Effects of metal cation substitution on hexavalent chromium reduction by green rust
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Engineering topics
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ICESat-2 carries NASA's next-generation laser altimeter, ATLAS, (Advanced Topographic Laser Altimeter System), designed to measure changes in ice sheet height, sea ice freeboard, and vegetation canopy height. ATLAS contains a photon-counting lidar which transmits green (532-nm) pulses at 10kHz. Each pulse is split into 3 pairs of beams (one strong and one weak). Approximately 1014 photons per pulse travel from ATLAS through the atmosphere to reflect off the Earth's surface. Some return back into the ATLAS telescope where they are recorded. Photons from sunlight and instrument noise at the same wavelength are also recorded. The flight software time tags all photons within a 500m to 6 km range window and generates histograms. Using the histograms, it selects a telemetry window which varies from 20m over flat surfaces to hundreds of meters over rougher terrain. ATL03 contains the time, height (relative to the WGS-84 ellipsoid), latitude and longitude of every photon within the telemetry window. The basic challenge is to determine which of these photons were reflected off the surface. We have developed an algorithm that identifies these signal photons and assigns a confidence level (low, medium, or high) to each signal photon based on the signal to noise ratio. We present an overview of the signal identification algorithm and show the results on actual ICESat-2 data over ice sheet, sea ice, vegetated, and water surfaces. Higher level ATLAS products work with aggregations of the photons in order to determine the ellipsoidal height of the Earth, canopy height and structure, and other quantities of geophysical interest.
Large offshore wind farms are usually clustered around transmission grids to minimize the expense of transmission, due to military zones, pipelines, and due to other uses such as nature preserves. However, this close proximity can undermine power production in downwind wind farms due to wakes from upwind wind farms. Therefore, the wind energy industry has great interest in determining the spatial dimensions of offshore wind farm wakes to assess the economical potential of planned wind farms. In this work we use wake measurements conducted by a research aircraft to evaluate the performance of a wind farm parameterization (WFP) in a mesoscale model during stably-stratified atmospheric conditions, in which the wake is expected to be the strongest. The observations were conducted on the 10 September 2016 within the project WIPAFF (Wind PArk Far Field) at the North Sea. The observations allow evaluation of both the horizontal and the vertical dimensions of the wake. The model simulates the length and most of the time the spatial dimensions of the wake. Further, we show that the largest potential for improving the performance of the WFP is rooted in an improvement of the background flow. This is due to the fact that the mesoscale model has problems representing the atmospheric boundary layer in the transition between land to open sea.
We propose a new ice sheet model validation framework the Cryospheric Model Comparison Tool (CMCT) that takes advantage of ice sheet altimetry and gravimetry observations collected over the past several decades and is applied here to modeling of the Greenland ice sheet. We use realistic simulations performed with the Community Ice Sheet Model (CISM) along with two idealized, non-dynamic models to demonstrate the framework and its use. Dynamic simulations with CISM are forced from 1991 to 2013 using combinations of reanalysis-based surface mass balance and observations of outlet glacier flux change. We propose and demonstrate qualitative and quanti- tative metrics for use in evaluating the different model simulations against the observations. We find 10 that the altimetry observations used here are largely ambiguous in terms of their ability to distinguish one simulation from another. Based on basin- and whole-ice-sheet scale metrics, the model initial condition as well as output from idealized and dynamic models all provide an equally reasonable representation of the ice sheet surface (mean elevation differences of <1 m). This is likely due to their short period of record, biases inherent to digital elevation models used for model initial conditions, and biases resulting from firn dynamics, which are not explicitly accounted for in the models or observations. On the other hand, we find that the gravimetry observations used here are able to unambiguously distinguish between simulations of varying complexity, and along with the CMCT, can provide a quantitative score for assessing a particular model and/or simulation. The new framework demonstrates that our proposed metrics can distinguish relatively better from relatively worse simulations and that dynamic ice sheet models, when appropriately initialized and forced with the right boundary conditions, demonstrate predictive skill with respect to observed dynamic changes occurring on Greenland over the past few decades. An extensible design will allow for continued use of the CMCT as future altimetry, gravimetry, and other remotely sensed data become available for use in ice sheet model validation.
NASA;s Ice, Cloud, and Land Elevation Satellite-2 (ICESat-2) mission, scheduled to launch no later than April 2018 (and currently slated for October 2017), is being developed to continue the multiyear observations of the earths surface elevation, ice, and clouds started by ICESat. To increase the use of the satellite data after launch, the ICESat-2 mission invested in an applications program aimed at innovatively applying the data in a variety of fields. The program provides a framework for building a broad and well-defined user community during the prelaunch period to maximize the use of data products after launch and to provide early insight into the range of potential uses of the mission data. Ideas and research on how altimetry data will be used for decision making arise from the end users; there-fore, the ICESat-2 mission is extending itself through its applications program.
The Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) is a next-generation laser altimeter designed to continue key observations of ice sheet elevation change, sea ice freeboard, vegetation canopy height, earth surface elevation, and sea surface height. Scheduled for launch in mid-2016, ICESat-2 will use a high repetition rate (10 kHz), small footprint (10 m nominal ground diameter) laser, and a single-photon-sensitive detection strategy (photon counting) to measure precise range to the earth's surface. Using green light (532 nm), the six beams of ICESat-2 will provide improved spatial coverage compared with the single beam of ICESat, while the differences in transmit energy among the beams provide a large dynamic range. The six beams are arranged into three pairs of beams which allow slopes to measured on an orbit-by-orbit basis. In order to evaluate models of predicted ICESat-2 performance and provide ICESat-2-like data for algorithm development, an airborne ICESat-2 simulator was developed and first flown in 2010. This simulator, the Multiple Altimeter Beam Experimental Lidar (MABEL) was most recently deployed to Iceland in April 2012 and collected approx 85 hours of science data over land ice, sea ice, and calibration targets. MABEL uses a similar photon-counting measurement strategy to what will be used on ICESat-2. MABEL collects data in 16 green channels and an additional 8 channels in the infrared aligned across the direction of flight. By using NASA's ER-2 aircraft flying at 20km altitude, MABEL flies as close to space as is practical, and collects data through approx 95% of the atmosphere. We present background on the MABEL instrument, and data from the April 2012 deployment to Iceland. Among the 13 MABEL flights, we collected data over the Greenland ice sheet interior and outlet glaciers in the southwest and western Greenland, sea ice data over the Nares Strait and Greenland Sea, and a number of small glaciers and ice caps in Iceland and Svalbard. Several of the flights were coincident in time and space with NASA's Operation IceBridge, which provides an independent data set for validation. MABEL also collected data along CryoSat track 10482 in north central Greenland approximately one month after CryoSat passed overhead.
The Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) mission is currently under development by NASA. The primary mission of ICESat-2 will be to measure elevation changes of the Greenland and Antarctic ice sheets, document changes in sea ice thickness distribution, and derive important information about the current state of the global ice coverage. To make this important measurement, NASA is implementing a new type of satellite-based surface altimetry based on sensing of laser pulses transmitted to, and reflected from, the surface. Because the ICESat-2 measurement approach is different from that used for previous altimeter missions, a high-fidelity aircraft instrument, the Multiple Altimeter Beam Experimental Lidar (MABEL), was developed to demonstrate the measurement concept and provide verification of the ICESat-2 methodology. The MABEL instrument will serve as a prototype for the ICESat-2 mission and also provides a science tool for studies of land surface topography. This paper outlines the science objectives for the ICESat-2 mission, the current measurement concept for ICESat-2, and the instrument concept and preliminary data from MABEL.
Satellite and aircraft observations have revealed that remarkable changes in the Earth s polar ice cover have occurred in the last decade. The impacts of these changes, which include dramatic ice loss from ice sheets and rapid declines in Arctic sea ice, could be quite large in terms of sea level rise and global climate. NASA's Ice, Cloud and Land Elevation Satellite-2 (ICESat-2), currently planned for launch in 2015, is specifically intended to quantify the amount of change in ice sheets and sea ice and provide key insights into their behavior. It will achieve these objectives through the use of precise laser measurements of surface elevation, building on the groundbreaking capabilities of its predecessor, the Ice Cloud and Land Elevation Satellite (ICESat). In particular, ICESat-2 will measure the temporal and spatial character of ice sheet elevation change to enable assessment of ice sheet mass balance and examination of the underlying mechanisms that control it. The precision of ICESat-2's elevation measurement will also allow for accurate measurements of sea ice freeboard height, from which sea ice thickness and its temporal changes can be estimated. ICESat-2 will provide important information on other components of the Earth System as well, most notably large-scale vegetation biomass estimates through the measurement of vegetation canopy height. When combined with the original ICESat observations, ICESat-2 will provide ice change measurements across more than a 15-year time span. Its significantly improved laser system will also provide observations with much greater spatial resolution, temporal resolution, and accuracy than has ever been possible before.