Engineering topics
Publications and source records attributed to Mumma, M. J..
Published data on a select group of SiO maser sources have been analyzed for velocity variations as a function of phase. No apparent correlation was found to a level of about 2 km/s. This places constraints on the location of the maser molecules. Such a correlation should be present at some level. The implications for future high resolution infrared measurements are discussed.
An improved CO2 laser heterodyne spectrometer is examined. The present system uses reflective optics to eliminate refocusing at different wavelengths, and the local oscillator is a line-center-stabilized isotopic CO2 laser. A tunable diffraction grating makes possible easy and rapid selection of over 50 transitions per isotope of CO2. The IF (0 to 1.6 GHz) from the HgCdTe photomizer is analyzed by a 128-channel filter bank, consisting of 64 tunable 5-MHz filters and 64 fixed 25-MHz RF filters. These filters provide resolving powers of about 1,000,000 to 10,000,000 and velocity resolution of 50 to 250 m/sec; their output is synchronously detected, integrated, multiplexed and stored in a buffer memory for the desired integration period. Kitt Peak observations show the wide spectral coverage, wide mixer and electronics bandwidth, and high sensitivity of the system.
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Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution (approximately 5 MHz = 0.000167 kaysers at 10 microns). The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described, and applications to synthetic lines of O3, CO2, CH4, and N2O are given. Some recent heterodyne measurements of CO2 and O3 absorption lines are analytically inverted, and the vertical distributions of the two gases are determined.
The paper reviews principles of laser heterodyne detection for sub-doppler spectroscopy of individual infrared spectral lines. State of the art capabilities are discussed and emphasis is placed on systems using semi-conductor diode lasers or CO2 lasers as local oscillators. Finally, the benefits of sub-doppler spectroscopy are illustrated by heterodyne spectroscopy of the atmospheres of Jupiter and Venus.
Measurements of a stratospheric ozone concentration profile are made by detecting infrared absorption lines with a heterodyne spectrometer. The infrared spectrometer is based on a line-by-line tunable CO2 lasers, a liquid-nitrogen cooled HgCdTe photomixer, and a 64-channel spectral line receiver. The infrared radiation from the source is mixed with local-oscillator radiation. The difference frequency signal in a bandwidth above and below the local-oscillator frequency is detected. The intensity in each sideband is found by subtracting sideband contributions. It is found that absolute total column density is 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio at about 24 km. The (7,1,6)-(7,1,7) O3 line center frequency is identified as 1043.1772/cm. Future work will involve a number of ozone absorption lines and measurements of diurnal variation. Completely resolved stratospheric lines may be inverted to yield concentration profiles of trace constituents and stratospheric gases.
Infrared heterodyne spectroscopy provides a means of measuring the intensity profiles of individual rotation-vibration spectral lines with high sensitivity. Considerable effort has been expended on optimizing these instruments for remote measurements of gases in planetary atmospheres with the result that present-generation spectrometers are beginning to provide new and startling results on the planets. The fundamental principles of laser heterodyne spectroscopy are discussed. Detailed considerations of the optical design and the electronic design of the spectral-line receiver are given. Representative results obtained with this spectrometer are discussed, including precision frequency measurements of NH3 (nu-2) lines, detection of auroral emission from Jupiter, and measurements of terrestrial O3 and CO2.
A stratospheric ozone absorption line in the 10 microns band was measured and resolved completely, using an infrared heterodyne spectrometer with spectral resolution of 5 MHz (0.000167 cm to -1 power). The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectral line profile. The absolute total column density was 0.34 cm atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) to (7,1,7) O3 line center frequency was found to be 1043.1775 + or - 0.00033 cm to toe -1 power, or 430 + or - 10 MHz higher than the P(24) CO2 laser line frequency.
The principles of spectral line formation and of techniques for retrieval of atmospheric temperature and constituent profiles are discussed. Applications to the atmospheres of Earth, Mars, Venus, and Jupiter are illustrated by results obtained with Fourier transform and infrared heterodyne spectrometers at resolving powers (lambda/delta hyperon lambda of approximately 10,000 and approximately 10 to the seventh power), respectively, showing the high complementarity of spectroscopy at these two widely different resolving powers. The principles of heterodyne spectroscopy are presented and its applications to atmospheric probing and to laboratory spectroscopy are discussed. Direct absorption spectroscopy with tuneable semiconductor lasers is discussed in terms of precision frequency-and line strength-measurements, showing substantial advances in laboratory infrared spectroscopy.
Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution. The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes, and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described and applications to synthetic lines of O3, CO2, CH4 and N2O are given.
A stratospheric ozone absorption line in the 10 micron band was measured and resolved completely, using an infrared heterodyne spectrometer with a spectral resolution of 5 MHz. The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectra line profile. The absolute total column density was 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) - (7,1,7) O3 line center frequency was found to be 1043.1772 plus or minus 0.00033 cm/1 or 420 plus or minus 10 MHz higher than the P(24) CO2 laser line frequency.
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Absolute line-center frequencies for eleven lines of ammonia in near coincidence with CO2-laser transitions have been determined to accuracies of + or -3 MHz by infrared heterodyne detection. These results were obtained by heterodyning a blackbody with a stable grating-tuned CO2 gas laser. A discussion of the apparatus and method of calculation, including error analysis, is presented. With these accurately determined line-center positions, the ammonia molecule will be a useful secondary-frequency standard for diode-laser spectroscopy in the 11-micron wavelength region.
The factors determining the sensitivity of a real astronomical heterodyne spectrometer are described. The deviation from the ideal heterodyne system for line detection is described in terms of a series of degradation factors. A discussion of degradation due to a low local oscillator power and to line profile detection is presented. Representative values for the degradation factors are given. Even with a total degradation of not less than 30, the heterodyne spectrometer is still found to be a highly sensitive tool in IR astronomy.
A discussion and an evaluation of the degradation in sensitivity are given for a heterodyne spectrometer employing a HgCdTe photodiode mixer and tunable diode lasers. The minimum detectable source brightness is considered as a function of the mixer parameters, transmission coefficient of the beam splitter, and local oscillator emission powers. The degradation in the minimum detectable line source brightness that results from the bandwidth being a fraction of the line width is evaluated and plotted as a function of the wavelength and bandwidth for various temperature to mass ratios. It is shown that the minimum achievable degradation in the sensitivity of a practical astronomical heterodyne spectrometer is about 30. Estimates of SNRs with which IR line emission from astronomical sources of interest may be detected are given.
Papers are presented dealing with observations of comets. Topic discussed include: photometry, polarimetry, and astrometry of comets; detection of water and molecular transitions in comets; ion motions in comet tails; determination of comet brightness and luminosity; and evolution of cometary orbits. Emphasis is placed on analysis of observations of comet Kohoutek.
Summarized are three proposed ballistic spacecraft missions to intercept P/Encke during the 1980 apparition. A baseline physical activity model for P/Encke is established and the performances of the neutral mass spectrometer and of the imaging experiment on each intercept mission are assessed.