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Engineering topics

Morgan, P. E. D.

Publications and source records attributed to Morgan, P. E. D..

The Influence of Interfacial Roughness on Fiber Sliding in Oxide Composites with La-Monazite Interphases

Room temperature debonding and sliding of La-Monazite coated fibers is assessed using a composite with a polycrystalline alumina matrix and fibers of several different single crystal (mullite, sapphire) and directionally solidified eutectic (Al2O3/Y3Al5O12 and Al2O3/Y-ZrO2) compositions. These fibers provide a range of residual stresses and interfacial roughnesses. Sliding occurred over a debond crack at the fiber-coating interface when the sliding displacement and surface roughness were relatively small. At large sliding displacements with relatively rough interfaces, the monazite coatings were deformed extensively by fracture, dislocations and occasional twinning, whereas the fibers were undamaged. Dense, fine-grained (10 nm) microstructures suggestive of dynamic recrystallization were also observed in the coatings. Frictional heating during sliding is assessed. The possibility of low temperature recrystallization is discussed in the light of the known resistance of monazite to radiation damage. The ability of La-Monazite to undergo plastic deformation relatively easily at low temperatures may be enabling for its use as a composite interface.

Davis, J. B.↗

Ceramic problems/challenges in high temperature oxide superconductors - Hysteretic force measurements as a new analysis tool

A technique is presented for analyzing high-temperature oxide superconductors using hysteretic magnetic force/distance measurements. Emphasis is placed on developing low weight, highly robust superconducting materials for space applications. Bi-Ca-Sr-Cu superconductors are prepared and characterized by standard techniques. It is found that standard techniques such as XRD, SEM, and TEM are insufficient to completely characterize superconductors. The magnetic properties of the superconductors are studied with the new technique, based on measuring the force between a magnet and the superconductor as a function of their separation.

Morgan, P. E. D.↗

Syntactic intergrowth problems with BCSCO and fabrication difficulties therefrom

EDXS performed on isolated particles of the Bi-Ca-Sr-Cu-O high-temperature ceramic superconductor has verified the presence of significant elemental exchange between the Ca and Sr, and, to a lesser extent, between Cu and Bi. Two primary preparations, identified as primarily 24.4 A and 30.6 A, respectively, are identified. The Cu:Bi ratio in the 30.6 A material is approximately 1:1 for most particles, although only a few particles of the nominally 24.4 A material have the expected 1:2 ratio. No unequivocal assignment of atomic composition to the predominantly 24.4 A or 30.6 A appears possible, if major syntactic problems are present.

Morgan, P. E. D.↗