Search NASA⌕ Search

Engineering topics

Mcdermott, P. P.

Publications and source records attributed to Mcdermott, P. P..

10 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Modeling taper charge with a non-linear equation

Work aimed at modeling the charge voltage and current characteristics of nickel-cadmium cells subject to taper charge is presented. Work reported at previous NASA Battery Workshops has shown that the voltage of cells subject to constant current charge and discharge can be modeled very accurately with the equation: voltage = A + (B/(C-X)) + De to the -Ex where A, B, D, and E are fit parameters and x is amp-hr of charge removed during discharge or returned during charge. In a constant current regime, x is also equivalent to time on charge or discharge.

Mcdermott, P. P.↗
NASA NTRS1984

Prediction of Battery Life and Behavior from Analysis of Voltage Data

A method for simulating charge and discharge characteristics of secondary batteries is discussed. The analysis utilizes a nonlinear regression technique where empirical data is computer fitted with a five coefficient nonlinear equation. The equations for charge and discharge voltage are identical except for a change of sign before the second and third terms.

Mcdermott, P. P.↗
NASA NTRS1980

Accelerated test design

The design of an accelerated life test program for electric batteries is discussed. A number of observations and suggestions on the procedures and objectives for conducting an accelerated life test program are presented. Equations based on nonlinear regression analysis for predicting the accelerated life test parameters are discussed.

Mcdermott, P. P.↗
NASA NTRS1980

An accelerated test design for use with synchronous orbit

The Naval Weapons Support Center at Crane, Indiana has conducted a large scale accelerated test of 6.0 Ah Ni-Cd cells. Data from the Crane test have been used to develop an equation for the description of Ni-Cd cell behavior in geosynchronous orbit. This equation relates the anticipated time to failure for a cell in synchronous orbit to temperature and overcharge rate sustained by the cell during the light period. A test design is suggested which uses this equation for setting test parameters for future accelerated testing.

Mcdermott, P. P.↗
NASA NTRS1979

Some practical observations on the accelerated testing of Nickel-Cadmium Cells

A large scale test of 6.0 Ah Nickel-Cadmium Cells conducted at the Naval Weapons Support Center, Crane, Indiana has demonstrated a methodology for predicting battery life based on failure data from cells cycled in an accelerated mode. After examining eight variables used to accelerate failure, it was determined that temperature and depth of discharge were the most reliable and efficient parameters for use in accelerating failure and for predicting life.

Mcdermott, P. P.↗
NASA NTRS1978

Dynamics of cell degradation

The use of chemical and physical data as a supplement to linear regression models in the prediction of cell failure is discussed. Principal factors to be considered are the positive thickness and weight, and the negative thickness. A model for cell degradation and failure in accelerated life test cells is presented and predictions based on a teardown analysis are included.

Mcdermott, P. P.↗
NASA NTRS1977

Analysis of voltage data

The use of statistical analysis (regression analysis) to determine the data correlation between eight voltage parameters is discussed. The eight parameters correlated include: temperature, depth of discharge; charge rate; discharge rate; percent recharge; concentration of KOH; amount of KOH; and precharge. Graphs are presented which show: (1) starpoint/centerpoint cycles to failure vs. parameters; (2) cycles to failure vs. temperature; and (3) positive and negative plate thickness and weight vs. cycles. An empirical equation derived from cycles to failure vs. temperature graph for cells cycled at 1C charge, 2C discharge, and 14 percent recharge is also presented.

Mcdermott, P. P.↗
NASA NTRS1977

Charge and discharge profile

Some possible parameters which could be used to predict failures within packs of electrochemical cells based on measurements that are taken while the cells are cycling are discussed. Discharge and charge curves are presented and fitted to measure the efficiency of the cells in terms of voltage vs. time.

Mcdermott, P. P.↗
NASA NTRS1976

Cadmium migration in aerospace nickel cadmium cells

The effects of temperature, the nature of separator material, charge and discharge, carbonate contamination, and the mode of storage are studied with respect to the migration of active material from the negative toward the positive plate. A theoretical model is proposed which takes into account the solubility of cadmium in various concentrations of hydroxide and carbonate at different temperatures, the generation of the cadmiate ion, Cd(OH)3(-), during discharge, the migration of the cadmiate ion and particulate Cd(OH)2 due to electrophoretic effects and the movement of electrolyte in and out of the negative plate and, finally, the recrystallization of cadmiate ion in the separator as Cd(OH)2. Application of the theoretical model to observations of cadmium migration in cycled cells is also discussed.

Mcdermott, P. P.↗