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Mummery, Paul M.

Publications and source records attributed to Mummery, Paul M..

Using porous random fields to predict the elastic modulus of unoxidized and oxidized superfine graphite

Nuclear graphite is a candidate material for Generation IV nuclear power plants. Porous materials such as graphite can contain complex networks of pores that influence the material's mechanical and irradiation response. A methodology known as the random finite element method (RFEM) was adapted to create synthetic microstructures and predict the influence of porosity on the elastic properties of graphite during oxidation. RFEM combines random field theory and the finite element method in a Monte Carlo framework to estimate the mechanical response of a given grade of graphite. In this research, the random fields were verified through experimental characterization to predict the elastic response of three nuclear graphite grades, ETU-10, IG-110, and 2114. Finite element models (FEM) were generated using segmentations of x-ray computed tomography (XCT) data known as image-based models (IBMs) to validate and compare with the RFEM results and better understand the effects of uniform oxidation in these graphite grades. The RFEM predictions appear to correlate well with the experimental values of the measured Young’s modulus of the three graphite grades and display the same trends as IBMs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The distribution and selective decontamination of carbon-14 from nuclear graphite

This work investigates 14 C release behaviour from UK Magnox reactor sourced irradiated graphite under relatively low temperature oxidation conditions: a 1% oxygen in argon atmosphere at temperatures ranging from 600°C to 700°C, and durations from 4 to 120 hours. A method is used for construction of a detailed 14 C release profile with mass loss. The 14 C release profile is predictable between samples, and an empirical release profile is derived to predict releases to higher mass losses than in this work. An accelerated 14 C release rate at small mass losses is observed, indicative of a 14 C-enriched surface region with a depleting concentration gradient into the material, and the source terms and complexities associated with predicting where the 14 C arose from are discussed. Selective decontamination of a fraction of the 14 C is possible, with the limitation of a reducing efficiency with mass loss and time. This work demonstrates a method for determining the distribution of 14 C between near-surface regions and the bulk material in differing sources of irradiated graphite, and provides data in support of making an informed assessment for the adoption of low temperature thermal treatment and isotopic reduction of irradiated graphite wastes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗