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Metcalfe, Martin

Publications and source records attributed to Metcalfe, Martin.

ASME – Grappling with the Concept of Component Failure

ASME concepts of component failure. Definition for failure, functionality, damage tolerance, including Magnox reactors and AGRs. How ASME is addressing damage tolerance, and Section III division 5 Design, Classification, Reliability Target for SRC-1 components, Basic analysis approach, simple assessment, and full assessments, Reference to reliability and integrity management and strategy for graphite components.

36 MATERIALS SCIENCE↗

ASME Non-metallic Component Degradation and Failure Task Group

ASME Non-metallic Component Degradation and Failure Task Group background, component failure and component functionality, the nature of graphite, damage tolerance, AGR design, damage tolerance, non-metallic component degradation and failure task group, task group progress, monitoring and examination, link between degradation processes and their impact on core components in the array of graphite components, the link between degradation processes and RIM options, and a way forward.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Damage tolerance in the graphite cores of UK power reactors and implications for new build

The United Kingdom has been operating graphite-moderated gas-cooled commercial nuclear power reactors for more than 60 years. Both Generation I Magnox reactors and Generation II Advanced Gas-cooled Reactors have operated beyond their nominal design lifetimes and the safety cases for continued operation have had to address the issue of damage tolerance of the graphite cores. This review describes the designs of the reactors and the methodologies employed for their assessment. Emerging issues arising from extended operation and ageing of the cores are discussed together with the evolution of assessment methodologies to address predicted and observed damage. The UK nuclear regulator perspective is summarised and some conclusions are drawn on the implications for new build.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

On the thermal oxidation of nuclear graphite relevant to high-temperature gas cooled reactors

Thermal oxidation of nuclear graphite components is highly undesirable because it can cause structural and property degradation that negatively affect a reactor's intended operation. In this work, the body of knowledge of nuclear graphite oxidation is highlighted, including when O 2 , H 2 O, and/or CO 2 are the oxidant. Oxidation conditions relevant to high-temperature gas-cooled reactors (i.e., when oxidation could occur either as an acute or chronic phenomenon) are emphasized. Here, the objective is to summarize graphite oxidation data in a practical and accessible way to inform future research and regulatory requirements. Although each grade of nuclear graphite is different, the oxidation mechanism has underlying commonalities. Although oxidation behavior is grade dependent, the general temperature dependence is well described by a sequence of elementary steps which become rate limiting. Because the regime transition temperature depends on sample microstructure, size, and oxidant supply rate, extrapolating results beyond the experimental range should be done cautiously. Gravimetric oxidation rate measurements generally replicate well. However, caution must be exercised when rates are estimated by other methods or for samples that deviate significantly in size. Air oxidation data for IG-110, NBG-18, and PCEA graphite is critically reviewed to emphasize this point. Despite the amount of experimental data, gaps remain. Sample size and shape effects are not fully explained. Data on the oxidant penetration depth are insufficient. Analytical assessments demonstrate that lower temperature oxidation does not necessarily imply that oxidation is uniform throughout the bulk. Oxidation occurs faster at higher temperature but is more localized to the exposed surface. Paradoxically, at equal mass loss percentage, low temperature oxidation leads to greater property degradation than at high temperature. The isolated effect of oxidation is important; however, a gap remains in the systematic understanding of any potential effect of neutron irradiation on graphite structure and reactivity.

36 MATERIALS SCIENCE↗