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Mcconnell, John C.

Publications and source records attributed to Mcconnell, John C..

A global numerical study of radon-222 and lead-210 in the atmosphere using the AES and York University CDT General Circulation Model (AYCG)

The Canadian Climate Center (CCC) GCM has been modified to allow its use for studies in atmospheric chemistry. The initial experiments reported here have been run to test and allow sensitivity studies of the new transport module. The impact of different types of parameterization for the convective mixing have been studied based on the large scale evolution of Rn-222 and Pb-210. Preliminary results have shown that the use of a scheme, which mixes unstable columns over a very short time scale, produces a global distribution of lead that agrees in some aspects with observations. The local impact of different mixing schemes on a short lived tracer like the radon is very important.

Beagley, Stephen R.↗

Modulations of stratospheric ozone by volcanic eruptions

We have used a time series of aerosol surface based on the measurements of Hofmann to investigate the modulation of total column ozone caused by the perturbation to gas phase chemistry by the reaction N2O5(gas) + H2O(aero) yields 2HNO3(gas) on the surface of stratospheric aerosols. We have tested a range of values for its reaction probability, gamma = 0.02, 0.13, and 0.26 which we compared to unperturbed homogeneous chemistry. Our analysis spans a period from Jan. 1974 to Oct. 1994. The results suggest that if lower values of gamma are the norm then we would expect larger ozone losses for highly enhanced aerosol content that for larger values of gamma. The ozone layer is more sensitive to the magnitude of the reaction probability under background conditions than during volcanically active periods. For most conditions, the conversion of NO2 to HNO3 is saturated for reaction probability in the range of laboratory measurements, but is only absolutely saturated following major volcanic eruptions when the heterogeneous loss dominates the losses of N2O5. The ozone loss due to this heterogeneous reaction increases with the increasing chlorine load. Total ozone losses calculated are comparable to ozone losses reported from TOMS and Dobson data.

Blanchette, Christian↗

The upper ionospheres of Jupiter and Saturn

The electron-density profiles of Jupiter's and Saturn's ionospheres are modeled with a 1D chemical diffusive model incorporating measured parameters of the neutral atmospheric structure. The Voyager RSS ion-density data are modeled by accounting for ion chemistry, the H3(+) recombination-rate coefficient, and H2O chemistry. Electron-density peaks for both ionospheres are 900-1000 km lower in the model than the measured values, and the role of vibrational excitation of H2 is discussed in converting H(+) to H2(+) and H3(+). Vertical ion flow is also considered which can maintain the plasma peaks under the conditions of electrical fields or horizontal neutral winds. An assumed influx of H2O molecules of a specific quantity is theorized to reproduce the measured values on Saturn when combined with a vertical plasma drift.

Majeed, Tariq↗

He 584 A dayglow at Neptune

The Voyager 2 Ultraviolet Spectrometer measured the emission intensity of the He resonance line at 584 A to be 0.34 + 0.2 or - 0.15 R on the day side of Neptune. Calculations of the He 584 A intensity at Neptune using partial frequency redistribution and inhomogeneous atmospheric models show that the product of the volume mixing ratio (mole fraction), fHe, and the eddy diffusion coefficient at the homopause, Kh, is fHeKh = 10 to the 7th sq cm/s with upper and lower bounds to the uncertainty of about a factor of 3 and 9, respectively. If fHe is taken as the current Infrared Interferometer Spectrometer working value, fHe = 0.19, then Kh = 5 x 10 to the 7th sq cm/s with a similar uncertainty. This range of K overlaps that obtained from analysis of the hydrocarbon distributions on Neptune (Broadfoot et al., 1989).

Parkinson, Christopher D.↗

Vibrationally excited H2 in the upper atmosphere of Saturn

The impact of resonance fluorescense of solar EUV radiation by H2 on the distribution of the vibrational levels of H2 in the upper atmosphere of Saturn is considered. It appears that, for vibration levels, v not smaller than 3, this is the most important source, more important than those due to photoelectron induced fluorescence, recombination of molecular ions such as H3(+), and vibrational excitation of H2 by photoelectron impact. Based on the Voyager limb observations of H2 band emission, it is estimated that some of the higher vibrational levels may have effective temperatures about 3500 K. Such high vibrational densities may have an impact on ionospheric densities.

Majeed, Tariq↗

The far ultraviolet reflection spectrum of Uranus - Results from the Voyager encounter

The present analysis of the 1250-1700 A region Uranus spectrum obtained by Voyager's US spectrometer characterizes these observation results as due primarily to solar light reflected from an H2 Rayleigh and Raman scattering atmosphere with small but measurable hydrocarbon absorption. The hydrocarbon abundances obtained are substantially lower than those at comparable levels of the Saturn or Jupiter atmospheres; it is suggested, in one-dimensional terms, that this is due to diffusive separation, in conjunction with photochemical depletion caused by a very low eddy-diffusion coefficient. Strong latitudinal variations in the hydrocarbon abundances are suggested in the subsolar, polar stratosphere.

Yelle, Roger V.↗