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Ma, Xiaohang

Publications and source records attributed to Ma, Xiaohang.

Synergistic Retrieval of Temperature and Humidity Profiles from Space-Based and Ground-Based Infrared Sounders Using an Optimal Estimation Method

The atmospheric temperature and humidity profiles of the troposphere are generally measured by radiosondes and satellites, which are essential for analyzing and predicting weather. Nevertheless, the insufficient observation frequencies and low detection accuracy of the boundary layer restricts the description of atmospheric state changes by the temperature and humidity profiles. Therefore, this work focus on retrieving the temperature and humidity profiles using observations of the FengYun-4 (FY-4) Geostationary Interferometric Infrared Sounder (GIIRS) combined with ground-based infrared spectral observations from the Atmospheric Emitted Radiance Interferometer (AERI), which are more accurate than space-based individual retrieval results and have a wider effective retrieval range than ground-based individual retrieval results. Based on the synergistic observations, which are made by matching the space-based and ground-based data with those of different spatial and temporal resolutions, a synergistic retrieval process is proposed to obtain the temperature and humidity profiles at a high frequency under clear-sky conditions based on the optimal estimation method. In this research, using the line-by-line radiative transfer model (LBLRTM) as the forward model for observing simulations, a retrieval experiment was carried out in Qingdao, China, where an AERI is situated. Taking radiosonde data as a reference for comparing the retrieval results of the temperature and humidity profiles of the troposphere, the root-mean-square error (RMSE) of the synergistic retrieval algorithm below 400 hPa is within 2 K for temperature and within 12% for relative humidity. Compared with the GIIRS individual retrieval, the RMSE of temperature and relative humidity for the synergistic method is reduced by 0.13–1.5 K and 2.7–4.4% at 500 hPa, and 0.13–2.1 K and 2.5–7.2% at 900 hPa. Moreover, the forecast index (FI) calculated from the retrieval results shows reasonable consistency with the FIs calculated from the ERA5 reanalysis and from radiosonde data. The synergistic retrieval results have higher temporal resolution than space-based retrieval results and can reflect the changes in the atmospheric state more accurately. Overall, the results demonstrated the promising potential of the synergistic retrieval of temperature and humidity profiles at high accuracy and high temporal resolution under clear-sky conditions from FY-4/GIIRS and AERI.

54 ENVIRONMENTAL SCIENCES↗

Dynamical properties of a room temperature ionic liquid: Using molecular dynamics simulations to implement a dynamic ion cage model [plus supplemental information]

The transport behavior of ionic liquids (ILs) is pivotal for a variety of applications, especially when ILs are used as electrolytes. Many aspects of the transport dynamics of ILs remain to be understood. Here, a common ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BmimNTf 2 ), was studied with molecular dynamics simulations. The results show that BmimNTf 2 displays typical structural relaxation, subdiffusive behavior, and a breakdown of the Stokes-Einstein diffusion relation as in glass-forming liquids. In addition, the simulations show that the translational dynamics, reorientation dynamics, and structural relaxation dynamics are well described by the Vogel-Fulcher-Tammann equation like fragile glass forming liquids. Building on previous work that employed ion cage models, it was found that the diffusion dynamics of the cations and anions were well described by a hopping process random walk where the step time is the ion cage lifetime obtained from the cage correlation function. Detailed analysis of the ion cage structures indicated that the electrostatic potential energy of the ion cage dominates the diffusion dynamics of the caged ion. The ion orientational relaxation dynamics showed that ion reorientation is a necessary step for ion cage restructuring. The dynamic ion cage model description of ion diffusion presented here may have implications for designing ILs to control their transport behavior.

36 MATERIALS SCIENCE↗