Engineering topics
Mallow, Anne
Publications and source records attributed to Mallow, Anne.
Metal Hydride Compression
Conventional hydrogen compressors often contribute over half of the cost of hydrogen stations, have poor reliability, and have insufficient flow rates for a mature fuel cell vehicle market. Fatigue associated with their moving parts including cracking of diaphragms and failure of seals leads to failure in conventional compressors, which is exacerbated by the repeated starts and stops expected at fueling stations. Furthermore, the conventional lubrication of these compressors with oil is generally unacceptable at fueling stations due to potential fuel contamination. MH technology offers a very good alternative to both conventional (mechanical) and newly developed (electrochemical, ionic liquid pistons) methods of hydrogen compression. Advantages of MH compression include simplicity in design and operation, absence of moving parts, compactness, safety and reliability, and the possibility to utilize waste industrial heat to power the compressor. Beyond conventional H 2 supply via pipelines or tanker trucks, another attractive scenario is the on-site generation and delivery of pure H 2 at pressure (> 875 bar) for refueling vehicles at electrolysis, wind, or solar H 2 production facilities in distributed locations that are too remote or widely distributed for cost effective bulk transport. MH hydrogen compression utilizes a reversible heat-driven interaction of a hydride-forming metal alloy with hydrogen gas to form the MH phase and is a promising process for hydrogen energy applications. To deliver hydrogen continuously, each stage of the compressor must consist of multiple MH beds with synchronized hydrogenation & dehydrogenation cycles. Multistage pressurization allows achievement of greater compression ratios using reduced temperature swings compared to single stage compressors. The objectives of this project are to investigate and demonstrate on a laboratory scale a twostage MH hydrogen gas compressor with a feed pressure of >100 bar and a delivery pressure > 875 bar of high purity H 2 gas using the scheme shown in Figure 1. Progress to date includes the selection of metal hydrides for each compressor stage based on experimental characterization of their thermodynamics, kinetics, and hydrogen capacities for optimal performance with respect to energy requirements and efficiency. Additionally, final bed designs have been completed based on trade studies and all components have been ordered. The prototype two-stage compressor will be fabricated, assembled, and experimentally evaluated in FY19.
Review of Inorganic Salt Hydrates with Phase Change Temperature in Range of 5°C to 60°C and Material Cost Comparison with Common Waxes
Phase change materials (PCMs) with desirable phase change temperatures can be used to provide a constant temperature thermal source or sink for diverse applications. As such, incorporating PCMs into building materials, equipment, or appliances can shift and/or reduce the energy load. The motivation of this work is to identify low-cost inorganic salt hydrate PCMs that can complement current building systems and designs, and compare them with common paraffins.In this work, we analyzed inorganic salt hydrates with phase change temperatures in the range of 5-60°C, to target both space heating and cooling applications. The properties of the salt hydrates were compared with paraffins over the same temperature range. The results showed that PCMs with a melting temperature above 20°C, salt hydrates have advantages over paraffins including higher thermal energy density (45-120 kWh/m3 for salt hydrates; 45-60 kWh/m3 for paraffins) and generally lower material energy cost (1-20 $/kWh for salt hydrates; 20-30 $/kWh for comparable paraffins). For PCMs with a melting temperature less than 20°C, the material cost is higher for both salt hydrates and paraffins (30-110 $/kWh for both classes of materials) and salt hydrates retain their advantage of greater thermal energy density (50-120 kWh/m3 for salt hydrates; 45-60 kWh/m3 for paraffins). In all cases, factors including thermal cyclability, stability, congruency, corrosion, and supercooling must be considered when comparing paraffins and salt hydrates for a particular application. Finally, we give an overview of enhancement techniques for salt hydrate PCMs and find that limited efforts have been pursued to tune salt hydrate phase change temperatures, with a wider range of studies investigating stabilization and minimization of supercooling. This analysis shows the potential of developing salt hydrate PCMs for low-cost heating and cooling thermal energy storage systems for a range of applications.
Experimental Study on Portable Air-Conditioning System with Enhanced PCM Condenser
A portable personal air-conditioning system with a vapor compression cycle (VCC), electrical battery, and thermal battery is an attractive option for localized cooling as compared with stationary air-conditioning systems. A phase change material (PCM) can be used for storing waste heat from the VCC condenser, thereby acting as a thermal battery. In the PCM condenser, copper tubes are submerged in the PCM container. Due to the low thermal conductivity of pure PCM, the overall heat transfer coefficient of the PCM condenser is limited resulting in high VCC condensing pressure and thus, low VCC coefficient of performance (COP). Therefore, it is necessary to improve VCC system performances by applying heat transfer augmentation in PCM. In this work, a portable air-conditioning system with heat transfer enhanced PCM that stores heat from condenser during VCC operation and is regenerated by a thermosyphon operation is proposed. The system also includes a receiver to address the charge difference between the thermosyphon and the VCC operation. The paper experimentally studies the effects of the following three types of enhanced PCM condensers on the system performance: (1) copper mesh enhanced PCM with helically coiled copper tube branches and large refrigerant distribution headers (CMPHX), (2) graphite matrix enhanced PCM with straight copper tube branches and small headers (GMPHX1), and (3) graphite matrix enhanced PCM with straight copper tube branches and large headers (GMPHX2). Results show that this system operates properly and effectively during both VCC and PCM regeneration operations. The system can provide four hours of continuous cooling, and the PCM can be fully regenerated after 7.4 hours by thermosyphon operation. The comparisons of three PCM condensers indicate that the system with GMPHX2 performs the best with the average VCC COP of 4.7. The VCC system with CMPHX has an average COP of 4.2, and GMPHX1 has an average COP of 3.1. GMPHX2 has the best heat transfer enhancement with an overall heat transfer coefficient of 632.1 W∙m-2∙K-1, which is more than twice of GMPHX1 and five times of CMPHX. Moreover, GMPHX2 can achieve more uniform refrigerant flows and PCM temperature distributions than GMPHX1. This leads to the higher utilization ratio of PCM latent heat. CMPHX is the second best but needs larger heat transfer surface area and inner volume as well as more refrigerant charge. In conclusion, the system design with GMPHX2 is recommended due to its small refrigerant charge, high VCC COP, and the use of good heat transfer enhancement material.
Enhancing the thermosiphon-driven discharge of a latent heat thermal storage system used in a personal cooling device
Personal cooling devices reduce energy loads by allowing buildings to operate with elevated setpoint temperatures, without compromising on the occupant comfort. One such novel technology called the Roving Comforter (RoCo) uses a compact R134a based vapor compression system for cooling. Following its cooling operation, during which waste heat from the condensing refrigerant is stored in a phase change material (PCM), a two-phase loop thermosiphon is used to discharge (solidify) the PCM to enable its next operation. The transient operation of this thermosiphon is the focus of the present paper. Use of a PCM as the storage medium provides high energy density due to the ability to store thermal energy as latent heat during the phase transition; however, the discharge rate is limited by the low thermal conductivity of the PCM. Insertion of a graphite foam within the PCM can increase the rate of discharge and decrease the downtime of the cooling device. Since graphite enhancement involves a tradeoff between improving the discharge time at the expense of PCM volumetric latent heat, the impact of graphite foam density on the PCM discharge rate is investigated by using a Modelica-based transient model of the thermosiphon. The semi-empirical model, which uses relevant heat transfer coefficient and pressure drop correlations for both refrigerant and airside heat transfer, captures the complex phenomena involving simultaneous phase change of the refrigerant and the PCM. Finally, the graphite enhanced PCM selected from this analysis results in a 51% reduction in the discharge time with addition of only 5% to the thermal storage weight, without compromising the required cooling time.
Personal cooling and the Roving Comforter
Today we heat and cool buildings to a single target temperature. Some problems with this conventional regime can be readily observed: first, people have differing opinions of the appropriate target temperature; and second, conditioning a whole building requires much more energy than conditioning the air immediately surrounding the occupants. In contrast to most conventional approaches to decreasing energy consumption, personal cooling offers a plug and play solution by providing localized space conditioning directly to individuals. Furthermore, this shift in perspective, from the room air temperature to the individual, opens new possibilities to enable more sustainable cooling architectures for energy efficient space and building design at lower cost.