Engineering topics

McLaughlin, Fred

Publications and source records attributed to McLaughlin, Fred.

6 records

DOE OSTI2025

Hero Carbonsafe Phase 2 Project in the Columbia River Basalt Group: Technical Program Overview

The Hermiston, Oregon Basalt CarbonSAFE Phase II project (HERO CarbonSAFE) seeks to accelerate the deployment of commercial carbon dioxide (CO2) storage projects in basaltic rocks. Hermiston is located near the center of the Columbia River Basalt Group (CRBG), which is one of the largest basalt flows in the US. Basalt CO2 storage has potential advantages to conventional saline storage reservoirs including 1. The potential for rapid mineralization of CO2, 2. associated decreases in pressure and CO2 migration risks, 3. reduced long-term monitoring requirements with respect to plume tracking, 4. widespread geographic distribution and, 5. large storage potential due to thickness, porosity, and CO2 interactions with basalt. For locations such as the Pacific Northwest (PNW), Hawaii, Iceland, India and Japan, whose localities are isolated from large sedimentary basins offering conventional saline storage options, basalt may offer the only feasible option for local CO2 storage. However, mineralization/basalt storage still has many uncertainties, as there are limited field-scale assessments of CO2 storage in basalt. There are significant uncertainties hindering the effective implementation of carbon capture utilization and storage (CCUS) in basalt. These include the lack of proven storage capacities, challenges in methodologies for modeling the area of review in igneous formations, limited understanding of mineralization kinetics and timing, and uncertainties in injectivity. Additionally, the domestic availability of specialized services and drilling expertise is constrained, and existing CCUS permitting and regulatory frameworks, originally developed for conventional saline reservoirs, may not adequately address the unique requirements of basalt systems. HERO CarbonSAFE is designed to address major research gaps and uncertainties associated with basalt storage. Specifically, the project will assess the feasibility of CO2 injection in the deep layered basalts of the CRBG, long-term storage (mineralization), practical approaches for large-scale implementation (50+ million metric tons of CO2 over 30 years), lithology-specific risks, and the technoeconomic potential for CO2 storage in basalts.

58 GEOSCIENCES↗

DOE OSTI2023

Critical Minerals and Rare Earth Elements in Powder River Basin Coal and Associated Sediments, Wyoming, USA

The demand for Rare Earth Elements (REE) and other critical minerals (CM) required for consumer products, defense-related applications, and low-carbon energy technology is increasing rapidly. Unconventional sources of REE/CM, such as coal and associated sediments, could prove very important in building resilient and ethical energy supply chains. Utilization of existing infrastructure and the highly trained energy workforce in traditionally coal-producing regions in emerging REE/CM industries could provide an economic boost to coal communities. The Powder River Basin (PRB) of Wyoming and Montana, USA, is a prime candidate to investigate the feasibility of extracting REE/CM from coal and associated sediments. The PRB hosts thick (>50 ft) coal seams that are mined at the surface and more than 40% of the coal produced in the US comes from the PRB. Geochemical data from multiple locations in PRB coal systems show REE enrichments at the top and bottom margins and at internal partings in coal seams. This trend is exhibited in two cores drilled at Peabody’s North Antelope Rochelle mine in the east central PRB, the largest coal mine in the world. The two cores include the Wyodak Anderson coal zone as well as the over- and underlying shale units. The Wyodak Anderson coal zone is part of the Paleocene Tongue River Member of the Fort Union Formation in which most of the coal resources in the PRB reside. To understand REE/CM enrichment, a total of 188 samples were analyzed for their major and trace element chemistry from both cores, sampled at one foot or smaller intervals. The two cores show distinct REE enrichments in the uppermost and lowermost 3 to 12 feet of the Wyodak Anderson coal zone, as well as enrichments in bounding carbonaceous shale units. Total REE+Y (REY) concentrations as high as 2510 ppm (all concentrations reported on an ash basis), or 15 times average upper continental crust values (Taylor and McLennan, 1995), were identified in the coal. Partings within the coal zone also show relative REE enrichment, with concentrations up to 485 ppm REY. The remaining interior portions of the coal zone contain lower concentrations of REE, resulting in an average REY for all samples from both cores of 288 ppm. The proportion of high-value critical REE (Nd, Eu, Tb, Dy, Er, Y) compared to REY averages 36%, which is higher than the critical REE proportion in average upper continental crust of 33%. This finding highlights the relative enrichment of middle REE compared to light REE, in contrast to many conventional REE deposits. Other critical trace elements that show enrichments above average upper continental crust include Ga, Nb, and V. Within this sample suite, Ga concentrations range from 2.8 to 213 ppm, with an average of 29 ppm; Nb from 2.9 to 166 ppm with an average of 26 ppm; and V from 27 to 1695 ppm with an average of 188 ppm. None of these trace elements exhibit the same distinct pattern of enrichment as REE in the upper and lower bounding layers and internal partings of the coal zone. Major element chemistry indicates CaO concentrations averaging ~25% in the coal samples from both cores, which has important implications for the extractability of REE from coal. Calcium-rich PRB coal has been shown to be more amenable to REE extraction than lower calcium coals by some methods (Stuckman et al., 2019; Taggart et al., 2016), highlighting the importance of REE extractability in addition to REE concentration in assessing the value of potential feedstocks. The original coal resource in the PRB is estimated at 1.16 trillion short tons (Luppens et al., 2015). Thus, the PRB represents an important potential unconventional source for REE and other CM. Ongoing research to fully characterize the REE/CM resource, identify enrichment mechanisms, and further develop and scale extraction technologies is necessary to understand the full potential of this resource.

Phillips, Erin↗

DOE OSTI2023

Critical Minerals from Waste Streams in the Powder River Basin of Wyoming and Montana, USA

Background/Objectives. Critical minerals (CM) are essential for numerous industrial and defense applications, including green technologies that will help to meet carbon emission reduction goals. Many CM are currently mined and processed in countries that lack stringent environmental and labor regulations. Unconventional sources such as existing industrial waste streams could play a part in building an ethical CM supply chain. Additionally, waste streams created in the extraction and processing of CM could be used for other industrial or commercial purposes, thereby reducing waste and advancing a circular economy. Approach/Activities. The Department of Energy funded Powder River Basin (PRB) CORE-CM project is exploring all aspects of the carbon ore, rare earth element (REE), and CM value chain, including the potential for extraction of CM from industrial waste streams in the basin. Waste streams that have potential as CM feedstocks are being inventoried to assess the concentration of CM in each waste stream and to estimate volume and accessibility. Although basin-specific technologies for extraction of CM are still in development, waste streams that may be produced during these processes are being cataloged and mapped to potential secondary uses. Results/Lessons Learned. Initial studies of the CM potential of PRB coal ash show that this waste stream contains concentrations of greater than 300 ppm total REE (Bagdonas et al., 2022, Renewable and Sustainable Energy Reviews). Moreover, calcium-rich PRB coal ash is amenable to REE extraction (Taggart et al., 2016, Environmental Science and Technology). Wyoming coal is shipped to 28 states, meaning that coal ash produced at power stations across the US represents a potential widespread resource for the extraction of REE. In addition to coal mining and coal fired electricity generation, the PRB is home to other energy industries including oil and gas production, in-situ uranium mining, and bentonite mining. Historically, precious and base metal mining has taken place on the perimeter of the PRB. Waste streams from these industries are currently being evaluated for their CM potential. Assessing the CM resource potential of waste streams could contribute to the development of an ethical CM supply chain. Results from these studies can be replicated for other waste streams, increasing the likelihood of successful creation of circular economies.

Phillips, Erin↗

DOE OSTI2021

Raman Microscopy Analysis of Wyoming CarbonSAFE Pilot Well Thin Sections for Mineralogy and Organic Matter Characterization

Scanning confocal Raman microspectroscopy (RMS) was used to analyze thin sections for inorganic mineral content and for evaluation of organic material (OM). Thin sections were selected from a stratigraphic test well core in the Powder River Basin, Wyoming under the Wyoming CarbonSAFE project. The well was analyzed with a variety of rock and fluid characterization techniques to determine the feasibility of a commercial-scale CO2 storage site. RMS complements other analyses, including traditional petrography, SEM, porosity and permeability, and XRD For this aspect of the study, RMS is especially important in the evaluation of OM in sealing lithologies. At prospective geologic CO2 storage sites, it is imperative to assess the unconventional oil and gas potential of seals to ensure that any future development would not compromise the integrity of the seals. Whole-slide mineralogical surveys were performed on thin sections from various shale and sandstone formations. Surveys were analyzed with Direct Classical Least Squares to identify and quantify minerals. The location and concentration of minerals was color-coded and overlaid on optical images for visualization of the distribution of minerals. Dense hyperspectral Raman mapping of OM was performed on five thin sections. Eleven spectral parameters diagnostic of organic type and thermal maturity were used to train a Partial Least Squares (PLS) calibration against a set of artificially matured samples spanning the pre- to mid-oil window. The PLS was applied to the study set and a post-mature set. Additionally, the PLS was applied to each point in hyperspectral maps for visualization of trends in maturity across sample sets and discrimination of organic matter types within a given map. In inorganic surveys on thin sections, a total of 14 unique inorganic minerals were identified in Raman spectra including quartz, dolomite, calcite, hematite and anhydrite. Shale thin sections tended to be dominated by organic material. OM was often observed mixed with inorganic minerals. Sand- and mudstones were dominated by inorganic minerals. The PLS extrapolated the post-mature set to reflectances >1.2%. The study set ranged from very immature to postmature in the median of map fit-peak parameters. However, point maturity maps indicate that matrix OM in all study samples is immature and that discreet organic particles selected for mapping, which may be inertinites, bias medians towards more-mature. The work demonstrates the capabilities of RMS to perform both whole-slide mineralogy and OM analysis with applications to formation evaluation in oil & gas, carbon sequestration and mining. Here, analysis of sealing formations in the well indicates high levels of immature organic matter that would not be a viable target for future oil production that could compromise the CO2 storage site. The work brings together diverse disciplines from geology and petrography to analytical chemistry, big data and microscopy.

Myers, Grant↗

DOE OSTI2021

Wyoming CarbonSAFE: Advancing Commercialization of Low-Carbon Energy Technologies in Fossil-Rich Wyoming

Wyoming’s Powder River Basin (PRB) is the most prolific coal producer and exporter in the United States and the State of Wyoming’s largest oil-producing basin. In addition to being a leading energy producer, the PRB is the site of research programs whose aim is to develop and integrate low-carbon technologies into existing fossil fuel energy industries. Much of the PRB’s low-carbon research is focused around Dry Fork Station (DFS), which is the newest coal-fired power station in the western US. Currently, DFS hosts five carbon capture projects, including pilot-scale capture projects that utilize different capture technologies and a full front-end engineering and design (FEED) study, a commercial CO 2 pipeline for nearby CO 2 -enhanced oil recovery industry, and is also co-located with the Wyoming Integrated Test Center, which is a host facility for unconventional carbon utilization research (i.e. flue gas carbon-to-products innovations). DFS is also the host site for the Wyoming CarbonSAFE project. Wyoming CarbonSAFE, funded by the Department of Energy/National Energy Technology Laboratory, is a multi-phased program (currently in Phase II) whose core objective is developing and validating storage sites within a complex capable of storing 50 million metric tonnes of CO 2 over a 30 year project period using carbon capture, utilization and storage (CCUS). This paper will provide an overview of the project to-date, showing that CarbonSAFE goals are achievable with respect to geologic, environmental, regulatory, CO 2 source and economic conditions, and why the State of Wyoming offers one of the more favorable environments to advance the commercialization studies. In 2019, the project team designed and completed a ~10,000 foot stratigraphic test well just south of DFS. From this well, the team collected over 600 feet of core, fluid samples from target injection zones, and a full petrophysical log suite. In addition, legacy 2D seismic lines were acquired and a 3D seismic survey was acquired in the fall of 2020. The objective of these field activities has been to identify and characterize target storage reservoirs and associated caprock. This complex has several reservoirs that could meet commercial injection goals, and over 4000 feet of associated caprock. Simulations of site performance suggest that stacked injection provides the most effective storage strategy, and would necessitate several sites within the greater complex to meet final project injection goals. Other work within this project includes the development of a business-case around proximal fields with CO 2 -enhanced oil recovery potential and existing tax credits, assessment of regulatory conditions, including pore space ownership and Class VI injection well permitting requirements, implementation of a robust public outreach Electronic copy available at: https://ssrn.com/abstract=3821220 GHGT-15 McLaughlin 2 program, and surface site characterization activities that have focused on environmental factors. In the PRB and at DFS, the State of Wyoming and other entities have made carbon management a priority of its future energy industry by providing a regulatory and business framework that is favorable to advancing these technologies. These endeavors will become more realistic with the successful implementation of Wyoming CarbonSAFE, and its ability to secure and validate commercial-scale CCUS at the center of Wyoming’s premier low-carbon research efforts.

McLaughlin, Fred↗

DOE OSTI2020

Impact of sub-core scale heterogeneity on CO2/brine multiphase flow for geological carbon storage in the Minnelusa sandstone

CO2 geological storage in deep saline aquifers is a mitigation option for CO2 emissions due to its large storage capacity and immediate accessibility. Accurately determining the CO2-brine relative permeability curves is key to the evaluation of CO2 injectivity and sweep efficiency in reservoir simulation as well as the CO2 injection in the field. This study highlights the remarkable effects of sub-core scale heterogeneity on the CO2-brine multiphase flow properties of the Minnelusa Sandstone in Wyoming. Two unsteady state CO2-brine drainage experiments were performed on the two samples. The first sample exhibits slanted laminated structure, while the second one represents a more homogeneous sandstone system. The CO2 saturation distributions during drainage reveals that the main variation in multiphase flow properties of two core samples were attributed to the porosity distribution that leads to the capillary pressure heterogeneity. Assisted history matching was used to obtain the respective relative permeability curves, which suggests heterogeneity-dependent behavior. In addition, sensitive and uncertainty analyses indicate that physical and petro-physical properties of low-porosity and low-permeability bedding layers exert marked effects on CO2 front breakthrough time and brine production. The results presented in this study help to gain insight into the CO2-brine multiphase flow properties in heterogeneous sandstones and can pave the way for the upscaling of CO2 migration and field-scale simulation accurately. This work is funded under the Department of Energy CarbonSAFE program (awards DE-FE0031624 DE0031891).

Kou, Zuhao↗