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Nichols, John

Publications and source records attributed to Nichols, John.

7 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Engineering Design of a Linde-BASF Advanced Post-Combustion CO 2 Capture Technology at a Linde Steam Methane Reforming H 2 Plant

Linde carried out an initial engineering design study for a Linde-BASF advanced post combustion CO 2 capture technology to be installed at a commercial-scale steam methane reforming (SMR) hydrogen plant located in the US Gulf Coast. This pre-FEED equivalent study included following: (1) basic design, including specific project scope definition and design basis, (2) basic engineering, including development of process flow diagrams and heat & material balances, (3) inside the battery limit (ISBL) equipment and systems specification, (4) balance of plant outside the battery limit (OSBL) equipment and systems specifications, (5) technology maturation plan, (6) hazard and operability (HAZOP) review, (7) environmental, health and safety (EH&S) assessment and environmental permitting analysis, (8) constructability review, (9) ISBL and OSBL EPC cost estimation, and (10) commercial-scale techno-economic analysis including capital expenditures (CAPEX) and operating expenditures (OPEX) and CO 2 capture cost estimates.

08 HYDROGEN↗
DOE OSTI2022

Front End Engineering Design of Linde-BASF Advanced Post-Combustion CO 2 Capture Technology at a Southern Company Natural Gas-Fired Power Plant (Final Scientific/Technical Report)

This document details the execution of Cooperative Agreement DE-FE0031847, “Front End Engineering Design of Linde-BASF Advanced Post-Combustion Carbon Dioxide (CO 2 ) Capture Technology at a Southern Company Natural Gas-Fired Power Plant” during the period of 10/1/2019 to 6/30/2022. The project was funded by the U.S. Department of Energy’s Office of Fossil Energy and Carbon Management (FECM) and managed by the National Energy Technology Laboratory (NETL). Southern Company Services, Inc. (SCS) was the prime recipient and led the project team. Other members of the project team included Linde, Inc. (Linde), Linde Engineering – Dresden (LED), and BASF. The overall goal of the project was to complete a front-end engineering design (FEED) study for installing the Linde-BASF post-combustion capture (PCC) technology at an existing domestic natural gas-fired combined cycle (NGCC) power plant within Southern Company’s portfolio of assets. The CO 2 capture plant was to be of commercial scale (at least 375 MWe) and include process units for pre-conditioning of the flue gas system, the CO 2 capture plant island, storage vessels, the CO 2 compression train, and any necessary components for integration into the NGCC plant. Mississippi Power’s Plant Daniel Unit #4 was chosen as the host site for the FEED with the target of capturing 90% of CO 2 emissions from the existing combustion turbines. The information produced by the FEED was used to develop a cost estimate of +/- 15% accuracy. Capital costs, excluding financing, are estimated at approximately $\$752$ million dollars (2021). The execution of a project based on this FEED study has an estimated duration of almost five years.

03 NATURAL GAS↗
DOE OSTI2020

Interfacial tuning of chiral magnetic interactions for large topological Hall effects in LaMnO 3 /SrIrO 3 heterostructures

Chiral interactions in magnetic systems can give rise to rich physics manifested, for example, as nontrivial spin textures. The foremost interaction responsible for chiral magnetism is the Dzyaloshinskii-Moriya interaction (DMI), resulting from inversion symmetry breaking in the presence of strong spin-orbit coupling. However, the atomistic origin of DMIs and their relationship to emergent electrodynamic phenomena, such as topological Hall effect (THE), remain unclear. Here, we investigate the role of interfacial DMIs in 3 d –5 d transition metal-oxide-based LaMnO 3 /SrIrO 3 superlattices on THE from a chiral spin texture. By additively engineering the interfacial inversion symmetry with atomic-scale precision, we directly link the competition between interfacial collinear ferromagnetic interactions and DMIs to an enhanced THE. The ability to control the DMI and resulting THE points to a pathway for harnessing interfacial structures to maximize the density of chiral spin textures useful for developing high-density information storage and quantum magnets for quantum information science.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Photoemission and dynamical mean field theory study of electronic correlations in a t 2 g 5 metal SrRhO 3 thin film

Perovskite rhodates are characterized by intermediate strengths of both electronic correlation as well as spin-orbit coupling (SOC) and usually behave as moderately correlated metals. A recent publication on epitaxial SrRhO 3 thin films reported a bad-metallic behavior and suggested the occurrence of antiferromagnetism below 100 K. In this work, we have further studied this SrRhO 3 thin film by hard x-ray photoemission spectroscopy and found a very small density of states (DOS) at the Fermi level $(E_F)$, which is consistent with the previously reported bad-metallic behavior. However, the absence of DOS persists up to room temperature, which contradicts the explanation of antiferromagnetic transition at ~100 K. We also employed electronic structure calculations within the framework of density functional theory and dynamical mean-field theory. In contrast to the photoemission results, our calculations indicate metallic behaviors of both bulk SrRhO 3 and the SrRhO 3 thin film, and a stronger correlation effect was observed in the thin film than that in the bulk. The calculated uniform magnetic susceptibility is substantially larger in the thin film than that in the bulk. We also investigated the role of SOC and found only a moderate modulation of the band structure. Hence SOC is not expected to significantly affect the electronic correlation in SrRhO 3 . Extrinsic effects of finite-thickness effects beyond our calculations and localization effects may play important roles to induce the negligible spectral weight at $(E_F)$.

36 MATERIALS SCIENCE↗
NASA NTRS2017

Transformational Solar Array Final Report

We have made outstanding progress in the Base Phase towards achieving the final NASA Research Announcement (NRA) goals. Progress is better than anticipated due to the lighter than predicted mass of the IMM solar cells. We look forward to further improvements in the IMM cell performance during Option I and Option II; so, we have confidence that the first four items listed in the table will improve to better than the NRA goals. The computation of the end of life blanket efficiency is uncertain because we have extrapolated the radiation damage from room temperature measurements. The last three items listed in the Table were not intended to be accomplished during the Base Phase; they will be achieved during Option I and Option II.

Gaddy, Edward↗
NASA NTRS2017

Transformational Solar Array Option I Final Report

This report summarizes the work performed under NASA contract NNC16CA19C from May 2, 2017 through April 2, 2018. This work is directed toward meeting the goals of the associated NASA NRA and, of course, the requirements of the contract. In brief, the goals are: (1) Over 47% beginning of life cell efficiency at 5 AU and -125 °C (2) Over 32% end of life efficiency at the blanket level at 50 W m-2, -125 °C and 4E15 1 MeV e cm-2 (3) Over 8 W kg-1 at EOL for the entire array including structure, deployment, and pointing mechanisms using beginning of life performance. (4) A stowed packaging density of greater than 66 kW m-3 (5) An ability to survive launch and numerous deploy retract cycles without degradation (6) An output higher than 300 V (7) An ability to operate in a plasma generated by xenon thrusters, typically 1E8 cm-3 ions with an average energy of 2 eV (8) A design compatible with electrostatic and magnetic cleanliness (9) Record breaking inverted metamorphic (IMM) 6 junction solar cells (10) IMM solar cells that have no anomalous flat spot behavior at low irradiance and low temperature (11) A mock-up production line for the low-cost manufacture of spacecraft blanket arrays. The Option I phase of the project continued efforts, started in the base-phase, to eliminate or reduce to very low levels the flat spots that reduce power to an unacceptable value in a significant percentage of cells and to reduce outgassing contamination of the concentrators to acceptable levels. Option I adds tasks to increase the efficiency of IMM cells from those produced in the Base Phase, to eliminate delamination of the coatings that were present in previous versions of the concentrator mirrors, to evaluate pressure sensitive adhesive as a method of fixing solar cell assemblies to blankets, to design a magnetically clean brake for ROSA, to test the robustness of a sample blanket in deploy and retract, to test for the adequate performance of a blanket in vibration and thermal environments, and to define the capital equipment needed to optimize production of the Transformational Array. 5 Work for this Final Report showed that the greatest likely improvement in the solar cells would be by emphasizing the effort for the IMM4 solar cells and stopping work on other IMM cells. For this phase, the solar cell work was primarily on the IMM4 cells with little work on IMM5 and none on IMM6 cells.

Gaddy, Edward↗