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Oppenheimer, M.

Publications and source records attributed to Oppenheimer, M..

Ultraviolet absorption studies of H2O and other species in comet comae with satellite telescope-spectrometers

It is noted that ultraviolet absorption by H2O and other species in the comae of comets could be detected by studying, with satellite telescope-spectrometers, the occultation of hot stars by comets. Observations of this type could produce the first detection of H2O, the fundamental parent molecule in comet comae, and give measures of molecular level populations. The capabilities of the High Resolution Spectrograph on Space Telescope, the first instrument suitable for such observations, are discussed. A Haser model is used to estimate the molecular column densities and to predict equivalent widths for lines of H2O, OH, CO, C, and O as functions of time and angular distance from a comet with a high H2O production rate. The minimum detectable equivalent widths are determined, thereby giving the maximum angular separation from such a comet at which H2O, OH, and CO could be studied. Estimated equivalent widths for CO, OH, and the resonance lines of C and O suggest that these species may also be detected.

Smith, P. L.↗

EUV flux variations during solar cycle 21 from AE-E He/+/ abundances

The ionization rate of helium in the thermosphere is inferred from AE-E ion and neutral particle composition measurements, made on several days during solar cycle 21, in the context of a steady state photochemical model for helium ions. The inferred ionization rate varies by a factor of 4 between July 1976 and January 1979, a value consistent with the variation in the flux measured during the same period by the EUV spectrometer on board the AE-E satellite.

Oppenheimer, M.↗

The effect of solar-cycle ultraviolet flux variations on cometary gas

The effects on comet gas of variations in the solar ultraviolet flux during solar cycle 21 are discussed. The photoionization, photodissociation, and resonance fluorescence and scattering rates of individual atoms and molecules increase by factors ranging up to 4, leading to potential order of magnitude variations in emission-line fluxes between minimum and maximum solar activity. These effects are illustrated for H2O and CO. Recent observations of comet Bradfield (1979) are discussed, and it is suggested that comets appearing near solar maximum be extensively observed to provide information on the response of cometary gas to solar flux variations, which can be used to discriminate between cometary models.

Oppenheimer, M.↗

Sodium D-line emission in Comet West /1975n/ and the sodium source in comets

A spectrum of the sodium D-line emission from Comet West (1975n) taken at heliocentric distance 1.4 AU is analyzed by comparing the D-line brightness to that in the underlying continuum. Using the observations of this comet by Ney and Merrill, it is found that the dust grains which dominate the visible and infrared continua are too cool to provide the observed sodium atoms through evaporation of sodium metal or a sodium compound from grain surfaces. Though sodium metal may evaporate from a small-grain component, it is suggested that molecules embedded in the volatile nuclear matrix are a more plausible source of sodium. The relationship between this source and the interstellar sodium abundance is discussed.

Oppenheimer, M.↗

Molecular diagnostics of interstellar shocks

The chemistry of molecules in shocked regions of the interstellar gas is considered and calculations are carried out for a region subjected to a shock at a velocity of 8 km/sec. Substantial enhancements are predicted in the concentrations of the molecules H2S, SO, and SiO compared to those anticipated in cold interstellar clouds.

Hartquist, T. W.↗

An analysis of the coma of comet Bennett 1970 II

Brightness profiles for emission features of H2O(+) in comet Bennett 1970 II are analyzed, taking into account the role of chemical reactions in the coma. By comparing the rates of transport processes derived from the brightness profile with known chemical rate constants, upper limits on the abundances and production rates of H2O, CH4, NH3, and other possible coma constituents are found. The derived upper limit on the H2O production rate inside 10 to the 4th power km is less than the observed OH production rate averaged over the coma of this comet. It is concluded that the brightness profiles of H2O(+) and OH in comet Bennett 1970 II which are presently available are inconsistent with production of OH primarily by photodissociation of H2O molecules sublimating from the nucleus. The existence of an extended source of H2O is not ruled out.

Oppenheimer, M.↗

The EUV flux inferred from AE-C He/+/ abundances

The ionization rate of helium in the thermosphere is inferred from He(+) abundances determined by instrumentation on the Atmosphere Explorer-C satellite. The inferred ionization rate is independent of the particular geophysical parameters of the thermosphere for solar zenith angles less than 80 deg and altitudes between 280 and 360 km. The ionization rate is consistent with a value calculated from the EUV flux of Hinteregger (1976) below 504 A.

Oppenheimer, M.↗

Comparison of measured and calculated thermospheric molecular oxygen densities

The open source neutral mass spectrometers on the AE-C, -D, and -E satellites were equipped with a 'fly-through' mode of operation which has provided direct measurements of molecular oxygen densities over a large portion of the globe. A complementary set of O2 densities is derived by using AE ion measurements and a scheme based on the daytime ion chemistry of O2(+) in the thermosphere. A comparison of the two data sets reveals general agreement over northern latitudes during periods of relatively low Ap and F10.7. The simplifying assumptions made in the photochemical scheme require that caution be used in calculating O2, especially at high latitudes and altitudes below 200 km

Potter, W. E.↗

Ion chemistry of N2/+/ and the solar ultraviolet flux in the thermosphere

We have analyzed daytime composition measurements in the thermosphere from Atmosphere Explorer-C by use of a theory of the ion chemistry. Predicted and measured N2(+) densities are compared to infer global variation of the solar ionizing flux. Results indicate that the solar flux of Hinteregger measured on Atmosphere Explorer-C provides an adequate basis for the calculation of solar ultraviolet photoionization rates. The role of metastable species is examined, and theoretical O+(2D) densities are presented.

Oppenheimer, M.↗

Recombination of NO/+/ in the ionosphere

Simultaneous nighttime measurements of ion and neutral concentrations and temperatures made by the Atmosphere Explorer-C satellite were used to determine the recombination rate coefficient of NO(+) as a function of electron temperature. The results agree in shape and absolute magnitude to within one standard deviation with those of Walls and Dunn (1974), indicating that NO(+) ions in the ionosphere may be in the ground vibrational state.

Torr, D. G.↗

Gas phase chemistry in comets

The significance of gas phase reactions in determining the nuclear structure of comets is discussed. The sublimation of parent molecules such as H2O, CH4, CO2, and NH3 from the surface of the nucleus and their subsequent photodissociation and ionization in forming observed cometary molecular species are elaborated.

Oppenheimer, M.↗

Metastable 2P oxygen ions in the daytime thermosphere

Dayglow radiation at 7319 A has been measured by the visible airglow experiment on Atmosphere Explorer C. The overhead surface brightness measured at 15.4 hours local solar time on January 27, 1974, was 250 plus or minus 10 R. The volume emission rate had a peak value of 20 photons per cu cm per sec at a height of about 210 km. The data show clear evidence of quenching by collisons with thermal electrons at the higher altitudes and with neutral particles at lower altitudes. Quenching by neutral particles occurs at nearly the gas kinetic rate.

Walker, J. C. G.↗

Collision matrix elements near a pseudocrossing of potential energy curves.

The cross sections of certain inelastic atomic collision processes can be determined from the matrix elements of the collision operator, d/dR, where R is the separation of the colliding atoms. At one extreme, the matrix element may pass through zero near a pseudocrossing of potential energy curves, while at the other extreme, it may pass through a maximum. The resulting cross sections are entirely different in magnitude and in energy dependence. An attempt is made to predict the qualitative behavior of the collision matrix elements with variations in R from an analysis of the Born-Oppenheimer adiabatic Hamiltonian. The modifications caused by a second pseudocrossing with a third adiabatic state are studied.

Oppenheimer, M.↗

Nonresonant charge-capture - Na/+/ + Li reversibly proceeding to Na + Li/+/.

The cross sections for the process Na(+) + Li reversibly proceeding to Na + Li(+) are calculated in the range from 100 eV to 12 keV using a perturbed stationary state formulation, and are found to agree with experiment to the extent of reproducing detailed structure. A simple interpretation is presented of the observed quasi-oscillatory structure.

Bottcher, C.↗