Engineering topics
Publications and source records attributed to McGrane, Shawn D..
Disclosed herein are embodiments of devices comprising energetic materials capable of superdetonation and methods of making and using such devices. The devices disclosed herein comprise components, dimensions, and configurations optimized to utilize superdetonation velocities produced by the energetic materials disclosed herein.
Disclosed herein are embodiments of devices comprising energetic materials capable of superdetonation and methods of making and using such devices. The devices disclosed herein comprise components, dimensions, and configurations optimized to utilize superdetonation velocities produced by the energetic materials disclosed herein.
The number and capability of explosives detection and analysis methods have increased substantially since the publication of the Analytical and Bioanalytical Chemistry special issue devoted to Explosives Analysis (Moore and Goodpaster, Anal Bioanal Chem 395(2):245–246, 2009). We review and critically evaluate the latest (the past five years) important advances in explosives detection, with details of the improvements over previous methods, and suggest possible avenues towards further advances in, e.g., stand-off distance, detection limit, selectivity, and penetration through camouflage or packaging. The review consists of two parts. Moreover, Part I, reviews methods based on animals, chemicals (including colorimetry, molecularly imprinted polymers, electrochemistry, and immunochemistry), ions (both ion-mobility spectrometry and mass spectrometry), and mechanical devices. Part II will review methods based on photons, from very energetic photons including X-rays and gamma rays down to the terahertz range, and neutrons.
The number and capability of explosives detection and analysis methods have increased dramatically since publication of the Analytical and Bioanalytical Chemistry special issue devoted to Explosives Analysis [Moore DS, Goodpaster JV, Anal Bioanal Chem 395:245–246, 2009]. Here we review and critically evaluate the latest (the past five years) important advances in explosives detection, with details of the improvements over previous methods, and suggest possible avenues towards further advances in, e.g., stand-off distance, detection limit, selectivity, and penetration through camouflage or packaging. Our review consists of two parts. Part I discussed methods based on animals, chemicals (including colorimetry, molecularly imprinted polymers, electrochemistry, and immunochemistry), ions (both ion-mobility spectrometry and mass spectrometry), and mechanical devices. In Part II, we review methods based on photons, from very energetic photons including X-rays and gamma rays down to the terahertz range, and neutrons.
Explore the source record for details and available documents.
Abstract Not Provided
The principle goal of this $\$$150K/yr, 3-yr. project was to experimentally measure the time evolution of shock induced chemistry in the explosive RDX. Since direct measurements of shock induced chemistry in RDX, or any other explosive, have eluded researchers for several decades, new techniques had to be developed. Transient absorption was coupled to laser shock loading to probe the possible role of electronic excitations in the chemistry of RDX. Transient absorption signatures turned out to be a good indication of the relative degree of chemical reaction versus time, but were not conclusive regarding whether electronic excitation was an important factor in shock initiation. Preliminary efforts to sensitize shock induced chemistry with ultraviolet pulsed excitation were performed, but are not yet conclusive. The bulk of the effort of the project was directed at development of femtosecond stimulated Raman spectroscopy (FSRS) as a diagnostic of temperature in the presence of chemistry. This effort was significantly more difficult than initially anticipated. While we had planned to apply the method to single shot laser experiments, the sensitivity achieved during the project duration was insufficient to measure the sub-nanogram amounts of material shocked. Despite the difficulties applying this measurement to our current small scale laser shock experiments, it shows significant promise for measurements where there is more volume of material shocked. We have established the theoretical framework and experimentally validated FSRS as a sub-picosecond molecular vibrational temperature measurement diagnostic. We have also followed the shock induced chemistry of RDX through transient absorption spectroscopy and established the shock stresses required to achieve sub-nanosecond reaction rates. The project led to 3 peer reviewed journal articles, 4 conference proceedings, 3 invited talks at conferences, 2 contributed talks at conferences, and a number of other presentations.
Abstract not provided.