Investigation of minimum NOx emissions for cracked ammonia combustion
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Engineering topics
Publications and source records attributed to Noble, David.
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Abstract Ammonia (NH3) is being explored as a hydrogen carrier with no carbon emissions. However, if burned directly as NH3, rather than being completely decomposed back to N2/H2, the fuel-bound nitrogen comes with a potentially significant NOx emissions penalty. Indeed, several existing studies are showing ammonia combustion NOx emissions that exceed current natural gas fueled, DLN technologies by one to two orders of magnitude. Therefore, it is important to establish the theoretical minimum NOx emissions for an ammonia combustor, to determine how much NOx levels can be reduced via further technology development. In other words, the purpose of this work is not to analyze the performance of a specific combustor but, rather, the fundamental limits of what is achievable. This study quantifies this minimum NOx level for a two-stage combustor system for a given combustor exit temperature and residence time, with a constraint on unburned fuel levels. As expected, the optimum configuration is a rich front end combustor to burn and crack ammonia with significant H2 production, followed by an NO relaxation reactor, followed by a lean stage that consumes the remaining H2. The optimum residence time and stoichiometry of each zone are determined in the fast mixing limit, which essentially balances between NOx production in the primary and secondary zones. These results show minimum NOx levels are in 200–400 ppm range at 1 bar, but drop to levels of ∼25 ppm at 20 bar. These NOx emissions are dominated by NOx production in the primary stage which relaxes to equilibrium levels quite slowly. As processes controlling NOx relaxation to equilibrium in the primary stage dominate overall NO emission levels, combustor NOx sensitivities are essentially opposite that of natural gas fired, DLN systems. Specifically, NOx values drop with increased combustor residence time, increased pressure, and increased combustor exit temperature. These results also suggest that the most important strategy for NOx minimization is to provide sufficient relaxation time after the primary zone for NOx to approach equilibrium—this can be done via kinetic means to accelerate this relaxation rate, such as enhancing pressure or temperature, or increasing residence times. Indeed, this work shows that low pressure combustors specifically optimized for ammonia will have residence times that are one to two orders of magnitude larger than current natural gas systems. By doing so, NOx levels below 10 ppm may be achievable. Finally, we discuss the sensitivity of these values to uncertainties in ammonia kinetics.
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Combustion instability in gas turbines is often mitigated using fuel staging, a strategy where the fuel is split unevenly between different nozzles of a multiple-nozzle combustor. This work examines the efficacy of different fuel staging configurations by comparing axisymmetric and non-axisymmetric fuel staging in a four-around-one model gas turbine combustor. Fuel staging is accomplished by increasing the equivalence ratio of the center nozzle (axisymmetric staging) or an outer nozzle (non-axisymmetric staging). When the global equivalence ratio is ϕ = 0.70 and all nozzles are fueled equally, the combustor undergoes longitudinal, self-excited oscillations. These oscillations are suppressed when the center nozzle equivalence ratio is increased above ϕ Staging = 0.79. This bifurcation equivalence ratio varies between ϕ Staging = 0.86 and ϕ Staging = 0.76 for the outer nozzles, and is attributed to minor hardware differences between each nozzle. High speed CH* chemiluminescence images in combination with dynamic pressure measurements are used to determine the instantaneous phase difference between the heat release rate fluctuation and the combustor pressure fluctuation throughout the combustor. This analysis shows that the staged flame has similar phase relationships for all staging configurations. It is found that axisymmetric staging can be as effective as non-axisymmetric staging; however, the aforementioned hardware variations can impact both the bifurcation equivalence ratio and the effectiveness of staging.
The SIERRA Toolkit is a collection of libraries to facilitate the development of parallel engineering analysis applications. These libraries supply basic core services that an engineering application may need such as a parallel distributed and dynamic mesh database (for unstructured meshes), mechanics algorithm support (parallel infrastructure only), interfaces to parallel solvers, parallel mesh and data I/O, and various utilities (timers, diagnostic tools, etc.)
Remote Access Multi-mission Processing and Analysis Ground Environment (RAMPAGE) is a Java-language server computer program that enables near-real-time display of spacecraft telemetry data on any authorized client computer that has access to the Internet and is equipped with Web-browser software. In addition to providing a variety of displays of the latest available telemetry data, RAMPAGE can deliver notification of an alarm by electronic mail. Subscribers can then use RAMPAGE displays to determine the state of the spacecraft and formulate a response to the alarm, if necessary. A user can query spacecraft mission data in either binary or comma-separated-value format by use of a Web form or a Practical Extraction and Reporting Language (PERL) script to automate the query process. RAMPAGE runs on Linux and Solaris server computers in the Ground Data System (GDS) of NASA's Jet Propulsion Laboratory and includes components designed specifically to make it compatible with legacy GDS software. The client/server architecture of RAMPAGE and the use of the Java programming language make it possible to utilize a variety of competitive server and client computers, thereby also helping to minimize costs.