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McLaughlin, J. Fred

Publications and source records attributed to McLaughlin, J. Fred.

HERO CarbonSAFE Phase 2 Project in the Columbia River Basalt Group

The Hermiston, Oregon Basalt CarbonSAFE Phase II project (HERO CarbonSAFE) seeks to accelerate the deployment of commercial carbon dioxide (CO2) storage projects in basaltic rocks. Basalt CO2 storage has several advantages to conventional saline storage reservoirs including 1. The potential for rapid mineralization of CO2, 2. Associated decreases in pressure and CO2 migration risks, 3. Reduced long-term monitoring requirements with respect to plume tracking, 4. Widespread geographic distribution and, 5. Large storage potential due to thickness, porosity, and CO2 interactions with basalt. And for locations such as the Pacific Northwest, Hawaii, Iceland, India and Japan, basalts may offer the only economically feasible option for local CO2 storage. However, there are limited field-scale assessments of CO2 storage in basalt, and current carbon capture utilization and storage (CCUS) permitting and regulatory frameworks were developed for conventional saline reservoirs. HERO CarbonSAFE is designed to address research gaps and uncertainties associated with basalt storage. Specifically, the project will assess the feasibility of CO2 injection in the deep layered basalts, long-term storage (mineralization), practical approaches for large-scale implementation (50+ million metric tons of CO2 over 30 years), lithology-specific risks, and the technoeconomic potential for CO2 storage in basalts. The HERO CarbonSAFE project will assess feasibility of developing a commercial-scale (50+ million metric tons of CO2) geological storage complex within the Columbia River Basalt Group (CRBG), a layered continental flood basalt complex that underlies Calpine’s natural gas-fired Hermiston Power Project (HPP) in Hermiston, OR (Figure 1). Under this 2-year CarbonSAFE Phase II project, the HERO team will conduct a data acquisition campaign that includes drilling a stratigraphic well to a total depth of ~1,500 m into the thick layered basalts proximal to HPP. A comprehensive well logging and hydrologic testing program will be augmented with new core collected from flow zones and sealing units, and comprehensive laboratory testing to help refine the kinetic rates of mineralization. The newly acquired information will be integrated with existing data from regional wells to correlate basalt injection zone properties to develop storage hub/commercial-scale models. Using these models, the project team will evaluate injection scenarios to define the technical and economic potential for storing a minimum of 50 million metric tons of CO2 over a 30-year period, along with a robust sensitivity analysis on key parameters governing reservoir viability for sustainable injection over a commercial project lifetime. Specific technical objectives of HERO are: (1) assessing the reservoir response of a series of stacked layered reservoir flowtop sequences occurring in this area of the CRBG to commercial-scale injection volumes; (2) extending prior efforts by the project team to characterize the deep layered basalts encountered in regional studies, to leverage prior investments by U.S. Department of Energy’s (DOE) Carbon Storage program; (3) leveraging DOE’s mineralization characterization efforts to advance model parametrization for commercial scale injection of CO2 in basalts; (4) conducting risk assessments associated with scaling up to commercial storage hub injection goals, while validating DOE’s National Risk Assessment Partnership (NRAP) tools, to identify potential constraints that would prevent the CRBG from serving as a commercial-scale storage complex; (5) developing mitigation plans to address identified risks; (6) developing a commercial-scale injection and monitoring, verification and accounting (MVA) strategy; (7) utilizing computational models to define and minimize, if possible, the Area of Review (AoR) under Class VI regulations; and (8) developing a robust CO2 management strategy for CRBG that also considers a regional source/sink approach that is responsive to stakeholder needs and industrial demand. Specific institutional objectives are: (1) identifying and developing plans to mitigate the nontechnical challenges associated with the build-out of a commercial-scale storage complex within the CRBG with integrated CO2 sources; (2) implementing the community outreach plan; (3) conducting regulatory research, including a survey of issues related to pore space ownership, MVA and long-term assurance of mineralization-based storage, to support an eventual application for a UIC Class VI permit; (4) advancing the project’s plan for CO2 liability management; and (5) continuing to refine and update the project’s economic model. The final objective is the preparation of a comprehensive Site Characterization Plan that draws upon the technical and institutional feasibility assessments to prepare the project for future commercialization efforts.

58 GEOSCIENCES↗

Gigaton commercial-scale carbon storage and mineralization potential in stacked Columbia River basalt reservoirs

This work presents a detailed supercritical CO 2 storage resource estimation for the stacked basalt reservoirs in the Grande Ronde Basalt of the Columbia River Basalt Group in eastern Washington and Oregon. The assessment aims to derisk the commercialization potential of geologic carbon storage in basalt by leveraging both structural and mineralization trapping of CO 2 in basalt. The structural closures formed by anticlinal ridges and synclinal valleys in Yakima Fold Belt are excellent physical traps to accommodate injected supercritical CO 2 . Rigorous hydraulic testing, well logs and simulation results from the Wallula Basalt Pilot #1 well showed the occurrence of 17 suitable permeable injection zones (up to 2,496 mD) intercalated with dense seals (~2.6E-10 mD) in the Grand Ronde Basalt. In addition, geochemical studies showed fast reactions between supercritical CO 2 and dissolved basalt minerals to form stable carbonates. In conclusion, our calculation indicates up to 40 gigatons (P90) of mineralization storage resources exist in the Grande Ronde Basalt reservoirs.

58 GEOSCIENCES↗

Investigation of enhanced CO 2 storage in deep saline aquifers by WAG and brine extraction in the Minnelusa sandstone, Wyoming

Geological CO 2 sequestration in deep saline aquifers has been extendedly investigated to reach the goal of carbon neutral as large amount of CO 2 can be reduced in a short time. Here, this study investigates the feasibility of water-alternating-gas (WAG) injection and brine extraction on enhancing CO 2 storage in a target deep saline aquifer, Minnelusa Sandstone in the Powder River Basin (PRB) of Wyoming. An integrated numerical model is developed to account for four scenarios: (1) CO 2 continuous injection (CI) through one injection well, (2) WAG injection through one injection well, (3) CO 2 CI through one injection well and brine extraction through one producer, (4) WAG injection through one injection well and brine extraction through one producer. Simulation results suggest that WAG injection and brine extraction corporately make it possible to enhance CO 2 injectivity while securing CO 2 storage safety. For instance, WAG injection considerably reduces structural trapping contribution while enhances dissolved and residual trapping contributions. As for brine extraction, it can decrease the maximum averaged reservoir pressure by 37% and 22% for CI and WAG injection, respectively. Besides, sensitive analyses of the operational parameters for the fourth scenarios are performed. Results reveal that, when the amount of total CO 2 injection has been predetermined, CO 2 injection time and rate within each period of WAG should be small whereas it is preferable to have large water injection time and rate. This is to secure desirable dissolved and residual trapping contributions (store CO 2 with safety). Sensitive degree results confirm that CO 2 injection rate, water injection time, and CO 2 injection time of WAG injection exhibit significant effects on CO 2 storage whereas the impacts of producer bottom-hole pressure (BHP), water injection rate, and CO 2 -water injection time are relatively weaker. This study not only sheds light on achieving double-win goal: enhance CO 2 injectivity and store CO 2 with safety, but also can be a critical reference for other CO 2 storage in deep saline aquifers.

58 GEOSCIENCES↗

Effects of Carbonic Acid-Rock Interactions on CO2/Brine Multiphase Flow Properties in the Upper Minnelusa Sandstones

Summary Carbon dioxide (CO2) injection into a deep saline aquifer can dissolve into formation brine and generate carbonic acid. The resulting acid can drive fluid-rock geochemical reactions. The impact of these fluid-rock geochemical reactions on porosity, permeability, and multiphase flow responses is relevant to the determination of CO2 storage capacity of deep saline aquifers. In this research, carbonic acid flooding experiments were performed on core samples consisting of poorly sorted, quartz-rich sand with laminated bedding from a possible CO2 storage target in northwest Wyoming. Complementary pre- and post-injection porosity and permeability, thin-section, Brunauer-Emmett-Teller (BET) surface area, mercury intrusion capillary pressure (MICP), and time-domain nuclear magnetic resonance (TD-NMR) measurements were conducted. Overall, both core porosity and permeability increased after a 7-day carbonic acid injection, from 6.2 to 8.4% and 1.6 to 3.7 md, respectively. We attributed these changes to carbonate mineral dissolution, which was evidenced by the effluent brine geochemistry, pore-throat size distribution (PTSD), and BET surface area. To be more specific, within the more-permeable section of core samples containing larger pore size, the permeability increment is apparent due to dolomite mineral grains and cements dissolution. However, for the lower-permeability section corresponding to the smaller pore size, mineral precipitation possibly lessened dissolution effects, leading to insignificant petrophysical properties changes. Consequently, the observed heterogeneous carbonic acid-rock interactions resulted in alterations of CO2/brine relative permeability (i.e., the initial CO2 saturation decreased and the CO2 flow capacity was enhanced). This research provides a fundamental understanding regarding effects of fluid-rock reactions on changes in static and multiphase flow properties of eolian sandstones, which lays the foundation for more accurate prediction/simulation of CO2 injection into deep saline aquifers.

Engineering↗

Multiscale petrophysical characterization and flow unit classification of the Minnelusa eolian sandstones

Integration of petrophysical and geological information is critical to simulation of subsurface carbon storage (GCS). In this sense, two depositional facies were identified from the core description and well-log interpretation, namely massive (MS) and cross-bedded (CB) facies groups. Additionally, pore-scale characteristics were studied by a combination of techniques, e.g. Nuclear Magnetic Resonance (NMR) and mercury intrusion capillary pressure (MICP). Scanning electron microscope (SEM) and petrographic analyses show that the pore structure is dominantly controlled by the depositional environment and dolomite cementation. NMR-T 2 distributions of MS and CB facies show triple and quadruple modes, respectively. In addition, MICP of high- and low-permeability MS facies samples, and their CB facies group mixtures were collected. The MS sample pore-throat size distribution is uni-modal, while the triple-modal characteristic of the mixtures indicates heterogeneous pore structures at the sub-core scale for CB facies. The reliably estimates of porosity and permeability for both facies groups via NMR techniques and the MLR (Multiple Linear Regression) approach demonstrate the applicability of these techniques to eolian sandstone. Moreover, irreducible water saturation via the T 2 -cutoff method correlates strongly with T 2LM instead of porosity. Finally, the rock quality index and flow zone indicator were calculated based on Combinable Magnetic Resonance (CMR) log interpretations. This provides direct connection to properties measured in the well. Four flow units were classified for both facies groups. Finally, results show that better reservoir quality with significant heterogeneities is observed in the CB facies. This study highlights the importance integrating multiscale petrophysical properties including facies, pore architecture and diagenesis analysis with core- to log-scale property characterization. The results herein validate our reservoir characterization and flow unit classification in eolian reservoirs.

58 GEOSCIENCES↗

Effect of CO 2 -brine-rock reactions on pore architecture and permeability in dolostone: Implications for CO 2 storage and EOR

Geologic carbon sequestration (GCS) is considered a feasible technology for storing substantive volumes of greenhouse gases in subsurface geological formations. In the reservoir, far from carbon dioxide (CO 2 ) injection wells or in post-injection scenarios, diffusion dominates over advection. This condition conjoins with spatially distributed geochemical reactions to induce heterogeneous changes in pore architecture, i.e. pore body and throat sizes or surface roughness. These changes can affect CO 2 transport properties and storage capacity. In this work, we investigated mineral dissolution and precipitation in dolomite samples saturated with a CO 2 -saturated brine at 93 °C and 34.5 MPa, aged without flow. Two rock types samples, i.e. intergranular- and vuggy-dominant, were selected to investigate changes in pore size, porosity and permeability under reactive conditions. Mineral dissolution and precipitation were characterized using scanning electron microscopy. Changes in pore size were quantified via time-domain nuclear magnetic resonance (TD-NMR) transverse relaxation time (T 2 ) and diffusion coefficient (D) distributions. We show that mineral dissolution likely occurs in highly permeable pathways. These observations are confirmed through analysis of (T 2 ) and diffusion coefficient (D) distributions. In contrast to results during CO 2 -enriched brine continuous injection, mineral precipitation was observed in micropores. The leftward shift of the T 2 peaks, corresponding to micropores, also evidenced mineral precipitation in lowpermeability zones. However, microscale alterations resulted only in a subtle increase in porosity and permeability. Results in this study shed light on effects of geochemical reactions on alteration of rock properties in diffusion-dominated regions during CO 2 storage.

58 GEOSCIENCES↗

Commercial-scale Carbon Storage Complex Feasibility Study at Dry Fork Station, Wyoming

This report summarizes the results of the technical and nontechnical feasibility study (“Phase II”) conducted as part of the “Commercial-Scale Carbon Storage Complex Feasibility Study at Dry Fork Station, Wyoming” project (“Wyoming CarbonSAFE”), which is part of the U.S. Department of Energy’s (“DOE”) National Energy Technology Laboratory’s (“NETL”) Carbon Storage Assurance Facility Enterprise (“CarbonSAFE”) Initiative. This report concludes that the Wyoming CarbonSAFE project is feasible based upon analyses of numerous technical and non-technical criteria in Phase II.

54 ENVIRONMENTAL SCIENCES↗

Link Between CO 2 –Induced Wettability and Pore Architecture Alteration

Changes in pore (throat) size, surface roughness and mineralogy induced by supercritical-CO 2 -water-rock reactions impact petrophysical properties such as porosity, permeability, and especially wettability. Herein, we show that these changes directly impact relative permeability and capillary pressure curves, a fact rarely studied in the literature. In this work, we show that CO 2 contact angle changes emerge after Madison Limestone samples were soaked for 400 hours in CO 2 -enriched brine. Coreflooding results show that the water production rate and cumulative water production increased after the rock was exposed to carbonic acid. Moreover, the mercury capillary pressure decreased in meso- and macro-pores, indicating the increase of size in these pores due to reactions. This compounded wettability and pore network alteration can directly affect CO 2 injectivity, migration and storage capacity. Furthermore, this fundamental insight into CO 2 geological storage processes should aid practitioners to reduce uncertainties in forecasting CO 2 distribution via injection simulation.

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