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M Zolensky

Publications and source records attributed to M Zolensky.

Unraveling the Complex History of Aqueous Alteration and Metamorphism in CV Chondrite, Camel Donga 040

Camel Donga (CD) 040 is a CV breccia collected from Australia in 1988. Initial studies of CD 040 revealed two lithologies, both containing chondrules up to 1 mm in diameter (some with fine-grained rims) and abundant troilite, but each with remarkably different olivine compositions. Lithology 1 was characterized as petrologic type 3 material, while lithology 2 was described as being “heated to ~1100°C”. CD 040 was initially classified as an ungrouped C3; however, subsequent analyses of oxygen isotopes and bulk rock compositions confirmed that both lithologies were CV chondrite material. Though CD 040 was one of the earliest examples of a CV chondrite containing metamorphosed material, it was never extensively studied. Here we report the results of a detailed study of CD 040, focusing primarily on the petrography and mineral chemistry of metamorphosed lithology.

T L Dunn↗

Contamination Control and Assessment Strategy for Martian Moons Exploration (MMX)

Martian Moons eXploration (MMX) is a sample return mission from the Martian moon Phobos. The MMX spacecraft is scheduled for launch in 2026 and return to Earth in 2031. The primary science objective of MMX is to reveal the origin of the Martian moons, thereby advancing the understanding of planetary system formation and material transport in the solar system, as well as to observe processes affecting the circumplanetary and surface environments of Mars. The returned sample will be transported to the curation facility at ISAS/JAXA, and the subsequent curation and sample analysis activity will be conducted. As a sample return mission, MMX requires strict contamination control to prevent the intrusion of terrestrial materials.

H Sugahara↗

Oxygen-Bearing Organic Components in Ryugu Samples

The Hayabusa2 mission visited the near-Earth Cb-type asteroid (162173) Ryugu and has returned to Earth with the surface material of Ryugu. Ryugu is an airless rubble pile asteroid exposed to space weathering. Initial organic analyses indicate that Ryugu contains aliphatic rich, ketone and carboxyl functional groups, in associated with phyllosilicate and carbonate minerals. Here we investigate the alteration history of Ryugu by comparing the organic content of carbonate-bearing Ryugu samples to that of naturally and experimentally heated meteorites.

Q H S Chan↗

A Doubling of Anthropogenic Solid Contaminants in the Stratosphere as Evidenced By NASA's Cosmic Dust Collection

Every year the Earth’s surface accretes about 40,000 tons of extraterrestrial material less than 1 mm in size. These dust particles originate from active comets, asteroids and the Moon and usually remain for a significant time in the stratosphere of the Earth where they are mixed with terrestrial particles of natural and anthropogenic origin. With the recent increase in space activities (Figure 1) in terms of rocket launches as well as number of objects put into low Earth orbit, one may wonder whether changes in the quantity of anthropogenic material injected in the terrestrial stratosphere can be detected. The NASA Cosmic Dust catalog database is an ideal dataset to test whether this is the case.

J Lasue↗

Direct Analyses of Aqueous Fluids from C-Class Asteroid 162173 Ryugu

Imaging using X-ray absorption contrast by synchrotron nano-computed tomography (47.4 nm/voxel, 7keV) of a Ryugu pyrrhotite crystal revealed probable fluid inclusions. The inclusions were completely encapsuled in pyrrhotite, suggesting the fluids were trapped in the early stages of crystal growth, and filled with low-Z material. We performed Time-of Flight-Secondary Ion Mass Spectrometry (TOF-SIMS) depth profiling and high-resolution mapping at -120°C to exposure and measure the composition of the trapped fluids in a frozen state. These measurements revealed that the ancient, trapped fluids on Ryugu’s parent asteroid were saline aqueous solutions containing H2O, CO2, sulfur species, and nitrogen- and chlorine-bearing organic compounds identified by representative secondary ion species including O(-), OH(-), CO(-), S(-), Cl(-), C2(-), C2H(-), and CN(-). The inferred presence of CO2 indicates formation of the sulfides, and by implication the Ryugu parent body, beyond the H2O and CO2 snow lines of the early solar system, i.e. > 3-4 au from the Sun.

M Zolensky↗

Direct Analysis of Early Solar System Aqueous Fluids by TOF-SIMS

We lack fundamental information related to the location and timing of the aqueous alteration in the early solar system, and the detailed nature of the aqueous fluid itself [1,2,3]. Two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans 1998, hereafter simply “Monahans” (H5) and Zag (H3-6)) contain fluid inclusion-bearing halite (NaCl) crystals [4,5]. The halites were dated by K-Ar, Rb-Sr and I-Xe systematics to be ~4.5 billion years old [4,6,7] and thus the trapped aqueous fluids are at least as ancient. Through previously-published O, H, Cr isotopic work we have established that the fluid-bearing halite originated in the outer solar system[8].

M Zolensky↗

Non-Targeted Direct Infusion Soluble Organic Analysis on a Tarda Meteorite Extract

The differences in chemistry, mineralogy, and structure of chondrites demonstrate thevariations in time/space of their forming regions in the solar nebula. In contrast, the variationof the organic reserves in the solar nebula is unclear. Furthermore, their subsequent evolutionof organic matter on the parent body is still under debate. In a previous study on Tagish Lake(C2 ungrouped) we showed that the primordial soluble organic matter (SOM) could bedistinguished from the parent body's secondary alteration threw mass distribution. This studywill show the Tarda meteorite SOM primordial distribution, using the model from ourprevious study. We discuss its organic reservoirs and secondary alteration effects. We alsocompare the character of the SOM with previously analysed Orgueil (CI). Sample and method: Tarda (fall, 2020) was classified as a C2 ungroup carbonaceouschondrite. Its bulk three oxygen isotope composition is distinct from other chondrite groupsbut similar to CI-chondrite-like and Yamato-type-like [1] values. We analysed themethanol/toluene extract using the high-resolution Orbitrap mass spectrometer at the Institutede Planétologie et d’Astrophysique Grenoble (IPAG) by directly injecting and ionizing theSOM and the solvent using the Heated Electrospray Ionization (HESI) source. After thespectra acquisition, the in-house developed post-processing data analysis tools, Attributor [2],was used. Preliminary Result: The SOM mass distribution of Tarda was well-fitted by the modelinterpreted as the primordial SOM distribution in Tagish lake. This common distributionpattern implies the presence of a common organic reservoir or SOM formation mechanism.Orgueil’s mass spectrum showed a more complex mass-distribution and seemed to be affectedby secondary processes. In contrast to the mass-distribution, SOM’s elemental abundance wasdistinct. The Tarda extract was enriched in S-bearing organic compounds which was incontrast to the Tagish Lake extract consisting of mostly CHNO elements. The presentationwill also discuss the application of our technique to Ryugu or Bennu samples. [1] Meteoriticalbulletin database [2] Orthous-Daunay, F. R. et al. (2019) Geochemical Journal, 53(1), 21-32

J Isa↗

Pneumatic Sampler (P-SAMPLER) for the Martian Moons Exploration (MMX)

The Martian Moons eXploration (MMX) mission, led by the Japanese Aerospace Exploration Agency (JAXA), will focus on the exploration of the two Martian moons – Phobos and Deimos (). The spacecraft will perform close-up remote sensing and observations of both moons, and collect a sample from Phobos for Earth sample return.

D Van Dyne↗

Spectroscopic Investigation of Ungrouped Carbonaceous Chondrites

Carbonaceous (C) chondrites are the most primitive meteorite samples of our solar system. They retain records of their origin, formation mechanisms, evolution and secondary processes. This makes them excellent samples for studies to better understand and shed light on the early history of the solar system. A small fraction of C chondrites is type 2 ungrouped (C2-ung) chondrites. These meteorites could not be easily classified into one of the well-established groups due to compositional/petrological differences and other anomalies [1]. Different starting materials and/or complex post-accretionary processes in the parent bodies may have caused their anomalous compositional properties. As such, chemical characterization of C2-ung chondrites can potentially enable us to differentiate between processes and shed light onto the cosmochemical processes/events that cause such incompatibilities. In this work, we present detailed spectroscopic and imaging data on multiple C2-ung chondrites and compare them with various members of well-established C chondrite groups.

M. Yesiltas↗

Tarda an Unusual Carbonaceous Chondrite Meteorite Fall from Morocco

A fireball with a SW to NE trajectory was widely witnessed from the towns of Alnif, Zagora, Tazarine, and Rich in southern Morocco on the 25th of August 2020, around 2:30 pm Moroccan time (GMT+1). The fall was followed immediately by a search campaign by hundreds of Moroccan hunters and curious people in the area of the likely fall zone. On the following day, the first piece was found close to the village of Tarda between Goulmima and Errachidia. A field mission was conducted, and several eyewitnesses were interviewed. They describe a yellow and bright, barrel-sized fireball with green edges lasting ~3s, and accompanied by a whistling sound, followed by multiple detonations. The meteor produced a thick trail of white smoke that remained suspended for several minutes. The fireball was reported to release little pieces around its edges [1].

H. Chennaoui Aoudjehane↗

Martian Brines in Ancient Salt Lake Beds – A High Priority Target for Mars Sample Return

Mars hosts over 600 chloride deposits as identified from orbital imagery [1-3], including deposits in settings resembling dry, evaporite lacustrine bedforms on Earth. A Mars sample return mission to one of these salt lake beds has a strong potential to directly sample present-day brines originating from ancient martian surface fluids, allowing direct laboratory investigation into fluids, atmosphere, and either potential biology or prebiological conditions on the martian surface at the Noachian through the Hesperian epochs. These sites are extraordinarily well suited for sample return missions because they are favorable for landing and for drill-based sampling, and preserve samples of parent water bodies, including dissolved atmosphere and potential well-preserved biological remains. Such a mission would provide a foundational set of reference samples for understanding Mars’ physiochemical and pre-/biological history, likely to be investigated in depth for generations to come.

brine↗

Direct Measurement of the Composition of Aqueous Fluids from the Parent Body of Asteroid 162173 Ryugu

Imaging using X-ray absorption contrast by synchrotron nano-computed tomography (47.4 nm/voxel, 7keV) of a Ryugu pyrrhotite crystal (C0002-FC012-from the second touch-down site) revealed probable fluid inclusions (Fig. 1A,B) [1]. The inclusions were completely encapsuled in pyrrhotite, suggesting the fluids were trapped in the early stages of crystal growth, and filled with low-Z material. We performed Time-of Flight-Secondary Ion Mass Spectrometry (TOF-SIMS) depth profiling and high-resolution map-ping at -120°C to exposure and measure the composition of the trapped fluids in a frozen state.

M Zolensky↗

Update on Measurement of the Composition of Ryugu Fluid Inclusions

Imaging using X-ray absorption contrast by synchrotron nano-computed tomography of a Ryugu pyrrhotite crystal (C0002-FC012 - from the second Hayabusa2 spacecraft touch-down site) revealed probable fluid inclusions in the center of a crystal of pyrrhotite, suggesting the parent fluids were trapped in the early stages of crystal growth on Ryugu’s parent asteroid. We previously described the performance of Time-of Flight-Secondary Ion Mass Spectrometry (TOF-SIMS) depth profiling and high-resolution mapping at -120°C to expose and measure the composition of the trapped fluids in a frozen state in two Ryugu inclusions [1,2]. Here we report results from follow-on measurements of additional inclusions in the same pyrrhotite crystal, and the initial results of measurement of standards. The ultimate goal is to reveal the quantitative composition of the fluids that caused aqueous alteration, in particular the H2O:CO2 ratio, which will also facilitate cosmochemical modeling of the alteration process.

M Zolensky↗

Assessing Stratospheric Aerosols Contamination Due to Space Activities

The life cycle of a spacecraft starts and ends in the atmosphere: it interacts with the atmosphere right after the launch and during the atmospheric reentry when it usually mostly ablates. Both phases induce emissions of gases and solid particles, providing a source of these components in the middle atmosphere. Little is known about the exact nature, composition and effects of these emissions on the atmosphere and climate, but their impact is expected to rise as more and more orbiting satellites are launched. Ever since the years 2000, the number of space rockets launched per year has increased by a factor 3 globally. At the same time, the number of satellites launched in orbit around the Earth per year has been multiplied by about 30. One may wonder whether changes in the anthropogenic material injected in the terrestrial stratosphere can be detected and what its influence may be. In order to study the cosmic dust particles arriving on Earth, the NASA Johnson Space Center (JSC) has been systematically collecting solid dust particles from the Earth’s stratosphere by aircraft equipped with dedicated particle collectors since 1981. So far, 25 catalogs have been published, covering campaigns of collection from 1981 to 2020, with a total of 5071 solid particles that have been preliminary characterized and curated. In this work, we use the preliminary classification of the dust particles. Based on SEM images and X-ray EDS composition the collected dust is separated into four groups: C (Cosmic), TCN (Terrestrial Contaminant Natural), TCA (Terrestrial Contaminant Artificial) and AOS (Aluminum Oxide Sphere). The AOS being mostly generated by solid rocket propellant, they also belong to the TCA class. Our analysis of the data published indicates that from 1980 to 2009 the cosmic dust particles typically represent on average 40% of the collection with TCA and TCN corresponding to about 30% each. In the recent years, the TCA fraction has doubled to about 60% of the collection (2010-2020). This increase in anthropogenic particles is likely due to the overall human space activity and its recent increase. We will present the properties of the solid stratospheric dust particles collected and their evolution with time. Future work will be dedicated to better classify the natural and anthropogenic particles collected and described in the existing databases. We will use numerical modelling to produce quantitative estimates of the injected mass, the lifetime of particles in the middle atmosphere (stratosphere) and the relative abundance of the anthropogenic particles with respect to the stratospheric background particle population.

J Lasue↗