Experimental transition probabilities and Stark broadening for singly-ionized bismuth
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Engineering topics
Publications and source records attributed to Miller, M. H..
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Shock-tube data are used to examine systematic f-value behavior in prominent visible transition arrays for the homologous emitter sequence Si-II, Ge-II, Sn-II, and Pb-II. Regularities found in these data are compared with trends in lighter elements. Agreements and disparities with theoretical and experimental oscillator strengths from existing literature are noted.
Strengths and Stark widths of the prominent visible PbI and PbII lines are measured in emission by means of a gas-driven shock tube. Absolute ionic line strengths for 7s-7p and 7p-7d arrays conform well to quantum-mechanical sum rules and agree with theoretical predictions, but 6d-5f results differ markedly from central-field approximations. Neutral-line strengths agree satisfactorily with available comparison data. Semiempirical theory predicts the widths of PbII lines with characteristic reliability of better than 25%.
Strengths and Stark-effect widths of the Sn I and Sn II lines prominent between 3200 and 7900 A are measured with a spectroscopic shock tube. Absolute strengths of 17 ionic lines are obtained with estimated (22-50)% accuracy and conform to appropriate quantum-mechanical sum rules. Relative transition probabilities for nine prominent neutral tin lines, normalized to radiative-lifetime data, are compared with other experiments and theoretical predictions. Parameters for Stark-effect broadening are measured over a range of plasma electron densities. Broadening data (with accuracies of 15-35%) for one neutral and ten ionic lines of tin are compared to theoretical predictions.
Federal and state laws require the imminent retrofit of offstream condenser cooling to the newer steam electric stations. Waiver can be granted based on sound experimental data, demonstrating that existing once-through cooling will not adversely affect aquatic ecosystems. Conventional methods for monitoring thermal plumes, and some remote sensing alternatives, are reviewed, using on going work at one Maryland power plant for illustration.
Specific cases of known or potentially useful applications of remote sensing in assessing biological resources are discussed. It is concluded that the more usable remote sensing techniques relate to the measurement of population fluctuations in aquatic systems. Sensing of the flora and the fauna of the Bay is considered with emphasis on direct sensing of aquatic plant populations and of water quality. Recommendations for remote sensing projects are given.
Shock tube data are used to examine the systematic f value behavior in prominent visible transition arrays (ns-np, np-(n+l)s, np-nd) for the homologous emitter sequence Si 11, Ge 11, Sn 11, and Pb 11. Regularities found for these data are compared with trends in lighter elements. Agreements and s disparities with theoretical and experimental oscillator strengths from the literature are noted.
Stark shift of the B II line at 3451 A due to plasma microfields was measured in a luminous shock tube. Line profiles, photographically recorded in second order, were compared with closeby wavelength fiduciaries from low-pressure rare-gas lamps. Electron densities for each exposure were found by fitting H-beta profiles to theoretical line shapes. Results, estimated reliable to 25-30%, are compared with theoretical predictions.
Absolute transition probabilities of the three most prominent visible Br II lines are measured in emission. Results compare well with Coulomb approximations and with line strengths extrapolated from trends in homologous atoms.
Results of determinations of neutral-cobalt transition probabilities measured relative to Co I 4150.43 A and Co II 4145.15 A, using a gas-driven shock tube as the spectroscopic light source. Results are presented for 139 Co I lines in the range from 3940 to 6640 A and 11 Co II lines in the range from 3840 to 4730 A, which are estimated to have reliabilities ranging from 8 to 50%.
Work has been conducted to reduce substantially uncertainties concerning the line strengths for carbon and sulfur. Two or more independent methods were used to measure thermodynamic variables and to calibrate detectors for absolute sensitivity and spectral response. The absolute transition probabilities of 124 visible and infrared lines of C I, S I, and S II were measured in a consistent way.
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Device can operate in close-open-close mode. Beam splitter placed behind static-slit assembly allows use of more than one camera. Each frame in particular series may be conveniently varied in exposure time and spacing. This can be done independent of other frames in the series. In ''open'' position, shutter transmits light over wide wavelength range.
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First experimental line strength data for the visible Kr II lines and for several of the more prominent Kr I lines are given. The spectroscopic light source used is the thermal plasma behind the reflected shock wave in a gas-driven shock tube. A 3/4-m spectrograph and a 1-m spectrograph were employed simultaneously to provide redundant photometry. The data are compared with other measurements and with theoretical calculations.
Use of a gas-driven shock tube to measure the absolute strengths of 21 P I lines and 126 P II lines (from 3300 to 6900 A). Accuracy for prominent, isolated neutral and ionic lines is estimated to be 28 to 40% and 18 to 30%, respectively. The data and the corresponding theoretical predictions are examined for conformity with the sum rules.-
Neon red lines Stark widths and shifts in function of electron and neutral Ne densities in shock tube
High temperature plasmas optical properties measurement by plasma spectroscopy, using gas driven shock tube as light source