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Mcconnell, J. C.

Publications and source records attributed to Mcconnell, J. C..

At least 19 records

Simulations of isoprene: Ozone reactions for a general circulation/chemical transport model

A parameterized reaction mechanism has been created to examine the interactions between isoprene and other tropospheric gas-phase chemicals. Tests of the parameterization have shown that its results match those of a more complex reaction set to a high degree of accuracy. Comparisons between test runs have shown that the presence of isoprene at the start of a six day interval can enhance later ozone concentrations by as much as twenty-nine percent. The test cases used no input fluxes beyond the initial time, implying that a single input of a biogenic hydrocarbon to an airmass can alter its ozone chemistry over a time scale on the order of a week.

Makar, P. A.

Calculations of Arctic ozone chemistry using objectively analyzed data in a 3-D CTM

A three-dimensional chemical transport model (CTM) (Kaminski, 1992) has been used to study the evolution of the Arctic ozone during the winter of 1992. The continuity equation has been solved using a spectral method with Rhomboidal 15 (R15) truncation and leap-frog time stepping. Six-hourly meteorological fields from the Canadian Meteorological Center global objective analysis routines run at T79 were degraded to the model resolution. In addition, they were interpolated to the model time grid and were used to drive the model from the surface to 10 mb. In the model, processing of Cl(x) occurred over Arctic latitudes but some of the initial products were still present by mid-January. Also, the large amounts of ClO formed in the model in early January were converted to ClNO3. The results suggest that the model resolution may be insufficient to resolve the details of the Arctic transport during this time period. In particular, the wind field does not move the ClO(x) 'cloud' to the south over Europe as seen in the MLS measurements.

Kaminski, J. W.

Modelling stratospheric polar ozone using objective analysis

We have studied the development of the austral ozone hole using a 3-D spectral chemical transport model at R15 resolution for the period 15th September to 15th October, 1991. The model is driven by objectively analyzed wind fields obtained from the Canadian Meteorological Center and uses the chemical module developed by Kaminski (1992). Although extensive processing of NO(y) and Cl(x) occurs within the model, the ozone hole that develops appears shallow and ephemeral. Analysis of the results indicate that the meridional transport of ozone is sufficient to overwhelm the substantial chemical depletion that does occur. We suggest that the low resolution objectively analyzed data used is unable to capture the essential isolated nature of the vortex.

Sandilands, J. W.

A model for the disc Lyman alpha emission of Uranus

A new efficient radiative transfer algorithm for nonhomogeneous model atmospheres has been applied to the Uranian atmosphere. The contribution of the scatter solar Lyman-alpha to the Uranain emission is of the order of 300 R, and the Rayleigh contribution may reach 450 R for small values of the eddy diffusion coefficient (EDC). The total solar contribution may then reach about 750 R for a solar flux of 2.5 x 10 to the 11th photons/sq cm/s/A. A level of up to 400 R is confirmed in some directions for the interstellar wind contribution. The values of the atmospheric EDC necessary to mimic the observations are 50-100 sq cm/s. A small additional source located on the dayside Uranian atmosphere seems necessary correctly to fit the shape of the limb to limb intensity variation, especially near the limbs. Its contribution to the emergent intensity would range from 100 to 500 R.

Ben Jaffel, L.

The ionosphere of Triton

A model of the atmospheric temperature structure and composition inferred from the Voyager (UVS) solar occultations was used together with a one-dimensional chemical diffusive model to interpret the Voyager Radio Science Spectrometer (RSS) ingress measurements of Triton's electron density. Although N2(+) is the major ion created, N(+) produced by dissociative ionization is the dominant ion. Reaction of thermospheric H2, produced by Lyman-alpha dissociation of CH4 in the lower atmosphere, is the major loss for N(+) ions and maintains these ions in PCSS below 600 km. Solar EUV ionization cannot generate electron densities at the magnitude measured by the RSS experiment and an additional ionization source about 3 x 10 to the 8th ions/sq cm per sec is required. The ionosphere may undergo a transition from PCSS to diffusive control if the N(+) ion production rates were greater than the H2 flux derived from CH4. In this case, the upward flowing H2 is totally converted to H by reaction with N(+) and the remaining N(+) ions recombine radiatively to create an ionosphere under diffusive control above the peak.

Majeed, T.

Recent experiences using finite-element-based structural optimization

Structural optimization has been available to the structural analysis community as a tool for many years. The popular use of displacement method finite-element techniques to analyze linearly elastic structures has resulted in an ability to calculate the weight and constraint gradients inexpensively for numerical optimization of structures. Here, recent experiences in the investigation and use of structural optimization are discussed. In particular, experience with the commercially available ADS/NASOPT code is addressed. An overview of the ADS/NASOPT procedure and how it was implemented is given. Two example problems are also discussed.

Paul, B. K.

A reanalysis of rocket measurements of the ultraviolet dayglow

Rocket measurements of O I 989, 1304, 1356 A and N2 Lyman-Birge-Hopfield band emission in the midlatitude dayglow reported by Gentieu et al. (1979) and Eastes et al. (1985) are reexamined. MSIS-83 atomic oxygen densities, the 1304 and 1356 A excitation cross sections of Zipf and Erdman (1985), and SMM solar 1304 A irradiance measurements are consistent with the observed O I and N2 emission intensities. Atmosphere Explorer E (AE-E) measurements of the solar EUV irradiance near solar maximum are consistent with the 1980 rocket airglow data, but the solar EUV irradiance required to explain the 1978 airglow data is a factor of 1.5 larger than indicated by AE-E. Enhancement of the 1304 A excitation cross section due to radiative entrapment of cascade-feeding photons is much less than the factor of two predicted by the cascade model of Julienne and Davis (1976).

Link, R.

An analysis of satellite observations of the O I EUV dayglow

Observations of the latitudinal variation of the 1356-A, 1304-A, and 989-A O I earth dayglow, obtained with the USAF STP78-1 satellite at solar maximum on March 21, 1979, are reported and compared with the predictions of thermospheric models and published laboratory measurements of electron-impact excitation cross sections. The results are presented in extensive tables and graphs and characterized in detail, with particular attention to the 1304-A solar flux and the 989-A branching ratio. The STP78-1 data (as well as simultaneous AE-E satellite measurements ) are shown to indicate exospheric temperatures that were 220-240-K higher, but varied significantly less with latitude, than those predicted by the MSIS-83 model (Hedin, 1983) for the day of the observations.

Link, R.

The dependence of electroglow on the solar flux

Data from Voyager 2 UV spectrometer observations of electroglow at wavelengths below 110 nm in the atmospheres of Saturn, Jupiter, and Uranus are presented in extensive tables and graphs, analyzed statistically, and compared with the predictions of theoretical models. Findings reported include (1) a dependence (to within 10 percent) of electroglow intensity on the inverse square of heliocentric distance, (2) Uranian electroglow spectra consistent with Rayleigh-Raman scattering of sunlight, and (3) local-time electroglow variations suggesting a solar-flux-dependent excitation mechanism. Mechanisms involving the fluorescence of solar UV radiation in the H2 Lyman and Werner bands or H(-) photolysis are discussed.

Yelle, Roger V.

Modeling of the O I 989-A to 1173-A ratio in the terrestrial dayglow

The O I 989-A and 1173-A intensities in the midlatitude dayglow are modeled for the conditions of a Jan. 17, 1985, rocket flight. It is found that the branching ratio required to fit the 1173-A data is in agreement with the laboratory measurement of 1.3-1.5 x 10 to the -4th. The results also suggest that the electron impact excitation cross section for the 3s1 3D0 state in current use may be too large by a factor of about 2-3, in agreement with recent laboratory results. If this is indeed the case, then the 1173-A triplet is by far the most important branch for the 989-A multiplet.

Gladstone, G. R.

Theory, measurements, and models of the upper atmosphere and ionosphere of Saturn

The structure and composition of the thermosphere, exosphere, and ionosphere of saturn have been determined from observations at optical and radio wavelengths mainly by instruments aboard Voyager spacecraft. Techniques for determining the vertical profiles of temperature and density and the atmospheric vertical mixing in the upper Saturn atmosphere are discussed. Radio occultation measurements and theoretical models of Saturn's ionosphere are reviewed, and attempts to interpret the measurements using the models are discussed. Finally, mechanisms of thermospheric heating are examined.

Atreya, S. K.

Saturn's upper atmosphere from the Voyager 2 EUV solar and stellar occultations

The temperature and composition of the upper atmosphere of Saturn have been inferred from Voyager 2 ultraviolet-spectrometer-occultation measurements made by observing the sun and the star Delta Scorpii while they were being occulted by Saturn. The observations analyzed here provide atmospheric parameters from 2900 km down to 960 km above the 1-bar level referred to the equator. The temperature in the model simulation of the data is 420 + or - 30 K down to about 1600 km. Below 1600 km the temperature decreases with a variable lapse rate down to 120 + or - 30 K near the methane homopause located at 1010 + or - 40 km. A constant temperature at 120 K is applied in the model for the region of the methane homopause down to 960 km where the present analysis terminates. Column amounts of H2 and H were measured from 2900 km down to about 1100 km, giving respective densities of about 1.0 x 10 to the 8th/cu cm and about 5.5 x 10 to the 6th/cu cm near the exobase at 2500 km. Near the methane homopause the H2 density is = 1.2 x 10 to the 12th/cu cm with a CH4 number-density mixing ratio of 0.00006. The eddy-diffusion coefficient in the vicinity of the methane homopause is estimated to be 5.0 x 10 to the 6th sq cm/sec. The atomic hydrogen density profile suggests a downward H flux of 1.8 x 10 to the 9th sq cm/sec from near the exobase down to a terminal boundary of about 1200 km.

Smith, G. R.

Eddy diffusion at Saturn's homopause

Measurements of Saturn's He 584 A dayglow and the CH4 density profile deduced from stellar occultation data near the homopause have been combined to infer an eddy diffusion coefficient of 8 + or - 4 x 10 to the 7th sq cm/s and a temperature of 125 + 40 or - 25 K near the homopause at Voyager 2 encounter. It appears that the eddy diffusion coefficient may have increased between the Voyager encounters. Saturn's H Ly-alpha dayglow is qualitatively compatible with this increase and the interpretation of the He 584 A dayglow and CH4 absorption measurement.

Sandel, B. R.

A new look at the ionosphere of Jupiter in light of the UVS occultation results

Neutral model atmospheres derived from the Voyager UV Spectrometer's solar and stellar occultation data are used to calculate Jupiter ionospheric electron density profiles, demonstrating the inadequacy of such methods. It is also shown that electron densities calculated by means of standard parameters are larger than those measured by both Pioneer and Voyager. McElroy's (1973) suggestion as to the importance of H2 vibrational excitation is investigated, and it is found that no single vibrational temperature is appropriate for the entire thermosphere. The long recombination time constants involved in the plasma's movement, due to either meridional winds or electric fields, through large vertical distances, is shown to account for the observed electron density profiles. It is suggested that the outflow, and possibly the inflow, of plasma may play a role in the definition of electron density profiles.

Mcconnell, J. C.

Extreme ultraviolet observations from the Voyager 2 encounter with Saturn

Combined analysis of helium (584 A) airglow and the atmospheric occultations of the star delta Scorpii imply a vertical mixing parameter in Saturn's upper atmosphere of K (eddy diffusion coefficient) of approximately 8 x 10 to the 7th sq cm per second, an order of magnitude more vigorous than mixing in Jupiter's upper atmosphere. Atmospheric H2 band absorption of starlight yields a preliminary temperature of 400 K in the exosphere and a temperature near the homopause of 200 K. Certain auroral emissions can be fully explained in terms of electron impact on H2, and auroral morphology suggests a link between the aurora and the Saturn kilometric radiation. Absolute optical depths have been determined for the entire C ring and parts of the A and B rings. A new eccentric ringlet has been detected in the C ring. The extreme ultraviolet reflectance of the rings is fairly uniform at 3.5 to 5 percent. Collisions may control the distribution of H in Titan's H torus, which has a total vertical extent of about 14 Saturn radii normal to the orbit plane.

Sandel, B. R.

Overview of the Voyager ultraviolet spectrometry results through Jupiter encounter

The observations of a number of objects by the Voyager EUV instruments are summarized. The summary is considered to demonstrate the wide ranging application of the EUV spectroscopy. It also marks an important step forward in spectrography and emphasizes the continuing importance of the search and discovery nature of spectroscopic techniques.

Broadfoot, A. L.

Extreme ultraviolet observations from Voyager 1 encounter with Saturn

Hydrogen Lyman-alpha, helium and molecular hydrogen band ultraviolet emissions from Saturn and the Titan atmosphere are considered. The Saturn H2 band excitation mechanism, while qualitatively similar to that of Jupiter, is closely related to the solar flux. The occurrence of auroras at 80 deg latitude suggests an earth-like magnetotail activity. No ion emissions have been detected from the Saturn magnetosphere. Although nitrogen emissions excited by particles have been detected in the Titan dayglow and bright limb scans, no such emission has been detected from its dark atmosphere. Enhancement of the nitrogen emission is observed in the region of interaction between Saturn's corotating plasmasphere and the Titan atmosphere.

Broadfoot, A. L.

Voyager U.V. spectrometer observations of He 584 A dayglow at Jupiter

The intensity of Jupiter's He 584 A airglow has been measured by the Voyager UV spectrometers. The disk-averaged brightness is about 4 Rs and limb darkening is present. The intensity probably varies with longitude, the variation being out of phase with the H Lyman-alpha intensity bulge. Modelling of resonance scattering of the solar He 584 A line by Jupiter's atmosphere has shown that the hydrogen and helium emissions can be explained about equally well by at least two self-consistent scenarios involving the structure (temperature and eddy diffusion coefficient) and excitation of the atmosphere. All evidence points to a dramatic change of conditions in the Jovian atmosphere in the time between Pioneer and Voyager encounters.

Mcconnell, J. C.