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Norman, M. D.

Publications and source records attributed to Norman, M. D..

Constraining Solar System Bombardment Using In Situ Radiometric Dating

The leading, but contentious, model for lunar impact history includes a pronounced increase in impact events at around 3.9 Ga. This late heavy bombardment would have scarred Mars and the terrestrial planets, influenced the course of biologic evolution on the early Earth, and rearranged the very architecture of our Solar System. But what if it's not true? In the last decade, new observations and sample analyses have reinterpreted basin ages and "pulled the pin" on the cataclysm - we may only have the age of one large basin (Imbrium). The Curie mission would constrain the onset of the cataclysm by determining the age of a major pre-Imbrium lunar basin (Nectaris or Crisium), characterize new lunar lithologies far from the Apollo and Luna landing sites, including the basalts in the basin-filling maria and olivine-rich lithologies in the basin margins, and provide a unique vantage point to assess volatiles in the lunar regolith from dawn to dusk.

Cohen, Barbara A.↗

Early Impacts on the Moon: Crystallization Ages of Apollo 16 Melt Breccias

A better understanding of the early impact history of the terrestrial planets has been identified one of the highest priority science goals for solar system exploration. Crystallization ages of impact melt breccias from the Apollo 16 site in the central nearside lunar highlands show a pronounced clustering of ages from 3.75-3.95 Ga, with several impact events being recognized by the association of textural groups and distinct ages. Here we present new geochemical and petrologic data for Apollo 16 crystalline breccia 67955 that document a much older impact event with an age of 4.2 Ga.

Norman, M. D.↗

A Rb-Sr and Sm-Nd Isotope Geochronology and Trace Element Study of Lunar Meteorite LaPaz Icefield 02205

Rubidium-strontium and samarium-neodymium isotopes of lunar meteorite LaPaz Icefield (LAP) 02205 are consistent with derivation of the parent magma from a source region similar to that which produced the Apollo 12 low-Ti olivine basalts followed by mixing of the magma with small amounts (1 to 2 wt%) of trace element-enriched material similar to lunar KREEP-rich sample SaU 169. The crystallization age of LAP 02205 is most precisely dated by an internal Rb-Sr isochron of 2991+/-14 Ma, with an initial Sr-87/Sr-88 at the time of crystallization of 0.699836+/-0.000010. Leachable REE-rich phosphate phases of LAP 02205 do not plot on a Sm-Nd mineral isochron, indicating contamination or open system behavior of the phosphates. Excluding anomalous phases from the calculation of a Sm-Nd isochron yields a crystallization age of 2992+/-85 (initial Epsilon Nd-143 = +2.9+/-0.8) that is within error of the Rb-Sr age, and in agreement with other independent age determinations for LAP 02205 from Ar-Ar and U-Pb methods. The calculated Sm-147/Nd-144 source ratios for LAP 02205, various Apollo 12 and 15 basalts, and samples with strong affinities to KREEP (SaU 169, NWA 773, 15386) are uncorrelated with their crystallization ages. This finding does not support the involvement of a common KREEP component as a heat source for lunar melting events that occurred after crystallization of the lunar magma ocean.

Rankenburg, K.↗

High-Precision Nd Isotopes in Picrites from Hawaii and Iceland - No Evidence for an Early-Formed Enriched Reservoir

New high-precision Nd isotope measurements have shown that the present-day Nd-142/Nd-144 for average chondrites is approximately 20 ppm lower than that for the terrestrial standard and all recent mantle-derived samples measured to date. One explanation for these differences is that an enriched missing reservoir with lower Nd-142/Nd-144 resides in the mantle to balance the bulk Earth to chondritic. Data from Archean Greenland rocks show anomalies in Nd-142/Nd-144 of up to 40 ppm higher than the proposed average for chondrites. This difference between the Archean Greenland rocks and present-day mantle-derived samples has been interpreted to result from remixing of an early-formed enriched reservoir into the convecting mantle during the Archean. If so, the implication from this is that remixing of the enriched reservoir largely shut down some time in the past such that it must at present reside in a region in the mantle that infrequently participates dynamically and leading to volcanism at the surface. Several studies have suggested that the missing reservoir may be present just above the coremantle boundary (CMB). Depending on the size of this reservoir it could potentially make up all of D or exist as distinct domains within it. If such a reservoir does exist, then mantle-derived samples from plume systems that are thought to come from the CMB may be the best opportunity to identify this component using high-precision Nd isotope measurements. To test this, picrites from Hawaii with coupled enrichments in Os-186-Os-187 that has been proposed to be a signature of core-mantle interaction were measured on the JSC Triton for high-precision Nd-142/Nd-144. For comparison, picrites from Hawaii and Iceland that do not show coupled enrichments in Os-186-Os-187 were measured. We have established an external precision for Nd-142/Nd-144 of 3.6 ppm (2 sigma) during the analytical campaign. The Iceland (n=5) and Hawaiian data (n=9) have Nd-142 ranging from -0.01 plus or minus 0.03 to +0.03 plus or minus 0.03 (2 sigma) and there is no resolvable difference between samples with Os isotope enrichments versus those without. The average epsilon Nd-142 of +0.011 plus or minus 0.034 (2 sigma ) for all of the samples (n=14) is not resolvable from the Ames and La Jolla standards with epsilon Nd-142 of +0.000 plus or minus 0.036 (n=16, 2 sigma). These data confirm recent measurements on lavas for the absence of an ancient enriched Nd-142 isotopic signature in plume systems likely derived from D and indicates that such a reservoir, if existing, must now reside in areas of the deep mantle that plumes do not sample.

Brandon, A. D.↗

Mineralogy and Petrology of Unbrecciated Lunar Basaltic Meteorite LAP 02205

LAP 02205 is a 1.2 kg unbrecciated basalt found in the LaPaz icefield of Antarctica during the 2002-2003 ANSMET season [1]. It has been classified as a lunar basalt on the basis of pyroxene Fe/Mn ratios (approx. 60) and oxygen isotopes [1]; both are within previously defined compositional ranges for the Moon [2]. We have initiated a comprehensive study of the mineralogy, petrology and geochemistry of this new and unique meteorite. The results reported here will allow the comparison of this sample both to the other lunar basaltic meteorites (NWA 032, A881757, Y793169, Dho287A), as well as to lunar basalts in the Apollo and Luna collections.

Righter, K.↗

Isotopic Constraints on the Origin of Lunar Ferroan Anorthosites

Ferroan anorthosites have whole rock Nd isotopic compositions that are too radiogenic to have crystallized from a chondritic magma ocean. Mechanisms to disturb the whole rock Sm-Nd isotopic compositions are explored. Additional information is contained in the original extended abstract.

Borg, L. E.↗

Crystallization Age and Impact Resetting of Ancient Lunar Crust from the Descartes Terrane

Lunar ferroan anorthosites (FANs) are relics of an ancient, primary feldspathic crust that is widely believed to have crystallized from a global magma ocean. Compositions and ages of FANs provide fundamental information about the origin and magmatic evolution of the Moon, while the petrology and thermal history of lunar FANs illustrate the structure and impact history of the lunar crust. Here we report petrologic, geochemical, and isotopic (Nd-Sr-Ar) studies of a ferroan noritic anorthosite clast from lunar breccia 67215 to improve our understanding of the composition, age, and thermal history of the Moon.

Norman, M. D.↗

Alkali element constraints on Earth-Moon relations

Given their range of volatilities, alkali elements are potential tracers of temperature-dependent processes during planetary accretion and formation of the Earth-Moon system. Under the giant impact hypothesis, no direct connection between the composition of the Moon and the Earth is required, and proto-lunar material does not necessarily experience high temperatures. Models calling for multiple collisions with smaller planetesimals derive proto-lunar materials mainly from the Earth's mantle and explicitly invoke vaporization, shock melting and volatility-related fractionation. Na/K, K/Rb, and Rb/Cs should all increase in response to thermal volatization, so theories which derive the Moon substantially from Earth's mantle predict these ratios will be higher in the Moon than in the primitive mantle of the Earth. Despite the overall depletion of volatile elements in the Moon, its Na/K and K/Rb are equal to or less than those of Earth. A new model presented here for the composition of Earth's continental crust, a major repository of the alkali elements, suggests the Rb/Cs of the Moon is also less than that of Earth. Fractionation of the alkali elements between Earth and Moon are in the opposite sense to predictions based on the relative volatilities of these elements, if the Moon formed by high-T processing of Earth's mantle. Earth, rather than the Moon, appears to carry a signature of volatility-related fractionation in the alkali elements. This may reflect an early episode of intense heating on Earth with the Moon's alkali budget accreting from cooler material.

Norman, M. D.↗

The granulite suite: Impact melts and metamorphic breccias of the early lunar crust

The granulite suite consists of two major types of rocks. One is coarse-grained and poikilitic with many euhedral crystals of olivine and plagioclase. These characteristics indicate crystallization from a melt; the poikilitic granulites are impact melt breccias. The other group is finer-grained and granoblastic, with numerous triple junctions; the granoblastic granulites are metamorphic rocks. Compositional groups identified by Lindstrom and Lindstrom contain both textural types. Two pyroxene thermometry indicates that both groups equilibrated at 1000 to 1150 C. Calculations suggest that the granoblastic group, which has an average grain size of about 80 microns, was annealed for less than 6 x 10 exp 4 y at 1000 C, and for less than 2500 y at 1150 C. Similar equilibration temperatures suggest that both groups were physically associated after impact events produced the poikilitic melts. Granulitic impactites hold important information about the pre-Nectarian bombardment history of the Moon, and the composition and thermal evolution of the early lunar crust. Granulitic impactites are widely considered to be an important rock type in the lunar crust, but how they formed is poorly understood. Metal compositions and elevated concentrations of meteoritic siderophile elements suggest that most lunar granulites are impact breccias. Their occurrence as clasts in approximately 3.9 Ga breccias, and Ar-(40-39) ages greater than or = 4.2 Ga for some granulites show that they represent a component of the lunar crust which formed prior to the Nectarian cataclysm. Petrographic characteristics of lunar granulites indicate at least two endmember textural variants which apparently formed in fundamentally different ways. One type has granoblastic textures consisting of equant, polygonal to rounded grains, and abundant triple junctions with small dispersions around 120 degrees indicating a close approach to textural equilibrium. As suggested by many authors, granoblastic granulites probably formed by subsolidus annealing and recrystallization of fragmental or glassy protoliths. Examples of this type include 15418, 78155, and 79215. The other textural type consists of poikilitic to poikiloblastic rocks with euhedral to subhedral plagioclase and olivine enclosed by interstitial pyroxene. In some cases, the texture resembles that of an orthocumulate. Examples of this type include 60035, 67955, and 77017. Rounding of grain edges is common in poikilitic granulites, but the regular crystal shapes and widely dispersed dihedral angles show they are far from textural equilibrium. The textures of poikilitic granulites are more consistent with the formation of these rocks by crystallization from a melt than by subsolidus metamorphism. A few samples have been recognized with textural characteristics transitional between those of the granoblastic and poikiloblastic endmembers (e.g., 72559, 78527). Pyroxene compositions taken from the literature and determined for this study by electron microprobe were used to calculate equilibration temperatures. The Kretz Ca transfer (solvus) thermometer and the Lindsley and Anderson graphical method both give similar temperatures, which range from approximately 1000 to 1150 C. There is no apparent temperature difference between granoblastic and poikilitic varieties, but there is a hint in these data that the more ferroan varieties equilibrated to lower temperatures. Additional studies are in progress to test this possibility.

Cushing, J. A.↗

Fragments of ancient lunar crust: Ferroan noritic anorthosites from the descartes region of the Moon

Noritic anorthosite clasts from breccia 67016 have bulk compositions similar to that of the upper crust of the Moon and petrogenetic affinities with pristine ferroan anorthosites. Rb-Sr and Sm-Nd isotopic compositions of mineral separates from one of these clasts suggest very old (greater than or = 4.4 Ga) ages, but interpretation of these data is complicated by the multi-stage history of the clasts which involved magmatic crystallization, brecciation, subsolidus recrystallization, and sulfide metasomatism. These clasts record some of the earliest events on the Moon, including early crust formation, accretionary bombardment, and degassing of the lunar interior. Modal analyses of these clasts show they are now composed of about 70 percent plagioclase, 28 percent pyroxene, 2 percent troilite, and minor amounts of ilmenite and chromite. No metallic iron, phosphates, or other trace phases were observed. Olivine is very rare, occurring only as relicts within secondary troilite+pyroxene intergrowths which may reflect reaction of olivine with sulfurous vapors. PIXE proton microprobe analyses of the sulfides show that the metasomatism was accompanied by enrichments of Cu, Zn, Ni, Se, and Sb. The clasts have been only mildly shocked since the observed texture was established. Major and minor element mineral compositions are very homogeneous and strikingly similar to those of pristine ferroan anorthosites. Pyroxene compositions indicate equilibration temperatures of 850-900 C. Except for the sulfide and chalcophile element metasomatism, these clasts appear to be essentially monomict and probably represent a noritic member of the ferroan anorthosite suite. Their low Ni contents and Ni/Co ratios are consistent with the interpretation of these clasts as igneous rocks which have escaped mixing with meteoritic material.

Norman, M. D.↗

Volatility in the lunar crust: Trace element analyses of lunar minerals by PIXE proton microprobe

In situ determination of mineral compositions using microbeam techniques can characterize magma compositions through mineral-melt partitioning, and be used to investigate fine-grained or rare phases which cannot be extracted for analysis. Abundances of Fe, Mn, Sr, Ga, Zr, Y, Nb, Zn, Cu, Ni, Se, and Sb were determined for various mineral phases in a small number of lunar highlands rocks using the PIXE proton microprobe. Sr/Ga ratios of plagioclase and Mn/Zn ratios of mafic silicates show that the ferroan anorthosites and Mg-suite cumulates are depleted in volatile lithophile elements to about the same degree compared with chondrites and the Earth. This links the entire lunar crust to common processes or source compositions. In contrast, secondary sulfides in Descartes breccia clasts are enriched in chalcophile elements such as Cu, Zn, Ni, Se, and Sb, and represent a potential resource in the lunar highlands.

Norman, M. D.↗

Petrology of suevitic lunar breccia 67016

The present investigation is concerned with a petrologic study of one of the largest samples of feldspathic fragmental breccia, 67016. Evidence presented indicates that 67016 (and by implication the entire suite of feldspathic fragmental breccias) was originally deposited in a single impact event, possibly in a setting geologically analogous to terrestrial suevite. 'Feldspathic fragmental breccia' is the term adopted for the friable, light-colored breccias with abundant dark clasts which are the predominant rock type on the rim and walls of North Ray crater. Macroscopically 67016 is a light-gray breccia with approximately 20% dark clasts, approximately 10% white lithic clasts, and scattered single grains of plagioclase, mafic silicates, opaques, metal, and spinel.

Norman, M. D.↗

Geochemical constraints on the igneous evolution of the lunar crust

Ti/Sm and Sc/Sm ratios confirm and extend the mineralogical dichotomy between the Mg-suite and the ferroan anorthosites. The latter have Ti/Sm near the chondritic ratio while the Ti/Sm of the pristine troctolites, norites, and KREEP basalts is nearly an order of magnitude lower. The two suites cannot be comagmatic; this implies that at least two major episodes of magmatism were involved in lunar crustal formation. Ferroan anorthosites probably formed as relatively direct products of the magma ocean. Mixing between a 'primitive' magma and a more 'evolved' magma may be necessary to account for both the major and trace element compositions of the Mg-suite.

Norman, M. D.↗

The distinction of pristine from meteorite-contaminated highlands rocks using metal compositions

Pristine highlands rocks, i.e., those which have retained the chemical characteristics they acquired from igneous processes, contain metal grains whose Ni and Co contents are distinct from those in most polymict, meteorite-contaminated rocks. The difference is mainly a result of the bulk Ni/Co ratios of pristine rocks being much lower than those of chondritic meteorites. The compositions of metal grains thus provide a rapid and effective criterion for the recognition of pristine highlands samples.

Ryder, G.↗

A summary of the petrology and geochemistry of pristine highlands rocks

The petrology and geochemistry of pristine lunar highlands rock samples consisting of ferroan anorthosites, norites, troctolites, spinel troctolites/dunite/lherzolite, and KREEP, are described. In addition, petrographic and chemical evidence is presented which shows that low-siderophile rocks are the result of endogenous igneous activity and not impact melt differentiation. For example, these rocks contain Fe-metal as a late-crystallizing phase, and have W/La ratios higher than polymict breccias.

Norman, M. D.↗