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Mack, R.

Publications and source records attributed to Mack, R..

A satellite stereoscopic technique to estimate tropical cyclone intensity

The techniques used to obtain the mean equivalent temperature of the eye wall for Hurricanes Frederic (1979) and Allen (1980) using GOES satellite IR and stereoscopic observations are described. The eye wall is the area of greatest convection near the center of the storm, and is bounded by the inner radius around the eye and the outer radius bounding the area of inner core convection. The stereoscopic capability afforded by the GOES West and East spacecraft permits simultaneous, two-view imagery of a tropical cyclone, yielding height measurement accuracies of 0.5 km and horizontal accuracies as small as 1 km. An airborne lidar unit was used to verify the height measurements made of Hurricane Frederic. At the same time, the GOES East Visible IR Spin Scan Radiometer (VISSR) provided the mean wall temperatures from the release of latent heat. The trials aided in identifying the assumptions and consequent inaccuracies introduced into the temperature sounding data during analysis. The satellite data is concluded useful for monitoring changes in storm intensity.

Rodgers, E. B.

Prebiotic organic syntheses and the origin of life

The outline of a modern paradigm for the origins of life on earth was first formulated by Oparin (1924). According to the considered hypothesis, living organisms arose naturally on the primitive earth through a lengthy process of chemical evolution of organic matter which began in the atmosphere and culminated in the primordial seas. Details regarding the chemical evolution paradigm are discussed, and chemical evolutionary processes formulated by principal contributors are reviewed in a historical context. Attention is given to the Oparin model of the prebiotic earth, the Urey model, the Rubey model, a multistage model for early atmospheric evolution, and other variations on the theme of prebiotic atmospheres. Evidence in support of the chemical evolution paradigm is considered along with modern models regarding the accretion of earth and the formation of its core, and problems and prospects for future studies.

Chang, S.

Stereoscopic observations from meteorological satellites

Stereo cloud top height measurements, accurate to within + or - 500 m, have been performed using operational weather satellites. The stereo has been demonstrated using various combinations of GEO and LEO satellites, and the use of synthetic stereo was considered. Stereo can be done over most of the earth (60 deg S to 60 deg N) during the day; at higher latitudes and at night, stereo can be done using two LEOs if the proper coincidences occur. The usefulness of stereo cloud top height measurements has been demonstrated by many studies of convective storm cloud systems. Recommendations relating to short, medium, and long term planning regarding stereo observations from meteorological satellites are outlined.

Hasler, A. F.

Stereoscopic observations of hurricanes and tornadic thunderstorms from geosynchronous satellites

Results are presented which show the application of GOES stereoscopy to the investigation of hurricanes and tornadic thunderstorms. Stereo cloud top height contour maps were constructed to observe the structural evolution of two hurricanes, Frederic on September 12, 1979 and Allen on August 8, 1980, and a tornadic thunderstorm complex over Oklahoma on May 2-3, 1979. Stereo height contours of Hurricane Allen reveal a very intense and symmetric storm with a circular shaped central dense overcast with an average height of 16.5 km. Contours of Hurricane Frederic reveal a preferred region for convection with an explosive exhaust tower attaining a maximum height of 17.8 km. Also presented is a technique for estimating tropical cyclone intensity using GOES stereo height and IR temperature information. Results indicate vertical motions ranging from 4.4 m/s for a moderate storm to 7.7 m/s for an intense storm.

Mack, R.

Noble-gas-rich separates from the Allende meteorite

Predominantly carbonaceous HF/HCl-resistant residues from the Allende meteorite are studied. Samples are characterized by SEM/EDXA, X-ray diffraction, INAA, C, S, H, N, and noble gas analyses. Isotopic data for carbon show variations no greater than 5%, while isotopic data from noble gases confirm previously established systematics. Noble gas abundances correlate with those of C and N, and concomitant partial loss of C and normal trapped gas occur during treatments with oxidizing acids. HF/HCl demineralization of bulk meteorite results in similar fractional losses of C and trapped noble gases, which leads to the conclusion that various macromolecular carbonaceous substances serve as the main host phase for normal trapped noble gases and anomalous gases in acid-resistant residues, and as the carrier of the major part of trapped noble gases lost during HF/HCl demineralization. Limits on the possible abundances of dense mineralic host phases in the residues are obtained, and considerations of the nucleogenetic origin for CCF-XE indicate that carbonaceous host phases and various forms of organic matter in carbonaceous meteorites may have a presolar origin.

Ott, U.

Mars ultraviolet simulation facility

A facility was established for long-duration ultraviolet (UV) radiation exposure of natural and synthetic materials in order to test hypotheses concerning Martian soil chemistry observed by the Viking Mars landers. The system utilized a 2500 watt xenon lamp as the radiation source, with the beam passing through a heat-dissipating water filter before impinging upon an exposure chamber containing the samples to be irradiated. The chamber was designed to allow for continuous tumbling of the samples, maintenance of temperatures below 0 C during exposure, and monitoring of beam intensity. The facility also provided for sample preparation under a variety of atmospheric conditions, in addition to the Mars nominal. As many as 33 sealed sample ampules have been irradiated in a single exposure. Over 100 samples have been irradiated for approximately 100 to 700 h. The facility has performed well in providing continuous UV irradiation of multiple samples for long periods of time under simulated Mars atmospheric and thermal conditions.

Zill, L. P.

Heterogeneous phase reactions of Martian volatiles with putative regolith minerals

The chemical reactivity of several minerals thought to be present in Martian fines is tested with respect to gases known in the Martian atmosphere. In these experiments, liquid water is excluded from the system, environmental temperatures are maintained below 0 C, and the solar illumination spectrum is stimulated in the visible and UV using a xenon arc lamp. Reactions are detected by mass spectrometric analysis of the gas phase over solid samples. No reactions were detected for Mars nominal gas over sulfates, nitrates, chloride, nontronite clay, or magnetite. Oxidation was not observed for basaltic glass, nontronite, and magnetite. However, experiments incorporating SO2 gas an expected product of volcanism and intrusive volatile release - gave positive results. Displacement of CO2 by SO2 occurred in all four carbonates tested. These reactions are catalyzed by irradiation with the solar simulator. A calcium nitrate hydrate released NO2 in the presence of SO2. These results have implications for the cycling of atmospheric CO2, H2O, and N2 through the regolith.

Clark, B. C.

Noble gas trapping and fractionation during synthesis of carbonaceous matter

An investigation of noble gas entrapment during synthesis of carbonaceous, macromolecular, and kerogen-like substances is presented. High molecular weight organic matter synthesized in aqueous condensation reactions contained little gas, and the composition was consistent with fractionation due to noble gas solubility in water; however, propane soot produced during a modified Miller-Urey experiment in an aritificial gas mixture contained high concentrations of trapped noble gases that displayed strong elemental fractionation from their reservoirs. It is concluded that theses experiemnts show that processes exist for synthesis of carbonaceous carriers that result in high noble gas concentrations and strong elemental fractionation at temperatures well above those required by absorption to achieve similar effects.

Frick, U.