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Miller, W. J.

Publications and source records attributed to Miller, W. J..

7 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Gel Precursors as Glass and Ceramic Starting Materials for Space Processing Applications Research

The crystallization kinetics and glass forming ability of reluctant glass formers is investigated. This could ultimately aid the formation of bulk samples of unique glass compositions outside of normal glass forming regions allowing the optimization of certain properties of the glass. One important aspect of processing in space is the containerless undercooling of molten substances. Theoretically, the extent of undercooling can be greatly enhanced by solidifying in the absence of heterogeneous nucleation resulting from contact with crucibles or molds. Techniques were established for the measurement of crystallization kinetics and critical cooling rates. The glass formation ability and crystallization kinetics of Ga2O-43CaO and several Al2O3-CaO compositions were measured. An apparatus was set up to measure the temperature of spherical samples on a thermocouple at large cooling rates. The time and temperature of nucleation is recorded and the probability of nucleation at various cooling rates can be measured.

Downs, R. L.↗
NASA NTRS1983

Research study for gel precursors as glass and ceramic starting materials for space processing applications research

The development of techniques for the preparation of glass and ceramic starting materials that will result in homogeneous glasses or ceramic products when melted and cooled in a containerless environment is described. Metal-organic starting materials were used to make compounds or mixtures which were then decomposed by hydrolysis reactions to the corresponding oxides. The sodium tungstate system was chosen as a model for a glass with a relatively low melting temperature. The alkoxide tungstates also have interesting optical properties. For all the compositions studied, comparison samples were prepared from inorganic starting materials and submitted to the same analyses.

Downs, R. L.↗
NASA NTRS1980

Silicon halide-alkali metal flames as a source of solar grade silicon

The feasibility of using continuous high-temperature reactions of alkali metals and silicon halides to produce silicon in large quantities and of suitable purity for use in the production of photovoltaic solar cells was demonstrated. Low pressure experiments were performed demonstrating the production of free silicon and providing experience with the construction of reactant vapor generators. Further experiments at higher reagent flow rates were performed in a low temperature flow tube configuration with co-axial injection of reagents and relatively pure silicon was produced. A high temperature graphite flow tube was built and continuous separation of Si from NaCl was demonstrated. A larger scaled well stirred reactor was built. Experiments were performed to investigate the compatability of graphite based reactor materials of construction with sodium. At 1100 to 1200 K none of these materials were found to be suitable. At 1700 K the graphites performed well with little damage except to coatings of pyrolytic graphite and silicon carbide which were damaged.

Olson, D. B.↗
NASA NTRS1979

Silicon halide-alkali metal flames as a source of solar grade silicon

The feasibility of using alkali metal-silicon halide diffusion flames to produce solar-grade silicon in large quantities and at low cost is demonstrated. Prior work shows that these flames are stable and that relatively high purity silicon can be produced using Na + SiCl4 flames. Silicon of similar purity is obtained from Na + SiF4 flames although yields are lower and product separation and collection are less thermochemically favored. Continuous separation of silicon from the byproduct alkali salt was demonstrated in a heated graphite reactor. The process was scaled up to reduce heat losses and to produce larger samples of silicon. Reagent delivery systems, scaled by a factor of 25, were built and operated at a production rate of 0.5 kg Si/h. Very rapid reactor heating rates are observed with wall temperatures reaching greater than 2000 K. Heat release parameters were measured using a cooled stainless steel reactor tube. A new reactor was designed.

Olsen, D. B.↗
NASA NTRS1976

Digital image correlation techniques applied to LANDSAT multispectral imagery

The author has identified the following significant results. Automatic image registration and resampling techniques applied to LANDSAT data achieved accuracies, resulting in mean radial displacement errors of less than 0.2 pixel. The process method utilized recursive computational techniques and line-by-line updating on the basis of feedback error signals. Goodness of local feature matching was evaluated through the implementation of a correlation algorithm. An automatic restart allowed the system to derive control point coordinates over a portion of the image and to restart the process, utilizing this new control point information as initial estimates.

Bonrud, L. O.↗
NASA NTRS1971

Fluorine negative ion detachment kinetics

A study of the rate of F(-) detachment by O and H atoms via the reactions F(-) + O yields FO + e and F(-) + H yields FH+ e was undertaken using a drift tube to produce F(-) ions at various drift velocities and therefore different ion temperatures. Preliminary mobility measurements of F(-) ions in Ar were made, indicating that ion temperatures in the 300 K to 5000 K range could be achieved; however due to numerous difficulties experienced in obtaining a reliable F(-) ion source, the study could not be completed.

Burke, R. R.↗