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Megan R Damon

Publications and source records attributed to Megan R Damon.

Faster Tropical Upper Stratospheric Upwelling Drives Changes in Ozone Chemistry

Tropospheric trends in long-lived source gases N2O and the chlorofluorocarbons (CFCs) cause trends in O3 through changes in their reactive product gases. Transport affects the product gases because it controls the distribution of the long-lived source gases. We find that large changes in tropical upwelling 10-5 hPa since 2012 have strengthened the northern branch of the upper stratospheric (UpS) transport circulation, dramatically altering the abundances of N2O and its odd nitrogen product gases, NOx and HNO3. Increased upwelling is connected to stronger and more frequent Quasi-Biennial Oscillation easterly winds at 10 hPa and above. We use simulations with and without time varying MERRA2 meteorology to quantify the impact of dynamical changes on O3 loss via the NOx and ClOx cycles. We find that dynamical impacts on these cycles explain the mid-stratospheric tropical O3 increase and Arctic UpS O3 decrease since 2005.

Middle atmosphere chemistry and composition↗

Unexpected Repartitioning of Stratospheric Inorganic Chlorine after the 2020 Australian Wildfires

The inorganic chlorine (Cl y ) and odd nitrogen (NO y ) chemical families influence stratospheric O 3 . In January 2020 Australian wildfires injected record-breaking amounts of smoke into the southern stratosphere. Within 1-2 months ground-based and satellite observations showed Cl y and NO y were repartitioned. Compared to decadal means, lower stratospheric (LS) HCl columns declined by ~30% between March and May while ClONO 2 columns increased by 40-50%. The Cl y perturbations recovered from June to October. The LS NO 2 decreased from February to April, consistent with sulfate aerosol reactions, but returned to typical values by June - months earlier than the Cl y recovery. Transport tracers show an air mass change explains the observed O 3 decrease after April. Simulations assuming wildfire smoke behaves identically to sulfate aerosols couldn’t reproduce observed Cl y changes, suggesting that their composition and chemistry differs from sulfate aerosols. This undermines our ability to predict ozone in a changing climate.

middle atmosphere chemistry and composition↗

Why Do Antarctic Ozone Recovery Trends Vary?

We use satellite ozone records and Global Modeling Initiative (GMI) chemistry transport model (CTM) simulations integrated with MERRA2 meteorology to identify a metric that accurately captures the trend in Antarctic ozone attributable to the decline in ozone depleting substances (ODSs). The GMI CTM Baseline simulation with realistically varying ODS levels closely matches observed interannual to decadal scale variations in Antarctic September ozone over the past 4 decades. The expected increase or recovery trend is obtained from the differences between the Baseline simulation and one with identical meteorology and fixed 1995 ODS levels. The differences show that vortex-averaged column O3 has the greatest sensitivity to ODS change from 1-20 Sep. The observed vortex-averaged column O3 during this period produces a trend consistent with the expected recovery attributable to ODS decline. Trends from dates after 20 Sep have smaller sensitivity to ODS decline and are more uncertain due to transport variability. Simulations show that the greatest decrease in O3 loss (i.e., recovery) occurs inside the vortex near the edge. The polar cap metrics have vortex size-dependent bias and do not consistently sample this region. Because the 60-90oS 220 DU O3 mass deficit (OMD) metric does not sample the edge region, its trend is lower than the expected trend; this is improved by area weighting. The 250 DU OMD metric samples more of the edge region, which increases its trend. Approximately 25% of the September Antarctic O3 increase is due to higher O3 levels in June prior to winter depletion.

Antarctic ozone↗

The Impact of Assimilating Large Volumes of GNSS Radio Occultation Observations from Spire’s Commercial Constellation into NASA’s Global Earth Observing System

The upcoming retrospective analysis for the 21st century (R21C) reanalysis product from NASA will include the full dataset of GNSS Radio Occultation (RO) observations collected by Spire with their constellation of smallsats. The Spire RO dataset, which was purchased by NASA for its Commercial Smallsat Data Acquisition (CSDA) archive, has global coverage and includes approximately 6 thousand RO profiles per day during 2019 increasing to nearly 20 thousand in 2022-2023. This more than doubles the volume of RO profiles from all other routinely assimilated RO missions combined during 2023. The increase in the number of RO profiles available is particularly important in the extratropics as the next largest RO constellation, the state-of-the-science Formosa Satellite Mission 7 (FORMOSAT-7)/Constellation Observing System for Meteorology, Ionosphere and Climate (COSMIC-2) mission (hereafter COSMIC-2), is focused on the Tropics and only provides approximately 4 thousand RO profiles per day. The large number of observations in the Spire RO dataset have great potential to improve analyses and forecasts of the Earth’s atmosphere produced by numerical weather prediction systems. Their impact is assessed through numerical experiments using NASA’s Global Earth Observing System (GEOS) Atmospheric Data Assimilation System (ADAS) with and without the observations from the COSMIC-2 mission. The ability of the Spire RO observations to make up for the omission of the RO observations from COSMIC-2 is directly assessed over the tropics and the impact of Spire over the extratropics is compared to that of the available RO missions that sample over this region. Finally, the quality of the Spire RO observations is compared to that of the routinely assimilated RO missions using Forecast Sensitivity-based Observation Impact (FSOI).

Michael J. Murphy, Jr.↗