that determined melting relations over a range of pressure. Pressures of multiple saturation (olivine + pyroxene +/-Cr-rich spinel +/-ilmenite) are in the range of 5 to 12.5 kbar for primitive mare basalts and in the range of 18 to 25 kbar for picritic basalts. High-Ti picrites have augite in the subliquidus region at intermediate pressures where olivine is the liquidus phase, but orthopyroxene is the liquidus phase at multiple saturation. Because of the steep depth/pressure gradient in the outer portion of the moon (20 km/kbar), these pressures imply great depths of melting within the moon and some means of transporting magmas hundreds of kilometers to the surface without significant chemical modification, if both olivine and pyroxene were left in the residuum.

Longhi, John↗

Workshop on the Physics and Chemistry of Magma Oceans from 1 Bar to 4 Mbar

Evidence for the existence of magma oceans is discussed in great detail, and among the many new items introduced were high-pressure phase equilibrium experiments, calculations of depth of impact-produced melting, models incorporating crystal growth rates with degree of crystallinity and convection, and models of hard turbulent convection. It was agreed that before we can point to some present-day observable parameters and confidently establish the existence of magma oceans, we must learn much more about their phase equilibria and solidification dynamics.

Agee, Carl B.↗

Origin of picritic green glass magmas by polybaric fractional fusion

A preliminary presentation is given of a model which explains the picritic lunar mare green glass compositions as composites or magmas derived by polybaric fractional melting. The model accommodates changes in source composition and solidus temperature. As in the Klein and Langmuir model, the final compositions of the melts signify only average depths of melting. The onset of melting is deeper, final segregation is shallower.

Longhi, John↗

The bulk composition, mineralogy and internal structure of Mars

A bulk composition for Mars is derived to a pressure-dependent mineralogy. The density distribution of the present model is compared with density distributions derived from the global gravity field. It is argued that the uppermost Martian mantle is likely to be dominated by olivine and orthopyroxene, as is the earth's upper mantle, although the Martian mantle has a lower MgO/(MgO + FeO) ratio (0.74 vs 0.89). The olivine-peridotite layer extends to a depth of 900 to 1100 km where the transition to silicate spinel begins. Calculations of the high-pressure liquidus and solidus temperatures indicate that for the case of a molten core the minimum temperature at the core-mantle boundary is about 2000 K, whereas for the case of a solid core the maximum temperature is about 1800 K. Summation of the masses in the various layers of Mars yields a value of 0.353 for the dimensionless moment of inertia, which is intermediate between the generally accepted value of 0.365 and the value of 0.345 predicated on a nonaxisymmetric distribution of mass about the Tharsis plateau.

Longhi, John↗

Phase equilibrium constraints on the howardite-eucrite-diogenite association

Model determinations of fractional crystallization and equilibrium partial melting in the 0-10-kbar range have been performed for a series of compositions relevant to diogenite and eucrite petrogenesis. Olivine is found to react with diogenite parent liquids along the plagioclase-absent olivine/low-Ca pyroxene liquidus boundary under conditions of both fractional and equilibrium crystallization up to about 2 kbar. Olivine also reacts with eucritic liquids saturated with plagioclase and low-Ca pyroxene to pressures in excess of 2 kbar. The ability of simple fractional crystallization at 2 kbar to account for mineralogical and chemical features of the diogenite-eucrite association is discussed.

Longhi, John↗

On the connection between mare basalts and picritic volcanic glasses

The liquid lines of descent were calculated for low-pressure equilibrium and fractional crystallization of mare basaltic liquids in order to examine the postulated link between picritic volcanic glasses and mare basalts. The models of Longhi (1977, 1982) were modified by including expressions for the armalcolite/ilmenite surface boundary and the Cr-spinel liquidus surface, average molar partition coefficients for armalcolite/liquid pairs, and new experimental data of Longhi and Pan (1987). The results indicate that, with two exceptions, mare basalts and picritic volcanic glasses are not related by simple, linear-surface crystallization processes. However, the compositions of Luna 24 ferrobasalt and Apollo 11 high-K basalts could be closely matched with the lines of liquid descent of certain green and orange picritic glasses, respectively. The calculations also show that the picritic magmas would have fractionated to produce basalts with bulk and mineral compositions similar to those of mare basalts, supporting the hypothesis that mare basalts have fractionated compositions and that the small number of observed linkages between basalts and picritic parents is a consequence of limited sampling.

Longhi, John↗

What SNC meteorites tell us about Martian magmatism

The SNC meteorites record relatively recent (less than b.y.) basaltic volcanism on a hydrous planet with a core. This much was known about Mars even before the Viking mission. The SNCs tell that the basalts were unusually low in Al2O3 and, despite overall similarities in major elements, apparently sampled two isotopically distinct regions of Mars: one is relatively depleted in incompatible elements (Nahklite source) with a U-Pb model age of 4.3 b.y. and is probably a portion of the upper Martian mantle, whereas the other is relatively enriched in incompatible elements (Shergottite source) with a 4.5 b.y. U-Pb age and is probably Martian crust assimulated into the mantle-derived Shergottite magma. The SNCs tell that the overall abundances of moderately volatile elements, such as alkalies, are higher on Mars than on earth. Given extensive volcanism and a depleted mantle, the present day absence of a thick atmosphere is more likely due to catastrophic removal of a primordial atmosphere than lack of degassing.

Longhi, John↗