Engineering topics

Mittlefehldt, D. W.

Publications and source records attributed to Mittlefehldt, D. W..

At least 19 records

NASA NTRS2020

Documenting Antarctic Alteration of Eucrites

When meteorites were discovered in Antarctica, it was anticipated that terrestrial alteration would be at a minimum because of their deepfreeze storage where chemical reaction rates would be low. However, early compositional and petrologic studies established the presence of terrestrial alteration phases (e.g., [1, 2]). These were especially prevalent in chondrites because metal and troilite are most susceptible to terrestrial alteration [3]. Howardites, eucrites and diogenites (HEDs) are less prone to alteration because they have low abundances of metal and troilite. Nevertheless, investigations of HED meteorites document a wide array of mineralogical, compositional and isotopic effects of terrestrial alteration (e.g., [4-8]). Studies of the mineralogical effects of alteration [4] were done with old scanning electron microscope (SEM) technology which could only image small regions at a time. The micro-context of alteration phases was revealed, but larger-scale context was difficult to establish. Here we demonstrate the utility of wholethin-section X-ray mapping of eucrites by modern SEMs to document large-scale distributions of alteration materials which serve to evaluate sample freshness, highlight regions for detail study, and facilitate testing a hypothesis for alteration of eucrites [8]

Mittlefehldt, D. W.↗

NASA NTRS2020

Identification of Anomalous Eucrites and Diogenites by Multivariable Discriminant Analysis

Howardite, eucrite and diogenite clan (HED) is the largest magmatic achondrite group and has been suggested to be derived from asteroid (4) Vesta (e.g., [1]). Previous geochemical studies have suggested HEDs were generated by asteroid melting followed by crystallization, metamorphism, and impact [1-6]. However, numerous eucrites and diogenites have anomalous compositional, isotopic or petrological characteristics compared to the norm. This diversity might indicate more complex magma processes on the parent asteroid, or they could be linked to different parental asteroids (e.g., [5]). The former case would imply that the parent asteroid is more heterogenous than currently thought, and that our petrologic models are too simple. The latter case would increase the number of asteroids known to have formed mafic crusts, and would allow for petrological comparisons across numerous bodies. We apply multivariable discrimination analysis (MDA) to a large database of HED pyroxene analyses. This technique allows all elemental information to be considered simultaneously to facilitate identification of groupings, trends, and outliers within the dataset.

Peng, Z. X.↗

NASA NTRS2019

Sulfur on Mars

The S contents of rocks and soils are indicative of various alteration processes on Mars, e.g.[1]. It has been quantified along traverses at 4 landing sites – Pathfinder, both MERs and MSL – by the APXS [2,3]. At the MSL and MER sites, sulfur abundances, correlations with likely bound cations and other elements, and complementary mineralogical and textural data have provided important insights into alteration processes and periods of more habitable environments in the distant past.

Gellert, R.↗

NASA NTRS2019

Understanding Martian Alteration Processes by Comparing In-Situ Chemical Measurements from Multiple Landing Sites

Characterizing the history of aqueous activity at the martian surface has been an objective of the Mars Exploration Rovers (MER) and the Mars Science Laboratory (MSL). Although the geologic context of the three landing sites are different, comparisons across the datasets can provide greater insight than using data from one mission alone. The Alpha Particle X-ray Spectrometer (APXS) is common to all three rovers (Spirit at Gusev crater, Opportunity at Meridiani Planum, and Curiosity at Gale crater) and provides a consistent basis for these comparisons. Soil and Dust: Fine grained basaltic soils and dust are remarkably uniform in chemical composition across multiple landing sites. These similarities in the concentrations of major, minor, and a few trace elements (Fig. 1) are indicative of planet-wide consistency in the composition of source materials for the soils. S and Cl vary by a factor of two in the soil and dust, but there is no clear association with any bulk cation (e.g., no correlation between S and total Ca, Mg, or Fe in soils). These volatile elements, however, are clearly associated with the nanophase-ferric iron component in the soil established by Mössbauer spectroscopy [1,2]. S and Cl likely originated as acidic species from volcanic out-gassing and subsequently coalesced on dust and sand grain surfaces, possibly with an affinity towards Fe3+ sites. Importantly, given the mobility of S and Cl in aqueous exposures, soil samples maintaining the typical molar S/Cl ratio of ~3.7:1 indicate minimal interactions with liquid water after the addition of S and Cl. In contrast to this well-established baseline, soil samples have been discovered at all three landing sites with atypical S/Cl ratios (e.g., subsurface soils), indicative of a more complex aqueous history.

Yen, A. S.↗

NASA NTRS2019

Elemental Variation and Petrogenesis of Pyroxenes in HED Meteorites by Multivariable Discriminant Analysis Method

HED (Howardite, Eucrite and Diogenite) are meteorites with mafic and ultramafic igneous composition. Previous studies suggested HED came from asteroid (4) Vesta and they were generated by magmatic melting followed by differentiation crystallization, metamorphic, and impact. Uniform oxygen isotopic composition of HED samples favors global magma ocean for (4) Vesta. However, the petrological diversity of HED may indicate more complex magma processes in the meteorites. In general, most of the geochemical studies are using traditional methods (e.g. element to element or ratio to ratio plots) to classify the different rock type and groups. With the traditional methods, only limited elements can be shown in a figure. As such, some meteorites may have been identified as HED by a traditional method but found different either in isotopic composition or other elemental characteristic. These anomalous HED meteorites may or may not come from asteroid (4) Vesta. In fact, magma is a unit system where any elemental change should affect to all other elements as a whole, it would be reasonable to consider all elements together to look for the systematical changes. Using multivariable discriminant analysis (MDA) method is one of such testing for their geochemical variation. The method may be able to help us to better understand the petrologic processes and the relationship among elements. This study is to test the MDA method by focus mainly on pyroxene composition of eucrite and diogenite.

Peng, Z. X.↗

NASA NTRS2017

Impact-Facilitated Hydrothermal Alteration in the Rim of Endeavour Crater, Mars

Endeavour crater, a Noachian-aged, 22 km diameter impact structure on Meridiani Planum, Mars, has been investigated by the Mars Exploration Rover Opportunuity for over 2000 sols (Mars days). The rocks of the western rim region (oldest to youngest) are: (i) the pre-impact Matijevic fm.; (ii) rim-forming Shoemaker fm. polymict impact breccias; (iii) Grasberg fm., fine-grained sediments draping the lower slopes; and (iv) Burns fm., sulfate-rich sandstones that onlap the Grasberg fm. The rim is segmented and transected by radial fracture zones. Evidence for fluid-mediated alteration includes m-scale detections of phyllosilicates from orbit, and cm-scale variations in rock/soil composition/mineralogy documented by the Opportunity instrument suite. The m-scale phyllosilicate detections include Fe(3+)-Mg and aluminous smectites that occur in patches in the Matijevic and Shoemaker fms. Rock compositions do not reveal substantial differences for smectite-bearing compared to smectite-free rocks. Interpretation: large-scale hydrothermal alteration powered by impact-deposited heat acting on limited water supplies engendered mineralogic transfomations under low water/rock, near-isochemical conditions. The cm-scale alterations, localized in fracture zones, occurred at higher water/rock as evidenced by enhanced Si and Al contents through leaching of more soluble elements, and deposition of Mg, Ni and Mn sulphates and halogen salts in soils. Visible/near infrared reflectance of narrow curvilinear red zones indicate higher nanophase ferric oxide contents and possibly hydration compared to surrounding outcrops. Broad fracture zones on the rim have reflectance features consistent with development of ferric oxide minerals. Interpretation: water fluxing through the fractures in a hydrothermal system resulting from the impact engendered alteration and leaching under high water/rock conditions. Late, localized alteration is documented by Ca-sulfate-rich veins that are not confined to fracture zones; some cross-cut the Grasberg fm. Interpretation: late fluid mobilization of soluble elements, likely in a later alteration event.

Mittlefehldt, D. W.↗

NASA NTRS2017

Excess Silica Substitution in Plagioclase Grains in the Pasamonte Eucrite

Pasamonte is a clast-rich polymict basaltic breccia with O- and Cr-isotopic compositions that are resolved from those of most eucrites. It is dominated by two mafic clast types: (i) very-fine- to fine-grained, variolitic, subophitic and ophitic basalts, usually containing zoned pyroxenes; and (ii) fine- to medium grained hypidiomorphic-granular and allotriomorphic-granular microgabbros containing pyroxenes composed of augite lamellae in homogeneous pigeonite hosts. Minor clast types are fine-grained impact-melt, mafic-breccia and mafic-granular clasts; coarse matrix mineral fragments include pyroxene, plagioclase, silica, ferroan olivine and ilmenite. Our petrologic studies include determination of plagioclase compositions for the two major clast types and matrix grains, which we report here.

Mittlefehldt, D. W.↗

NASA NTRS2017

Petrology of Anomalous Mafic Achondrite Polymict Breccia Pasamonte

The most common asteroidal igneous meteorites are eucrite-type basalts and gabbros - rocks composed of ferroan pigeonite and augite, calcic plagioclase, silica, ilmenite, troilite, Ca-phosphate, chromite and Fe-metal [1]. These rocks are thought to have formed on a single asteroid, widely considered to be 4 Vesta, along with howardites and diogenites [1, 2]. High precision O-isotopic analyses have shown that some eucrites have small, well-resolved O-isotopic differences from the group mean [3-5]. These Oanomalous eucrites are thought to hail from asteroidal parents that are distinct from that of eucrites [5]. Three O-anomalous eucrites are PCA 82502, PCA 91007 (paired) and Pasamonte, all of which have the same O-isotopic composition [5, 6]. Our petrologic studies have shown that PCA 82502 and PCA 91007 have well-resolved anomalies in low-Ca pyroxene Fe/Mn compared to eucrites [6]. Divalent Mn and Fe are homologous species that do not greatly fractionate during igneous processes; mafic mineral Fe/Mn can be used to fingerprint parent object sources [7]. Previous petrological studies of Pasamonte [8-10] have not yielded sufficiently precise Fe/Mn ratios to allow distinction of anomalies of the scale of those found for the PCA basalts. We have begun petrological study of Pasamonte for comparison with our results on normal and anomalous eucrites [6], and to constrain its origin.

Mittlefehldt, D. W.↗

NASA NTRS2017

Petrology of Igneous Clasts in Regolithic Howardite EET 87503

The howardite, eucrite and diogenite (HED) clan of meteorites is widely considered to originate from asteroid 4 Vesta, as a result of a global magma ocean style of differentiation. A global magmatic stage would allow silicate material to be well mixed, destroying any initial heterogeneity that may have been present resulting in the uniformity of eucrite and diogenite delta(exp 17)O, for example. The Fe/Mn ratio of mafic phases in planetary basalts can be diagnostic of different source bodies as this ratio is little-affected by igneous processes, so long as the oxygen and sulphur fugacities are buffered. Here, pyroxene Fe/Mn ratios in mafic clasts in howardite EET 87503 have been determined to further evaluate whether the HED parent asteroid is uniform. Uniformity would suggest that the parent asteroid was subject to homogenization prior to the formation of HED lithologies, likely through an extensive melting phase. Whereas, distinct differences may point towards heterogeneity of the parent body.

Hodges, Z. V.↗

NASA NTRS2017

Acid-Sulfate Alteration at Gusev Crater and Across Mars: High-SiO2 Residues and Ferric Sulfate Precipitates

The Mars Exploration Rover Spirit ended its mission in Gusev crater on sol 2210 after it had become stuck in a deposit of fined-grained and sulfate rich soil with dust covered solar panels unfavorably pointed toward the sun. Final analysis of remaining data from Spirit's Moessbauer spectrometer (Fe redox and mineralogy) for sols 1529 through 2071 is now complete. We focus here on chemical (APXS) and MB data for targets having high-SiO2 or high-SO3 and process link the targets through mixing and geochemical modelling to an acid-sulfate system centered at Home Plate, which is considered to be a hydrovolcanic complex.

Morris, R. V.↗

NASA NTRS2017

Rim Structure, Stratigraphy, and Aqueous Alteration Exposures Along Opportunity Rover's Traverse of the Noachian Endeavour Crater

The Mars Exploration Rover Opportunity has traversed 10.2 kilometers along segments of the west rim of the 22-kilometer-diameter Noachian Endeavour impact crater as of sol 4608 (01/09/17). The stratigraphy, attitude of units, lithology, and degradation state of bedrock outcrops exposed on the crater rim have been examined in situ and placed in geologic context. Structures within the rim and differences in physical properties of the identified lithologies have played important roles in localizing outcrops bearing evidence of aqueous alteration.

Crumpler, L.S.↗

NASA NTRS2017

Acidic Fluids Across Mars: Detections of Magnesium-Nickel Sulfates

Calcium, magnesium and ferric iron sulfates have been detected by the instrument suites on the Mars rovers. A subset of the magnesium sulfates show clear associations with nickel. These associations indicate Ni(2+) co-precipitation with or substitution for Mg(2+) from sulfate-saturated solutions. Nickel is ex-tracted from primary rocks almost exclusively at pH values less than 6, constraining the formation of these Mg-Ni sulfates to mildly to strongly acidic conditions. There is clear evidence for aqueous alteration at the rim of Endeavour Crater (Meridiani Planum), in the Murray formation mudstone (Gale Crater), and near Home Plate (Gusev Crater). The discovery of Mg-Ni sulfates at these locations indicates a history of fluid-rock interactions at low pH.

Yen, A. S.↗

NASA NTRS2017

Pancam Multispectral and APXS Chemical Examination of Rocks and Soils in Marathon Valley and Points South Along the Rim of Endeavour Crater

The Mars Exploration Rover Opportunity has concluded its exploration of Marathon Valley, a 100-meter-wide valley in the western rim of the 22-kilometer-diameter Endeavour crater. Orbital observations from CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) indicated the presence of Fe smectites in Marathon Valley. Since leaving the valley, Opportunity has been traversing along the inner rim of the crater, and currently towards the outer rim. This presentation describes the Pancam 430 to 1009 nanometer (VNIR - Visible and Near Infared) multispectral reflectance and APXS (Alpha Particle X-ray Spectrometer) chemical compositions of rock and soil units observed during the latter portions of the Marathon Valley campaign on the Knudson Ridge area and observations of those materi-als along the traverse to the south. Full Pancam spectral coverage of rock targets consists of 13 filter (13f) data collections with 11 spectrally unique channels with data processing. Data were examined using spectral parameters, decorrelation stretch composites, and spectral mixture analysis. Note that color terms used here refer to colors in various false-color renditions, not true colors. The APXS determines major and select trace element compositions of targets.

Farrand, W. H.↗

NASA NTRS2017

Constraining the Origin of Basaltic Volcanic Rocks Observed by Opportunity Along the Rim of Endeavour Crater

The Mars Exploration Rover (MER) Opportunity continues its exploration along the rim of Endeavour Crater. While the primary focus for investigation has been to seek evidence of aqueous alteration, Opportunity has observed a variety of rock types, including some that are hard and relatively unaltered. These rocks tend to occur most commonly as "float rocks" or "erratics" where the geologic setting does not clearly reveal their origin. Along the rim of Endeavour crater (Fig. 1), such rocks, commonly noted in Panoramic Camera (Pancam) left eye composites as "blue rocks", are abundant components of some of the Endeavour crater rim deposits, scree slopes, and colluvium deposits. In this abstract, we examine the similarity of several of these rocks analyzed using Opportunity's Alpha Particle X-Ray Spectrometer (APXS), images and color from the Pancam, and textures observed with the Microscopic Imager (MI. At issue is the blue rocks origin; are they impact melt or volcanic, what is their age relative to Endeavour crater, and how they are related to each other?

Bouchard, M. C.↗

NASA NTRS2016

Automated Grouping of Opportunity Rover Alpha Particle X-Ray Spectrometer Compositional Data

The Alpha Particle X-ray Spectrometer (APXS) conducts high-precision in situ measurements of rocks and soils on both active NASA Mars rovers. Since 2004 the rover Opportunity has acquired around 440 unique APXS measurements, including a wide variety of compositions, during its 42+ kilometers traverse across several geological formations. Here we discuss an analytical comparison algorithm providing a means to cluster samples due to compositional similarity and the resulting automated classification scheme. Due to the inherent variance of elements in the APXS data set, each element has an associated weight that is inversely proportional to the variance. Thus, the more consistent the abundance of an element in the data set, the more it contributes to the classification. All 16 elements standard to the APXS data set are considered. Careful attention is also given to the errors associated with the composition measured by the APXS - larger uncertainties reduce the weighting of the element accordingly. The comparison of two targets, i and j, generates a similarity score, S(sub ij). This score is immediately comparable to an average ratio across all elements if one assumes standard weighted uncertainty. The algorithm facilitates the classification of APXS targets by chemistry alone - independent of target appearance and geological context which can be added later as a consistency check. For the N targets considered, a N by N hollow matrix, S, is generated where S = S(sup T). The average relation score, S(sub av), for target N(sub i) is simply the average of column i of S. A large S(sub av) is indicative of a unique sample. In such an instance any targets with a low comparison score can be classified alike. The threshold between classes requires careful consideration. Applying the algorithm to recent Marathon Valley targets indicates similarities with Burns formation and average-Mars-like rocks encountered earlier at Endeavour Crater as well as a new class of felsic rocks.

VanBommel, S. J.↗

NASA NTRS2016

Compositions of Normal and Anomalous Eucrite-Type Mafic Achondrites

The most common asteroidal igneous meteorites are eucrite-type mafic achondrites - basalts and gabbros composed of ferroan pigeonite, ferroan augite, calcic plagioclase, silica, ilmenite, troilite, Ca-phosphate, chromite and Fe-metal. These rocks are thought to have formed on a single asteroid along with howardites and diogenites. However, high precision O-isotopic analyses have shown that some mafic achondrites have small, well-resolved, non-mass-dependent differences that have been interpreted as indicating derivation from different asteroids. Some of these O-anomalous mafic achondrites also have anomalous petrologic characteristics, strengthening the case that they hail from distinct parent asteroids. We present the results of bulk compositional studies of a suite of normal and anomalous eucrite-type basalts and cumulate gabbros.

Mittlefehldt, D. W.↗

NASA NTRS2016

Igneous and Sedimentary Compositions from Four Landing Sites on Mars from the Alpha Particle X-Ray Spectrometer (APXS)

The APXS - supported and promoted strongly by Heinrich Waenke - on all four Mars Rovers has returned compositional data from about 1000 rocks and soil targets along the combined traverses of over 60 kilometers. Providing precise and accurate bulk chemistry with typically 16 quantified elements, the APXS is a powerful and versatile tool that when combined with the ability to traverse to key rocks and soils has provided critical information needed to understand the geologic evolution of Mars. APXS data allow comparisons among landing sites, provide ground truth for orbiters and connections back to SNC meteorites. The soils and dust are basaltic in character and represent the average Mars composition similar to Adirondack basalts from Gusev crater but with unambiguous elevated and correlated S, Cl and Zn contents. At all four landing sites the APXS found several rocks with a felsic composition. The similarity is best assessed in a logarithmic ratio plot of rock normalized to the average soil composition (Fig.1). High alkaline, Al, and low Mg, Fe, low S, Cl and Ni, Zn as well as an Fe/Mn ratio of approximately 50 indicate a likely unaltered and igneous origin. Sediments, e.g. the Burns formation, with approximately 25 wt% SO3 at Meridiani Planum have been documented over 10s of kilometers (Fig. 2). This formation is compositionally homogeneous, but showing the removal of MgSO4 and a threefold increase in Cl downhill in 2 craters. The degraded rim of the Noachian crater Endeavour resembles average Mars crust, with local Ca, Mg and Fe sulfate alteration and elevated Mn, some felsic rocks, and high Al, Si and low Fe rocks, possibly indicating clays. Unusual soils at Gusev crater in the area surrounding Home Plate include some very rich in ferric sulfate salts (up to 35 wt% SO3) and some with 90% wt% SiO2, possibly indicating fumerolic activities. Rocks in the Columbia Hills show significant signs of alteration including elevated S, Cl and Br in the abraded interior. At Gale Crater, mudstones with approximately 20% clay, less than 1% SO3 and overall average Mars composition indicate a former habitable environment with low acidity. A remarkable diversity of compositions was found during Curiosity's traverses, which likely stems from material influx from the northern Gale rim. At Pahrump, the base of Mount Sharp, a homogeneous mudstone with lower Mg and Ca was encountered. The composition of this Murray unit can be traced over several kilometers with smooth trends of higher Fe/Mn and lower soluble trace elements Ni and Zn at higher elevation. The likely aeolian Stimson formation with average Mars crustal composition intersects in several places in sharp contact with the Murray formation. Both units show local alteration halos with highly elevated SiO2 of up to 75%, usually correlated with increase in Ti and often P.

Gellert, R.↗

NASA NTRS2016

Opportunity Microscopic Imager Results from the Western Rim of Endeavour Crater

The Athena science payload on the Mars Exploration Rovers (MER Spirit and Opportunity) includes the Microscopic Imager (MI), a fixed focus close-up camera mounted on the instrument arm. The MI acquires images at a scale of 31 micrometers/pixel over a broad spectral range (400 to 700 nm) using only natural illumination of target surfaces. Radio signals from Spirit have not been received since March 2010, so attempts to communicate with that rover ceased in mid-2011. The Opportunity MI optics were contaminated by a global dust storm in 2007. That contamination continues to reduce the contrast of MI images, and is being monitored by occasionally imaging the sky.

Herkenhoff, K. E.↗