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Niemann, H.

Publications and source records attributed to Niemann, H..

Plasma radiation behavior approaching high-radiation scenarios in W7-X

The W7-X stellarator has so far performed experiments under both limiter and divertor conditions. The plasma is mostly generated by ECR-heating with powers up to 6.5 MW, and the plasma density is usually limited by the radiation losses from low-Z impurities (such as carbon and oxygen) released mainly from the graphite targets. The present work first summarizes the radiation loss fractions f rad achieved in quasi-stationary hydrogen plasmas in both operational phases, and then shows how impurity radiation behaves differently with the two different boundary conditions as the plasma density increases. The divertor operation is emphasized and some beneficial effects (with respect to impurity radiation) are highlighted: (1) intensive radiation is located at the edge (r/a > 0.8) even at high radiation loss fractions, (2) the plasma remains stable up to f rad approaching unity, (3) the reduction in the stored energy is about 10% for high f rad scenarios. Moreover, effects of wall boronisation on impurity radiation profiles are also presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Results from the Gas Chromatograph Mass Spectrometer (GCMS) Experiment on the Cassini-Huygens Probe

The Gas Chromatograph Mass Spectrometer was one of six instruments on the Cassini-Huygens Probe mission to Titan. The GCMS measured in situ the chemical composition of the atmosphere during the probe descent and served as the detector for the pyrolization products for the Aerosol Collector Pyrolyser (ACP) experiment to determine the composition of the aerosol particles. The GCMS collected data from an altitude of 146 km to ground impact. The Probe and the GCMS survived impact and collected data for 1 hour and 9 minutes on the surface. Mass spectra were collected during descent and on the ground over a range of m/z from 2 to 141. The major constituents of the lower atmosphere were confirmed to be N2 and CH4. The methane mole fraction was uniform in the stratosphere. It increased below the tropopause, at about 32 km altitude, monotonically toward the surface, reaching a plateau at about 8 km at a level near saturation. After surface impact a steep increase of the methane signal was observed, suggesting evaporation of surface condensed methane due to heating by the GCMS sample inlet heater. The measured mole fraction of Ar-40 is 4.3x10(exp -5) and of Ar-36 is 2.8x10(exp -7). The other primordial noble gases were below 10(exp -8) mole fraction. The isotope ratios of C-12/C-13 determined from methane measurements are 82.3 and of N-14/N-15 determined from molecular nitrogen are 183. The D/H isotope ratio determined from the H2 and HD measurements is 2.3x10(exp -4). Carbon dioxide, methane, acetylene and cyanogen were detected evaporating from the surface in addition to methane. The GCMS employed a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns, a chemical scrubber and a hydrocarbon enrichment cell. The GCMS gas inlet was heated to prevent condensation, and to evaporate volatiles from the surface after impact.

Niemann, H.↗

The Origin of Planetary Nitrogen

The nitrogen found today in planetary atmospheres appears to come from two sources: N2 and condensed, nitrogen-containing compounds. On Jupiter and thus presumably on the other giant planets, the nitrogen is present mainly as ammonia but was apparently delivered primarily in the form of N2, whereas on the inner planets and Titan, the nitrogen is present as N2 but was delivered as condensed compounds, dominated by ammonia. This analysis is consistent with abundance data from the Interstellar Medium and models for the solar nebula. For Jupiter and the inner planets, it is substantiated by measurements of N-l5/N-14 and is supported by investigations of comets and meteorites, soon to be supplemented by solar wind data from the Genesis Mission. The Cassini-Huygens Mission may be able to constrain models for Saturn s ammonia abundance that could test the proportion of N2 captured by the planet. The Titan story is less direct, depending on studies of noble gases. These studies in turn suggest an evolutionary stage of the early Earth s atmosphere that included the ammonia and methane postulated by S. L. Miller (1953) in his classical experiments on the production of biogenic compounds.

Owen, T.↗

Cassini-Huygens Probe Gas Chromatograph Mass Spectrometer (GCMS) Experiment: First Results

The Huygens Probe of the Cassini Huygens Mission entered the atmosphere of the moon Titan on January 14, 2005. The GCMS was part of the instrument complement on the probe to measure in situ the chemical composition of the atmosphere during the probe descent and to support the Aerosol Collector Pyrolyzer (ACP) experiment by serving as detector for the pyrolization products. The GCMS collected data from an altitude of 146 km to ground impact for a time interval of 2hours and 37minutes. The Probe and the GCMS survived the ground impact and collected data for 1hour and 9 minutes on the surface in the near surface environment until signal loss by the orbiter. The major constituents of the lower atmosphere were found to be N2 and CH4. The methane-mixing ratio was found to increase below the turbopause, about 35 km altitude, monotonically toward the surface to levels near saturation. After surface impact a steep increase of the mixing ratio was observed suggesting evaporation of surface condensed methane due to heating by the GCMS sample inlet heater. Other constituents were found to be in very low concentrations, below ppm levels. The presence of Argon 40 was confirmed. The results for the other noble gases are still being evaluated. Other hydrocarbons and nitriles were also observed and quantitative evaluation is in progress. Preliminary ratios for the major carbon and nitrogen isotopes were computed from methane and molecular nitrogen measurements. The instrument collected 5634 mass spectra during descent and 2692 spectra on the ground over a range of m/z from 2 to 141. Eight gas chromatograph samples were taken during the descent and two on the ground.

Niemann, H.↗

The Gas Chromatograph Mass Spectrometer (GCMS) Experiment on the Cassini-Huygens Probe: First Results

The Huygens Probe of the Cassini Huygens Mission entered the atmosphere of the moon Titan on January 14, 2005. The GCMS was part of the instrument complement on the Probe to measure in situ the chemical composition of the atmosphere during the probe descent and to support the Aerosol Collector Pyrolyzer (ACP) experiment by serving as detector for the pyrolization products. The GCMS collected data from an altitude of 146 km to ground impact for a time interval of 2 hours and 37 minutes. The Probe and the GCMS survived the ground impact and collected data for 1 hour and 9 minutes on the surface in the near surface environment until signal loss by the orbiter. The instrument collected 5634 mass spectra during descent and 2692 spectra on the ground over a range of m/z from 2 to 141. Eight gas chromatograph samples were taken during the descent and two on the ground. This is a report on work in progress. The major constituents of the lower atmosphere were found to be N2 and CH4. The methane-mixing ratio was found to increase below the turbopause, about 35 km altitude, monotonically toward the surface to levels near saturation. After surface impact a steep increase of the mixing ratio was observed suggesting evaporation of surface condensed methane due to heating by the GCMS sample inlet heater. Other constituents were found to be in very low concentrations, below ppm levels. The presence of Argon 40 was confirmed. The results for the other noble gases are still being evaluated. Other hydrocarbons and nitriles were also observed and quantitative evaluation is in progress. Preliminary ratios for the major carbon and nitrogen isotopes were computed from methane and molecular nitrogen measurements.

Niemann, H.↗

Ion Neutral Mass Spectrometer Measurements from Titan

Introduction: The Ion Neutral Mass Spectrometer (INMS) aboard the Cassini orbiter has obtained the first in situ composition measurements of the neutral densities of molecular nitrogen, methane, argon, and a host of stable carbon-nitrile compounds in its first flyby of Titan. The bulk composition and thermal structure of the moon s upper atmosphere do not appear to be changed since the Voyager flyby in 1979. However, the more sensitive techniques provided by modern in-situ mass spectrometry also give evidence for large-spatial-scale large-amplitude atmospheric waves in the upper atmosphere and for a plethora of stable carbon-nitrile compounds above 1174 km. Furthermore, they allow the first direct measurements of isotopes of nitrogen, carbon, and argon, which provide interesting clues about the evolution of the atmosphere. The atmosphere was first accreted as ammonia and ammonia ices from the Saturn sub-nebula. Subsequent photochemistry likely converted the atmosphere into molecular nitrogen. The early atmosphere was 1.5 to 5 times more substantial and was lost via escape over the intervening 4.5 billion years due to the reduced gravity associated with the relatively small mass of Titan. Carbon in the form of methane has continued to outgas over time from the interior with much of it being deposited in the form of complex hydrocarbons on the surface and some of it also being lost to space.

Waite, J. H., Jr.↗

The Cassini-Huygens Mission: Exo/Astro/Cosmobiological Perspectives

One of the main objectives of the Cassini-Huygens mission is to explore Titan in great detail and to study in particular the many exobiological aspects of Titan, this exotic world which presents so many analogies with our planet. The Cassini orbiter and the Huygens probe, in a complementary way, will systematically study the many chemical and physical aspects of the different parts of what can be called the "geofluid" of Titan. Many of the twelve instruments of the Cassini orbiter and most of the six instruments of the Huygens probe will provide much information of crucial importance for our knowledge of the complexity of Titan's organic chemistry. This is particularly the case with the GC-M4S and ACP experiments which will provide the first in situ chemical (including isotopic and molecular) analyses of the gas and aerosol phases of Titan's atmosphere. Indeed, because of the presence of a dense atmosphere, mainly made of N2 with noticeable fraction of CH4, and of an environment very rich in organics, and of many couplings involved in the various parts of its geofluid, in spite of low temperatures and the absence of liquid water, Titan is a reference for studying prebiotic chemistry on a planetary scale. Many programs have recently been developed to study in detail Titan's chemistry, in direct connection with the Cassini-Huygens mission. They include new observations, development of photochemical models, laboratory determination of IR and UV spectra of organics of interest for Titan's atmosphere, and experimental studies, such as laboratory simulation of Titan's gas and aerosol organic chemistry. The paper will review the exobiological aspects of Titan. It will also present some of the new data concerning Titan s organic chemistry that have been obtained through the several possible approaches and discuss the exobiological implication of the potential scientific return of the Cassini-Huygens mission.

Raulin, F.↗

Mars Solar Balloon Landed Gas Chromatograph Mass Spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload. The GCMS would obtain samples directly from the atmosphere at the surface and also from gases evolved from solid phase material collected from well below the surface with a Sample Acquisition and Transport Mechanism (SATM). The experiment envisioned in the Mars Micromission described would obtain samples from a much greater depth of up to one meter below the surface, and would search for organic molecules trapped in ancient stratified layers well below the oxidized surface. Insitu instruments on upcoming NASA missions working in concert with remote sensing measurement techniques have the potential to provide a more detailed investigation of mineralogy and the extent of simple volatiles such as CO2 and H2O in surface and subsurface solid phase materials. Within the context of subsequent mission opportunities such as those provided by the Ariane 5 piggyback payload based Micromissions, it is essential to implement an even broader chemical analysis and to enable a significant extension of previous isotope measurements. Such a development would enhance the presently very active study of questions of atmospheric evolution and loss and past climatic conditions. The method selected to implement this program can be based on well-established mass spectrometry techniques. Sampled gas is chemically and physically processed to separate the gas mixture into components using gas chromatograph and related enrichment techniques. This allows trace species to be identified and reveals isotopic distributions in many cases with improved precision. Samples of interest, such as organic molecules, may lie deep below the highly oxidized surface layer and the suggested program includes enhanced sampling techniques to measure volatiles preserved in solid phase material deep below the surface as well as gas from the well mixed atmosphere.

Mahaffy, P.↗

Composition of the Venus atmosphere

After giving an historical account of the development of Venus atmospheric composition explorations and the various instrumental techniques used in them, attention is given to recommended values for the mixing ratios of gases at altitudes below 100 km. Together with the various constituent groups of gases, their observations, and related processes and models, the mathematical background for current one-dimensional photochemical and transport models is given. Excited species are then discussed, and references to upper limits for the abundances of unobserved gases are listed. Available data on isotopic abundances are assessed, and questions pertinent to the further investigation of the Venus atmosphere's origin and evolution are formulated.

Von Zahn, U.↗

Variations in ion and neutral composition at Venus - Evidence of solar control of the formation of the predawn bulges in H/+/ and He1

A comparison of ion and neutral composition measurements at Venus for periods of greatly different solar activity provides qualitative evidence of solar control of the day-to-night transport of light ion and neutral species. Concentrations of H(+) and He in the predawn bulge near solar maximum in November, 1979, exhibit a depletion signature correlated with a pronounced modulation in the solar F10.7 and EUV fluxes. This perturbation, not observed in the predawn region during an earlier period of relative quiet solar conditions, is interpreted as resulting from pronounced changes in solar heating and photoionization on the dayside, which in turn modulate the transport of ions and neutrals into the bulge region.

Taylor, H. A., Jr.↗

Composition and structure of the atmosphere of Venus

Some of the main questions regarding the composition, structure, and origin of the atmosphere of Venus are posed. These questions are (1) the distribution of the constituents of the lower atmosphere, (2) cloud composition, (3) the planet's surface and interior as revealed by atmospheric data, (4) the state property profiles and their variation over the planet, (5) the reason for the high temperatures of the lower atmosphere, (6) composition and temperature profiles of the upper atmosphere and location of the homopause, (7) spatial and temporal variations in the upper atmosphere, (8) the cause of the stability of CO2 - global circulation or local turbulence, (9) influence of neutral composition on the thermal structure, (10) response of upper atmosphere to change in solar EUV and solar wind, (11) the source and destination of the atmosphere, and (12) the location of Venus's water. The main parameters to be measured which will aid in resolving these problems are enumerated.

Hoffman, J. H.↗