Engineering topics

Miller, Nathan A.

Publications and source records attributed to Miller, Nathan A..

3 records

DOE OSTI2023

Structural properties of aqueous grown polydopamine thin films determined by neutron reflectometry

Here, in this work, neutron reflectometry (NR) studies of the bio-mimetic polymer, polydopamine (PDA), deposited from differing initial concentrations of precursor material dopamine hydrochloride for a range of polymerization times, is reported. PDA can form a complex and highly versatile polymer film, with many structure studies having been performed previously, but a comprehensive structural determination of PDA by NR is lacking in the literature. It was found that simple box models were incapable of fully explaining the observed data, necessitating the use of a composite model consisting of the weighted average of both the 1 and 2 box models to fully capture the heterogeneous nature of the PDA film structure. Confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM) were performed to capture the surface structure and relative mechanical difference between the separate domains of the PDA. The CLSM results provide evidence that the PDA domains are larger than the coherent scattering length of a neutron used in these measurements, 10μm, supporting the need for a composite model. The AFM measurements show complex structure below the coherence length provide physical justification for the two box model. It was determined that film structure and quality are both heavily impacted by the initial concentration of dopamine hydrochloride and the polymerization time, giving confidence to the highly customizable nature of PDA as an adhesion promoting interface treatment in composite systems, such as plastic bonded explosives (PBX).

36 MATERIALS SCIENCE↗

DOE OSTI2022

A micromorphic filter for determining stress and deformation measures from direct numerical simulations of lower length scale behavior

A micromorphic filter is presented for the extraction of stress and deformation measures from underlying direct numerical simulation (DNS) of microstructural mechanical response. The filter is consistent with the micromorphic continuum theory of Eringen and Suhubi (1964), and allows the interrogation of a DNS to generate higher order constitutive models. The filter adopts aspects of the overlap coupling techniques for atomistic-continuum scale-bridging in order to update the nodal degrees of freedom of the finite-element-based filter. Here, two methods for the extraction of quantities of interest from the underlying DNS are presented. The first is a least squares fitting technique which is appropriate for finite-element-style macro-scale domains, and the second is a variationally based approach which generalizes the method to any macro-scale domain which has a variational form. No restrictions on the form of the micro-scale simulation are inherent to the approach, provided that the required quantities (stress, position, etc.) can be provided. The filter is applied to a simple homogeneous medium undergoing homogeneous deformation to demonstrate the recovery of a classical continuum response, what we call the null case. We then apply the framework to the same homogeneous medium with a central and edge penny-shaped crack to show micromorphic effects. We demonstrate that varying the size of the filter causes the micromorphic behaviors to arise and then dissipate as the filter becomes smaller than the crack's length scale. Additionally we show the effect of filter size on a chiral element network along with a plate perforated with evenly spaced and perturbed holes through the thickness. The micromorphic effects are shown to be present for the chiral elements under any loading but become most pronounced when a single element is located within each averaging domain. Micromorphic effects become pronounced for the plate upon the onset of localization.

97 MATHEMATICS AND COMPUTING↗

NASA NTRS2005

Using Beta Cen to Probe the Photosphere-wind Connection in B Stars

In this project we began by identifying the large number of emission lines visible in the XMM-Newton RGS spectra of Beta Cen. A comprehensive analysis of the temperature structure of the hot gas was carried out by simultaneously fitting the data from all the instruments on the spacecraft. This resulted in a measured temperature range of 0.1-0.6 keV. In more detailed analysis, three characteristic plasma temperatures were found: 0.1, 0.2, and 0.6 keV. The research carried out at UW-Eau Claire primarily focused on two aspects of the data: the analysis of the forbidden line to intercombination line ratio for He-like ions and the time variability of the overall X-ray flux as detected in the direct X-ray images of the star. The analysis of the lines from He-like ions indicate that the Ne IX lines are formed no farther than about 4 stellar radii from the star's photosphere, while the N VI lines are formed within 11 stellar radii of the photosphere. X-ray flux variability would be particularly interesting for this star because it is a known Beta Cep-type variable as seen in optical light: similar variation in the X-ray region would forge an interesting link between the two wavebands. Initial analysis of the X-ray flux was complicated by spikes in the count rates early in the observation. Detailed analysis of the spectral characteristics these count rate anomalies indicated that these flares were probably not intrinsic to the star, rather they were contaminations of the data due to the passage of the satellite through soft proton clouds in the Earth's magnetosphere. An analysis of the light curve of the uncontaminated portions of the light curve did not reveal any variation on the known optical period of variation for this star, and a general search for periodic variability also did not find any significant periods of variation.

Miller, Nathan A.↗