Engineering topics

Mlynczak, Martin G.

Publications and source records attributed to Mlynczak, Martin G..

45 records · Page 3

NASA NTRS1994

Non-local thermodynamic equilibrium limb radiance from O3 and CO2 in the 9-11 micrometer spectral region

Satellite remote sensing of mesospheric and thermospheric O3 abundance in the terrestrial atmosphere often uses 9-11 micrometer thermal emission. In this paper, we apply a line-by-line non-local thermodynamic equilibrium (non-LTE) radiance model to this spectral region and investigate the conditions of LTE breakdown and the effect that this has on the limb radiance measured by an i.r. sounder. Monochromatic and band-integrated radiance calculations have been performed for limb view tangent heights between 55 and 105 km under daytime and nighttime conditions. Non-LTE emission from both O3 and CO2 are shown to be important with the divergence of radiance from LTE values and the diurnal variation being band dependent. We have shown that the contribution of the CO2 bands to the Limb Infrared Monitor of the Stratosphere O3 channel is significant for daytime conditions at tangent heights above about 60 km. A study has been made to choose O3 sounding channel spectral passbands for the High Resolution Dynamics Limb Sounder. High resolution calculations are required to determine those spectral intervals that will filter radiance from selected bands and characterize their non-LTE behavior. This will allow for improved O3 retrievals above 70 km and non-LTE studies.

Edwards, David P.↗

NASA NTRS1993

An evaluation of the rate of absorption of solar radiation in the O2(X3Sigma-g - b1Sigma-g) transition

The rate at which molecular oxygen absorbs radiation in the O2(X3Sigma-g - b1Sigma-g) transition is calculated using a line-by-line radiative transfer model. This rate is critical to the determination of the population of the O2(b1Sigma-g) state required for studies of the O2(b1Sigma-g - X3Sigma-g) dayglow, the O2(a1Delta-g - X3Sigma-g) dayglow, and possibly the rates of oxidation of H2 and N2O. Previous evaluations of this rate (which is sometimes called the g-factor) have significantly overestimated its value. The rate is tabulated as a function of altitude, pressure, and solar zenith angle.

Mlynczak, Martin G.↗

NASA NTRS1993

A detailed evaluation of the heating efficiency in the middle atmosphere

The role of airglow losses in reducing the efficiency of solar heating in the Hartley, Huggins, and Chappuis bands of ozone in the Herzberg, Ly alpha, Schumann-Runge continuum, and in Schumann-Runge bands of molecular oxygen is investigated together with the role of heating due to seven chemical reactions in the middle atmosphere. The results of calculations of bulk efficiencies demonstrate that airglow and chemiluminescent emission significantly reduce the amount of energy available for heat throughout the mesosphere and lower thermosphere.

Mlynczak, Martin G.↗

NASA NTRS1992

Solar and chemical reaction-induced heating in the terrestrial mesosphere and lower thermosphere

Airglow and chemical processes in the terrestrial mesosphere and lower thermosphere are reviewed, and initial parameterizations of the processes applicable to multidimensional models are presented. The basic processes by which absorbed solar energy participates in middle atmosphere energetics for absorption events in which photolysis occurs are illustrated. An approach that permits the heating processes to be incorporated in numerical models is presented.

Mlynczak, Martin G.↗

NASA NTRS1991

Rapid computation of the radiative absorption rate in the nu3 mode of mesospheric and lower thermospheric ozone

An algorithm has been developed to calculate rapidly and accurately the rate at which the ozone nu3 fundamental band absorbs IR radiation in the terrestrial upper mesosphere and lower thermosphere. Accurate knowledge of this rate is essential for studies of non-LTE processes in ozone and for estimating ozone concentrations from measurements of non-LTE IR emission from the middle atmosphere. In the algorithm, the 1252 ozone nu3 fundamental lines that govern radiative absorption are divided into 13 groups according to line strength. The absorption rate due to a single line representative of the mean line strength of each group is then calculated. The total absorption rate is obtained by multiplying the absorption rate for each mean line by the total number of lines within each group and adding the resultant products for all 13 groups.

Mlynczak, Martin G.↗

NASA NTRS1991

On the efficiency of solar heating in the middle atmosphere

The efficiency at which solar ultraviolet radiation absorbed in the Hartley band of ozone is directly converted to heat in the terrestrial mesosphere and lower thermosphere (50-110 km) is calculated. The ozone molecule undergoes photolysis to yield the excited species O(1D) and O2(1Delta) with a quantum yield of about 0.9. Spontaneous emission from O2(1Delta) and from O2(1Sigma) (excited by energy transfer from O/1D/) significantly decreases the amount of energy available for heat. Similarly, the efficiency at which solar ultraviolet radiation absorbed by O2 in the Schumann-Runge continuum is directly converted to heat in the lower thermosphere (95-110 km) is calculated. The O2 undergoes photolysis and the excited product O(1D) is generated. Spontaneous emission from O2(1Sigma) (excited by energy transfer from O/1D/) reduces the amount of energy available for heat in the lower thermosphere. The consideration of these energy transfer and loss processes results in significantly reduced heating rates as compared to those conventionally calculated in models of the middle atmosphere.

Mlynczak, Martin G.↗

NASA NTRS1991

Middle atmosphere heating by exothermic chemical reactions involving odd-hydrogen species

The rate of heating which occurs in the middle atmosphere due to four exothermic reactions involving members of the odd-hydrogen family is calculated. The following reactions are considered: O + OH yields O2 + H; H + O2 + M yields HO2 + M; H + O3 yields OH + O2; and O + HO2 yields OH + O2. It is shown that the heating rates due to these reactions rival the oxygen-related heating rates conventionally considered in middle-atmosphere models. The conversion of chemical potential energy into molecular translational energy (heat) by these odd-hydrogen reactions is shown to be a significant energy source in the middle atmosphere that has not been previously considered.

Mlynczak, Martin G.↗

NASA NTRS1990

Calculation of infrared limb emission by ozone in the terrestrial middle atmosphere. I - Source functions. II - Emission calculations

The departure from LTE in the vibration-rotation bands of ozone in the middle atmosphere is analyzed using two statistical equilibrium models: the energy gap model and the simplified single model. The diurnal variations in the fundamental band source functions nu(1) and nu(3) is determined by the diurnal change in the rate of ozone photolysis by the solar radiation. Source functions are presented for the vibration-rotation bands of ozone that emit in the 9-11-micron spectral interval, over an altitude range of 1-110 km. Results are also reported of the evaluation of the radiative transfer equation incorporating these source functions and energy level populations. Using the results of the two statistical equilibrium models, calculations are carried out of the spectrally integrated limb radiance for the limb viewing geometry for daytime conditions. Results indicate that the interpretation of the measurements of spectrally integrated limb radiance from ozone will be greatly complicated by the breakdown of LTE in the vibration-rotational bands of ozone.

Mlynczak, Martin G.↗

NASA NTRS1986

Data inversion algorithm development for the hologen occultation experiment

The successful retrieval of atmospheric parameters from radiometric measurement requires not only the ability to do ideal radiometric calculations, but also a detailed understanding of instrument characteristics. Therefore a considerable amount of time was spent in instrument characterization in the form of test data analysis and mathematical formulation. Analyses of solar-to-reference interference (electrical cross-talk), detector nonuniformity, instrument balance error, electronic filter time-constants and noise character were conducted. A second area of effort was the development of techniques for the ideal radiometric calculations required for the Halogen Occultation Experiment (HALOE) data reduction. The computer code for these calculations must be extremely complex and fast. A scheme for meeting these requirements was defined and the algorithms needed form implementation are currently under development. A third area of work included consulting on the implementation of the Emissivity Growth Approximation (EGA) method of absorption calculation into a HALOE broadband radiometer channel retrieval algorithm.

Gordley, Larry L.↗